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  4. 碳纳米管溶解性及其化学修饰

新型炭材料, 2004, 19(4): 312-318. doi: 10.3969/j.issn.1007-8827.2004.04.013

碳纳米管溶解性及其化学修饰

晋卫军 1, , 孙旭峰 2, , 王煜 3,

1.山西大学,化学化工学院,山西,太原,030006

2.山西大学,化学化工学院,山西,太原,030006

3.山西大学,化学化工学院,山西,太原,030006

基金项目:   山西省留学回国人员科研项目(2001)   教育部科学技术研究项目(2002)  

关键词： 碳纳米管 , 溶解性 , 分散 , 化学修饰

Solubilization and functionalization of carbon nanotubes

详细评述了增加碳纳米管在水和有机溶剂中溶解性的途径,包括单一溶剂直接分散、电子供-受体电荷转移、可溶性聚合物或表面活性剂筒状胶束包裹等非共价键相互作用和顶端开口、化学衍生以及侧壁化学修饰等共价化学修饰.指出今后一段时期碳纳米管化学的主要任务为通过非共价的或共价的化学修饰,改善碳纳米管本身的性能和用途,并耦合其他如化学的、生物的或物理的功能扩展其应用范围.进一步深入理解碳纳米管化学(尤其是其溶液化学)反应理论.

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