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  4. 炭与TiO2光催化剂的复合及协同作用研究进展

新型炭材料, 2004, 19(3): 229-238. doi: 10.3969/j.issn.1007-8827.2004.03.013

炭与TiO2光催化剂的复合及协同作用研究进展

黄正宏 1, , 许德平 2, , 康飞宇 3, , 郝吉明 4,

1.清华大学,材料科学与工程系,北京,100084

2.中国矿大北京校区,化学与环境工程学院,北京,100083

3.清华大学,材料科学与工程系,北京,100084

4.清华大学,环境科学与工程系,北京,100084

基金项目:   国家高技术研究发展计划(863计划)(2002AA649060)  

关键词： 炭 , 二氧化钛(TiO2) , 复合光催化剂 , 协同作用

Recent developments in the preparation and of a C/TiO2 composite photocatalyst

通过论述炭与TiO2光催化剂的复合方式,系统总结了复合光催化剂的各种制备方法,指出炭与TiO2的复合呈现多样化的特征,炭不仅作为载体,还可以用作涂层、造孔剂以及助剂.同时,炭在复合体中也展现出多方面的作用,不仅可以富集目标污染物,捕获中间产物,还可以抑制水蒸气和其他组分对光催化降解的影响,并且可以抑制热处理时TiO2相变和晶粒长大.可见,炭与TiO2光催化剂的复合将为推动光催化技术的实用化产生积极影响.

