石墨烯光电子器件的应用研究进展

新型炭材料, 2014, (5): 329-356. doi: 10.3969/j.issn.1007-8827.2014.05.001

石墨烯光电子器件的应用研究进展

李绍娟 ^1, , 甘胜 ^2, , 沐浩然 ^3, , 徐庆阳 ^4, , 乔虹 ^5, , 李鹏飞 ^6, , 薛运周 ^7, , 鲍桥梁 ^8,

1.苏州大学功能纳米与软物质研究院，苏州纳米科技协同创新中心，江苏省碳基功能材料与器件高技术研究重点实验室，江苏苏州 215123

2.苏州大学功能纳米与软物质研究院，苏州纳米科技协同创新中心，江苏省碳基功能材料与器件高技术研究重点实验室，江苏苏州 215123

3.苏州大学功能纳米与软物质研究院，苏州纳米科技协同创新中心，江苏省碳基功能材料与器件高技术研究重点实验室，江苏苏州 215123

4.苏州大学功能纳米与软物质研究院，苏州纳米科技协同创新中心，江苏省碳基功能材料与器件高技术研究重点实验室，江苏苏州 215123

5.苏州大学功能纳米与软物质研究院，苏州纳米科技协同创新中心，江苏省碳基功能材料与器件高技术研究重点实验室，江苏苏州 215123

6.苏州大学功能纳米与软物质研究院，苏州纳米科技协同创新中心，江苏省碳基功能材料与器件高技术研究重点实验室，江苏苏州 215123

7.苏州大学功能纳米与软物质研究院，苏州纳米科技协同创新中心，江苏省碳基功能材料与器件高技术研究重点实验室，江苏苏州 215123

8.苏州大学功能纳米与软物质研究院，苏州纳米科技协同创新中心，江苏省碳基功能材料与器件高技术研究重点实验室，江苏苏州 215123

基金项目: Natural Science Foundation of Jiangsu Province(BK20130328) 国家高技术研究发展计划(2013AA031903) Key Projects in the National Science &Technology Pillar Program during the Twelfth Five-year Plan Period(51290273) 国家自然科学优秀青年科学基金(51222208) 江苏省自然科学基金(BK20130328).@@@@National High-tech R&D Program of China 863 Program(2013AA031903) National Science Fund for Distin-guished Young Scholars(51222208) 十二五重大项目(51290273)

关键词：石墨烯 , 脉冲激光器 , 光调制器 , 光探测器 , 表面等离子体 , 太赫兹

Research progress in graphene use in photonic and optoelectronic devices

Keywords： Graphene , Ultrafast lasers , Modulators , Photodetectors , Surface plasmon , Terahertz

自2004年被发现以来，石墨烯因其卓越的光学和电学性能及其与硅基半导体工艺的兼容性，备受学术界和工业界的广泛关注。作为一种独特的二维原子晶体薄膜材料，石墨烯有着优异的机械性能、超高的热导率和载流子迁移率、超宽带的光学响应谱及极强的非线性光学特性，使其在新型光学和光电器件领域具有得天独厚的优势。一系列基于石墨烯的新型光电器件先后被研制出，已显示出优异的性能和良好的应用前景。此外，近期石墨烯表面等离子体激元的发现及太赫兹器件的研究进一步促进了石墨烯基光电器件的蓬勃发展。综述重点总结近年来石墨烯在超快脉冲激光器、光调制器、光探测器以及表面等离子体领域的应用研究进展，并进一步分析目前所面临的主要问题、挑战及其发展趋势。

Graphene has very significant optical and electronic properties, which attract enormous attention. As a unique two-di-mensional crystal with one atom thickness, it has high electron and thermal conductivities in addition to ? exibility, robustness and impermeability to gases. Its ultra-broad band optical response and excellent non-linear optical properties make it a wonderful material for developing next generation photonic and optoelectronic devices. The fabrication of graphene-based devices is compatible with the existing semiconductor process, which has stimulated lots of graphene-based hybrid silicon-CMOS ( Complementary metal-oxide-semiconductor transistor) applications. Here we review the latest progress in graphene-based photonic and optoelectronic devices, ranging from pulsed lasers, modulators and photodetectors to optical sensors. Other exciting topics such as graphene surface plas-mons and their terahertz applications are also discussed.

