硼异质富勒烯制备过程中巴基管与巴基葱的异常生长行为

1.浙江大学,玉泉校区化学系,渐江,杭州,310027

2.浙江大学,玉泉校区化学系,渐江,杭州,310027

3.浙江大学,玉泉校区化学系,渐江,杭州,310027

4.渐江大学,玉泉校区物理系,渐江,杭州,310027

5.渐江大学,玉泉校区物理系,渐江,杭州,310027

基金项目: 高等学校博士学科点专项科研项目(97033510) 中国科学院资助项目(29573119) 浙江省自然科学基金(297009)

ABNORMAL GROWTH OF BUCKYTUBULES AND BUCKYONIONS DURING SYNTHESIS OF BORON HETEROFULLERENES

电弧法制备掺硼富勒烯过程中发现,与纯富勒烯相比,掺硼富勒烯烟灰的电导率提高一个数量级以上.电镜观察显示掺硼富勒烯烟灰中含有较多的巴基管和巴基葱,而阴极沉积物中则发现含有珠链状巴基葱.

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