参考文献

[1] Godish T.Indoor Air Pollution Control[M].Chelsea, Michigan: Lewis Publishers,1989:42-48.
[2] 欧洲地区办事处;刘向新.室内空气质量-有机污染物[M].北京:人民卫生出版社,1991:3-34.
[3] Zheng-Hong Huang;Feiyu Kang;Wen Lai Huang;Jun-Bing Yang;Kai-Ming Liang;Meng-Long Cui;Zhiying Cheng .Pore Structure and Fractal Characteristics of Activated Carbon Fibers Characterized by Using HRTEM[J].Journal of Colloid and Interface Science,2002(2):453-457.
[4] Cal M P;Rood M J;Larson S M .Removal of VOCs from humidified gas streams using activated carbon cloth[J].Gas Separation and Purification,1996,10(02):117-121.
[5] Cal M P;Rood M J;Larson S M .Gas phase adsorption of volatile organic compounds and water vapor on activated carbon cloth[J].Energy and Fuels,1997,11(02):311-315.
[6] Mangun CL.;Braatz RD.;Economy J.;Daley MA. .Effect of pore size on adsorption of hydrocarbons in phenolic-based activated carbon fibers[J].Carbon: An International Journal Sponsored by the American Carbon Society,1998(1/2):123-129.
[7] Cal M P;Rood M J;Larson S M .Experimental and modeled results describing the adsorption of acetone and benzene onto activated carbon fibers[J].Environmental Progress,1994,13(01):26-30.
[8] Foster K L;Fuerman R G;Economy J et al.Adsorption characteristics of trace volatile organic compounds in gas streams onto activated carbon fibers[J].Chemistry of Materials,1992,4(05):1068-1073.
[9] Huang Z H;Kang F Y;Zheng Y P et al.Adsorption of trace polar methy-ethyl-ketone and non-polar benzene vapors on viscose rayon based activated carbon fibers[J].Carbon,2002,40:1363-1367.
[10] KANG F Y;Huang Z H;Liang K M et al.Adsorption of volatile organic compounds in nitrogen streams on the oxidized activated carbon fibers[J].Adsorption Science and Technology,2001,19(05):423-433.
[11] Huang Z H;Kang F Y;Yang J B et al.Adsorption of volatile organic compounds on activated carbon fiber prepared by carbon dioxide[J].Molecular Crystals and Liquid Crystals,2002,388:437-442.
[12] Huang Z H;Kang F Y;Zheng Y P et al.Adsorption characteristics of trace volatile organic compounds on activated carbon fibers at room temperature[J].Adsorption Science and Technology,2002,20(05):495-500.
[13] Zheng-Hong Huang;Feiyu Kang;Kai-Ming Liang;Jiming Hao .Breakthrough of methyethylketone and benzene vapors in activated carbon fiber beds[J].Journal of hazardous materials,2003(1/3):107-115.
[14] Akira Fujishima;Tata N. Rao;Donald A. Tryk .Titanium dioxide photocatalysis[J].Journal of photochemistry and photobiology, C. Photochemistry reviews,2000(1):1-21.
[15] Takeda N;Torimoto T;Sampath S et al.Effect of inert supports for titanium-dioxide loading on enhancement of photodecomposition rate of gaseous propionaldehyde[J].Journal of Physical Chemistry,1995,99(24):9986-9991.
[16] 杨骏兵;康飞宇;黄正宏.室内环境中挥发性有机物的光催化转化及多孔炭的应用[A].绵阳,2001:317-321.
[17] 杨全红,郑经堂,王茂章.活性炭纤维对NH3的吸附研究Ⅰ PAN-ACF孔径结构对NH3静态吸附的影响[J].新型碳材料,1998(02):43-48.
[18] 符若文,杜秀英,曾汉民,林远声,徐浩.负载金属基活性炭纤维对一氧化氮和一氧化碳的吸附及催化性能研究[J].新型炭材料,2000(03):1-6.
[19] 马青兰,王增长,李敏敏,许并社.活性炭净化废水处理研究[J].新型炭材料,2002(01):59-61.
[20] 解强,张香兰,陈清如,宫国卓.活性炭硝酸表面改性对催化剂分散度的影响[J].新型炭材料,2003(03):203-208.
[21] 邹李鸣,黄正宏,康飞宇,杨骏兵.载银酚醛树脂基球形活性炭的研究[J].新型炭材料,2003(03):214-218.
[22] Doi M;Saka S;Miyafuji H et al.Development of carbonized tio-woody composites for environmental cleaning[J].Material Scientific Research International,2000,6(01):15-21.
[23] Tokoro H;Saka S .The photo-catalytic mechanism for formaldehyde by carbonized TiO2-woody composites[J].Material Scientific Research International,2001,7(02):132-137.
[24] Matos J;Laine J;Herrmann J M .Association of activated carbons of different origins with titania in the photocatalytic purification of water[J].Carbon,1999,37:1870-1872.
[25] Matos J;Laine J;Herrmann J M .Synergy effect in the photocatalytic degradation of phenol on a suspended mixture of titania and activated carbon[J].Applied Catalysis B:Environmental,1998,18:281-291.
[26] J.Matos;J.-M.Herrmann;J.Laine .Effect of the Type of Activated Carbons on the Photocatalytic Degradation of Aqueous Organic Pollutants by UV-Irradiated Titania[J].Journal of Catalysis,2001(1):10-20.
[27] 薛向东,金奇庭.TiO2-活性炭组合光催化降解苯酚废水[J].中国给水排水,2002(06):42-45.
[28] Ibusuki T;Takeuchi K .Removal of low concentration nitrogen-oxides through photoassisted heterogeneous catalysis[J].Journal of Molecular Catalysis(China),1994,88(01):93-102.
[29] 贺飞,唐怀军,赵文宽,方佑龄.纳米TiO2光催化剂负载技术研究[J].环境污染治理技术与设备,2001(02):47-58.
[30] Ao CH.;Lee SC. .Enhancement effect of TiO2 immobilized on activated carbon filter for the photodegradation of pollutants at typical indoor air level[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2003(3):191-205.
[31] Arana J.;Dona-Rodriguez JM.;Rendon ET.;Cabo CGI.;Gonzalez-Diaz O. Herrera-Melian JA.;Perez-Pena J.;Colon G.;Navio JA. .TiO2 activation by using activated carbon as a support - Part I. Surface characterisation and decantability study[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2003(2):161-172.
[32] C. H. Ao;S. C. Lee .Combination effect of activated carbon with TiO_2 for the photodegradation of binary pollutants at typical indoor air level[J].Journal of Photochemistry and Photobiology, A. Chemistry,2004(2/3):131-140.
[33] Arana I.;Dona-Rodriguez JM.;Rendon ET.;Cabo CGI.;Gonzalez-Diaz O. Herrera-Melian JA.;Perez-Pena J.;Colon G.;Navio JA. .TiO2 activation by using activated carbon as a support - Part II. Photoreactivity and FTIR study[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2003(2):153-160.
[34] 古政荣,陈爱平,戴智铭,古宏晨,陶国忠.活性炭-纳米二氧化钛复合光催化空气净化网的研制[J].华东理工大学学报(化学与生化工程专辑),2000(04):367-371.
[35] UCHIDA H;Itoh S;Yoneyama H.Photocatalytic decomposition of propyzamide using TiO2 supported on activated carbon[J].Chemistry Letters,1993(12):1995-1998.