参考文献

[1]	Novoselov K S;Geim A K;Morozov S et al.Electric field effect in atomically thin carbon films[J].SCIENCE,2004,306(5696):666-669.
[2]	Changgu Lee;Xiaoding Wei;Jeffrey W. Kysar;James Hone .Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene[J].Science,2008(5887):385-388.
[3]	Nair RR;Blake P;Grigorenko AN;Novoselov KS;Booth TJ;Stauber T;Peres NM;Geim AK .Fine structure constant defines visual transparency of graphene.[J].Science,2008(5881):1308-1308.
[4]	Qiaoliang Bao;Han Zhang;Yu Wang;Zhenhua Ni;Yongli Yan;Ze Xiang Shen;Kian Ping Loh;Ding Yuan Tang .Atomic-Layer Graphene as a Saturable Absorber for Ultrafast Pulsed Lasers[J].Advanced functional materials,2009(19):3077-3083.
[5]	Fengnian Xia;Thomas Mueller;Yu-ming Lin;Alberto Valdes-Garcia;Phaedon Avouris .Ultrafast graphene photodetector[J].Nature nanotechnology,2009(12):839-843.
[6]	Ming Liu;Xiaobo Yin;Erick Ulin-Avila;Baisong Geng;Thomas Zentgraf;Long Ju;Feng Wang;Xiang Zhang .A graphene-based broadband optical modulator[J].Nature,2011(Jun.2 TN.7349):64-67.
[7]	Jianing Chen;Michela Badioli;Pablo Alonso-Gonzalez;Sukosin Thongrattanasiri;Florian Huth;Johann Osmond;Marko Spasenovic;Alba Centeno;Amaia Pesquera;Philippe Godignon;Amaia Zurutuza Elorza;Nicolas Camara;F.Javier Garcia de Abajo;Rainer Hillenbrand;Frank H.L.Koppens .Optical nano-imaging of gate-tunable graphene plasmons[J].Nature,2012(Jul.5 TN.7405):77-81.
[8]	Z.Fei;A.S.Rodin;G.O.Andreev;W.Bao;A.S.McLeod;M.Wagner;L.M.Zhang;Z.Zhao;M.Thiemens;G.Dominguez;M.M.Fogler;A.H.Castro Neto;C.N.Lau;F.Keilmann;D.N.Basov .Gate-tuning of graphene plasmons revealed by infrared nano-imaging[J].Nature,2012(Jul.5 TN.7405):82-85.
[9]	Castro Neto, AH;Guinea, F;Peres, NMR;Novoselov, KS;Geim, AK .The electronic properties of graphene[J].Reviews of Modern Physics,2009(1):109-162.
[10]	Mikhailov SA;Ziegler K .New electromagnetic mode in graphene[J].Physical review letters,2007(1):6803-1-6803-4-0.
[11]	Sun Z;Popa D;Hasan T et al.A stable,wideband tunable,near transform-limited,graphene-mode-locked,ultrafast laser[J].Nano Research,2010,3(09):653-660.
[12]	Yong-Won Song;Sung-Yeon Jang;Won-Suk Han;Mi-Kyung Bae .Graphene mode-lockers for fiber lasers functioned with evanescent field interaction[J].Applied physics letters,2010(5):051122-1-051122-3.
[13]	Choi S Y;Cho D K;Song Y W et al.Graphene-filled hollow optical fiber saturable absorber for efficient soliton fiber laser mode-locking[J].Optics Express,2012,20(05):5652-5657.
[14]	Lin Y H;Yang C Y;Liou J H et al.Using graphenenano-par-ticle embedded in photonic crystal fiber for evanescent wave mode-locking of fiber laser[J].Optics Express,2013,21(14):16763-16776.
[15]	Bao Q;Zhang H;Ni Z et al.Monolayer graphene as a satura-ble absorber in a mode-locked laser[J].Nano Research,2011,4(03):297-307.
[16]	Graphene-Polymer Nanofiber Membrane for Ultrafast Photonics[J].Advanced functional materials,2010(5):782.
[17]	G. Sobon;J. Sotor;I. Pasternak;W. Strupinski;K. Krzempek;P. Kaczmarek;K. M. Abramski .Chirped pulse amplification of a femtosecond Er-doped fiber laser mode-locked by a graphene saturable absorber[J].Laser physics letters,2013(3):035104-1-035104-6.
[18]	B. V. Cunning;C. L. Brown;D. Kielpinski .Low-loss flake-graphene saturable absorber mirror for laser mode-locking at sub-200-fs pulse duration[J].Applied physics letters,2011(26):261109-1-261109-3.
[19]	Liu C;Ye C;Luo Z et al.High-energy passively Q-switched 2 μm Tm3+-doped double-clad fiber laser using graphene-oxide-deposited fiber taper[J].Optics Express,2013,21(01):204-209.
