采用了电弧放电方法合成纳米炭管,在使用Fe、Co、Ni、Ti、Zr等金属元素作催化剂的基础上,探索天然矿物-黄铁矿(FeS2)、磁黄铁矿(Fe1-xS)、方铅矿(PbS)、磁铁矿(FeFe2O4)、刚玉(Al2O3)及合成FeCl3、NaCl、KCl等化合物作催化剂合成纳米炭管的途径,讨论其催化机理.实验说明:用矿物(化合物)作催化剂合成纳米炭管是可行的,并有应用潜力,其催化效果与电子层结构、化合物键性类型、晶体缺陷等密切相关.就催化效果而言,总体上表现出过渡金属元素催化效果优于非过渡金属元素,晶体结构中共价键程度高的化合物(含金属键或改性的共价键的化合物)催化效果好于离子键程度高的化合物.
参考文献
[1] | Iijima S .Helical microtubules of graphitic carbon[J].Nature,1991,354(6348):56. |
[2] | Mintmire JW.;White CT. .ELECTRONIC AND STRUCTURAL PROPERTIES OF CARBON NANOTUBES[J].Carbon: An International Journal Sponsored by the American Carbon Society,1995(7):893-902. |
[3] | Takashi Kyotani;Li-fu Tsai;Akira Tomita .Preparation of Ultrafine Carbon Tubes in Nanochannels of an Anodic Aluminum Oxide Film[J].Chemistry of Materials,1996(8):2109-2113. |
[4] | A. FONSECA;K. HERNADI;J. B.NAGY;PH. LAMBIN;A. A. LUCAS .MODEL STRUCTURE OF PERFECTLY GRAPHITIZABLE COILED CARBON NANOTUBES[J].Carbon: An International Journal Sponsored by the American Carbon Society,1995(12):1759-1775. |
[5] | Charlier JC;Blase X .Microscopic Growth Mechanisms for Carbon Nanotubes[J].Science,1997(5300):646-649. |
[6] | 张孝彬.纳米碳管的电子衍射及其螺旋度测量[J].电子显微学报,1997(02):128. |
[7] | Kiang CH.;Beyers R.;Bethune DS.;Dresselhaus MS. .VAPOR-PHASE SELF-ASSEMBLY OF CARBON NANOMATERIALS[J].Chemical Physics Letters,1996(1/2):41-47. |
[8] | Weaver J H .Totally tubular[J].Science,1994,265(5172):611. |
[9] | Kiang C-H;Goddard W A;Beyers R et al.Structural modification of single-layer carbon nanotubes with an electron beam[J].Journal of Physical Chemistry,1996,100(09):3749. |
[10] | Ebbesn T W.Carbon nanotubes[M].CRC Press,Boca Raton,New York,London,Tokyo,1997 |
[11] | Kiang CH.;Beyers R.;Bethune DS.;Goddard WA. .CARBON NANOTUBES WITH SINGLE-LAYER WALLS[J].Carbon: An International Journal Sponsored by the American Carbon Society,1995(7):903-914. |
[12] | Iijima S .Growth of carbon nanotubes[J].Materials Science and Engineering B,1993,19(1-2):172. |
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