[36] Torimoto T;Okawa Y;Takeda N et al.Effect of activated carbon content in TiO2-loaded activated carbon on photodegradation behaviors of dichloromethane[J].Journal of Photochemistry and Photobiology A:Chemistry,1997,103:153-157.
[37] M.Nazir;J.Takasaki;H.Kumazawa .Photocatalytic Degradation of Gaseous Ammonia and Trichloroethylene over TiO_2 Ultrafine Powders Deposited on Activated Carbon Particles[J].Chemical Engineering Communications,2003(3):322-333.
[38] Harada M;Tanii A;Yamashita H et al.Preparation of titanium oxide photocatalysts loaded on activated carbon by an ionized cluster beam method and their photocatalytic reactivities for the degradation of 2-propanol diluted in water[J].Zeitschrift für Physikalische Chemie,1999,213:59-65.
[39] Hiromi Yamashita;Masaru Harada;Akihiro Tanii;Miwa Honda;Masato Takeuchi;Yuichi Ichihashi;Masakazu Anpo;Nobuya Iwamoto;Nobuhisa Itoh;Takashi Hirao .Preparation of efficient titanium oxide photocatalysts by an ionized cluster beam (ICB) method and their photocatalytic reactivities for the purification of water[J].Catalysis Today,2000(1):63-69.
[40] Yamashita H;Harada M;Tanii A et al.Preparation of efficient titanium oxide photocatalysts by an ionized cluster beam method and their application for the degradation of propanol diluted in water[J].Studies in surface science and catalysis,2000,130:1931-1936.
[41] B. Tryba;A.W. Morawski;M. Inagaki .Application of TiO_2-mounted activated carbon to the removal of phenol from water[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2003(4):427-433.
[42] B.Tryba;A.W.Morawski;M.Inagaki .A new route for preparation of TiO_2-mounted activated carbon[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2003(1):203-208.
[43] Seung-woo Lee;Wolfgang M. Sigmund .Formation of anatase TiO_2 nanoparticles on carbon nanotubes[J].Chemical communications,2003(6):780-781.
[44] Sun J;Iwasa M;Gao L et al.Single-walled carbon nanotubes coated with titania nanoparticles[J].CARBON,2004,42:885-901.
[45] J. PRZEPIORSKI;N. YOSHIZAWA;Y. YAMADA .Activated carbons containing TiO_(2): Characterization and influence of a preparation method on the state of TiO_(2) supported[J].Journal of Materials Science,2001(17):4249-4257.
[46] Tamai H.;Katsu N.;Ono K.;Yasuda H. .Simple preparation of TiO2 particles dispersed activated carbons and their photo-sterilization activity[J].Journal of Materials Science,2002(15):3175-3180.
[47] Harada M;Honda M;Yamashita Y et al.Preparation of titanium oxide photocatalyst loaded on activated carbon[J].Research on Chemical Intermediates,1999,25(08):757-768.
[48] Tsumura T.;Kojitani N.;Umemura H.;Toyoda M.;Inagaki M. .Composites between photoactive anatase-type TiO2 and adsorptive carbon[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2002(1/4):429-436.
[49] Ding Z;Hu X;Yue P L et al.Synthesis of anatase TiO2 supported on porous solids by chemical vapor deposition[J].Catalysis Today,2001,68:173-182.
[50] Motojima S;Suzuki T;Hishikawa Y et al.TiO2/C composite microcoils and TiO2 hollow microcoils with high photocatalytic activities and electromagnetic (EM) wave absorption abilities[J].Japanese Journal of Applied Physics,2003,42:938-940.
[51] Shoji Nagaoka;Yuu Hamasaki;Shin-ichiro Ishihara;Masanori Nagata;Kokoro Iio;Chohachiro Nagasawa;Hirotaka Ihara .Preparation of carbon/TiO_2 microsphere composites from cellulose TiO_2microsphere composites and their evaluation[J].Journal of molecular catalysis, A. Chemical,2002(2):255-263.
[52] Hendrik K. Kammler;Sotiris E. Pratsinis .Carbon-coated titania nanostructured particles: Continuous, one-step flame-synthesis[J].Journal of Materials Research,2003(11):2670-2676.
[53] Tomoki Tsumura;Naoko Kojitani;Ikuichiro Izumi;Norio Iwashita;Masahiro Toyoda;Michio Inagaki .Carbon coating of anatase-type TiO_2 and photoactivity[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2002(5):1391-1396.
[54] Michio Inagaki;Yumiko Hirose;Takafumi Matsunaga .Carbon coating of anatase-type TiO_2 through their precipitation in PVA aqueous solution[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(13):2619-2624.
[55] Takeda N.;Torimoto T.;Yoneyama H.;Iwata N. .Influence of carbon black as an adsorbent used in TiO2 photocatalyst films on photodegradation behaviors of propyzamide[J].Journal of Catalysis,1998(2):240-246.
[56] 陈中颖,余刚,张彭义,蒋展鹏.碳黑改性纳米TiO2薄膜光催化降解有机污染物[J].科学通报,2001(23):1961-1965.
[57] 陈中颖,余刚,张彭义,蒋展鹏.碳黑改性TiO2薄膜光催化剂的结构性质[J].环境科学,2002(02):55-59.
[58] Colón G;Hidalgo M C;Navo J A .A novel preparation of high surface area TiO2 nanoparticles from alkoxide precursor and using active carbon as additive[J].Catalysis Today,2002,76:91-101.
[59] Yoneyama H;Torimoto T .Titanium dioxide/adsorbent hybrid photocatalysts for photodestruction of organic substances of dilute concentrations[J].Catalysis Today,2000,58:133-140.
[60] Torimoto T;Ito S;Kuwabata S et al.Effects of adsorbents used as supports for titanium dioxide loading on photocatalytic degradation of propyzamide[J].Environmental Science and Technology,1996,30:1275-1281.
[61] LU M C;Chen J N;Chang K T .Effect of adsorbents coated with titanium dioxide on the photocatalytic degradation of propoxur[J].Chemosphere,1999,38(03):617-627.
[62] Hiroshi Irie;Yuka Watanabe;Kazuhito Hashimoto .Carbon-doped Anatase TiO_2 Powders as a Visible-light Sensitive Photocatalyst[J].Chemistry Letters,2003(8):772-773.
[63] Shanmugasundaram Sakthivel;Horst Kisch .Daylight Photocatalysis by Carbon-Modified Titanium Dioxide[J].Angewandte Chemie,2003(40):4908-4911.
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