[20]	W. D. Tan;C. Y. Su;R. J. Knize;G. Q. Xie;L. J. Li;D. Y. Tang .Mode locking of ceramic Nd:yttrium aluminum garnet with graphene as a saturable absorber[J].Applied physics letters,2010(3):031106-1-031106-3.
[21]	Jin-Long Xu;Xian-Lei Li;Yong-Zhong Wu;Xiao-Peng Hao;Jing-Liang He;Ke-Jian Yang .Graphene saturable absorber mirror for ultra-fast-pulse solid-state laser[J].Optics Letters,2011(10):1948-1950.
[22]	Cho W B;Kim J W;Lee H W .High-quality, large-area mon-olayer graphene for efficient bulk laser mode-locking near 1. 25μm[J].OPTICS LETTERS,2011,36(20):4089-4091.
[23]	Yu W J;Liu Y;Zhou H et al.Highly efficient gate-tunable photocurrent generation in vertical heterostructures of layered materials[J].Nature Nanotechnology,2013,8(12):952-958.
[24]	Zhao C;Zhang H;Qi X et al.Ultra-short pulse generation by a topological insulator based saturable absorber[J].Applied Physics Letters,2012,101:211106.
[25]	Liu, M.;Yin, X.;Zhang, X. .Double-layer graphene optical modulator[J].Nano letters,2012(3):1482-1485.
[26]	Kinam Kim;Jae-Young Choi;Taek Kim;Seong-Ho Cho;Hyun-Jong Chung .A role for graphene in silicon-based semiconductor devices[J].Nature,2011(Nov.19 TN.7373):338-344.
[27]	Lu, Z.;Zhao, W. .Nanoscale electro-optic modulators based on graphene-slot waveguides[J].Journal of the Optical Society of America, B. Optical Physics,2012(6):1490-1496.
[28]	Qiaoliang Bao;Kian Ping Loh .Graphene Photonics, Plasmonics, and Broadband Optoelectronic Devices[J].ACS nano,2012(5):3677-3694.
[29]	Midrio M;Boscolo S;Moresco M.Graphene-assisted critically-coupled optical ring modulator[J].Optics Express,2012:23144-23155.
[30]	Grigorenko, A.N.;Polini, M.;Novoselov, K.S. .Graphene plasmonics[J].Nature photonics,2012(11):749-758.
[31]	Ran Hao;Wei Du;Hongsheng Chen;Xiaofeng Jin;Longzhi Yang;Erping Li .Ultra-compact optical modulator by graphene induced electro-refraction effect[J].Applied physics letters,2013(6):061116-1-061116-4.
[32]	Lee C C;Suzuki S;Xie W et al.Broadband graphene electro-optic modulators with sub-wavelength thickness[J].Optics Ex-press,2012,20(05):5264-5269.
[33]	Polat, E.O.;Kocabas, C. .Broadband optical modulators based on graphene supercapacitors[J].Nano letters,2013(12):5851-5857.
[34]	Sensale-Rodriguez B;Yan R S;Kelly M M et al.Broadband graphene terahertz modulators enabled by intraband transitions[J].Nat Commun,2012,3:780.
[35]	Sensale-Rodriguez B;Yan R S;Rafique S et al.Extraordinary control of terahertz beam reflectance in graphene electro-absorp-tion Mmodulators[J].Nano Letters,2012,12(09):4518-4522.
[36]	Berardi Sensale-Rodriguez;Rusen Yan;Mingda Zhu;Debdeep Jena;Lei Liu;Huili Grace Xing .Efficient terahertz electro-absorption modulation employing graphene plasmonic structures[J].Applied physics letters,2012(26):261115-1-261115-3.
[37]	T. Mueller;F. Xia;M. Freitag;J. Tsang;Ph. Avourist .Role of contacts in graphene transistors: A scanning photocurrent study[J].Physical review, B. Condensed matter and materials physics,2009(24):245430:1-245430:6.
[38]	Thomas Mueller;Fengnian Xia;Phaedon Avouris .Graphene photodetectors for high-speed optical communications[J].Nature photonics,2010(5):297-301.
[39]	Liu Y;Cheng R;Liao L et al.Plasmon resonance enhanced multicolour photodetection by graphene[J].Nat Commun,2011,2:579.
[40]	Fang, Z.;Liu, Z.;Wang, Y.;Ajayan, P.M.;Nordlander, P.;Halas, N.J. .Graphene-antenna sandwich photodetector[J].Nano letters,2012(7):3808-3813.
[41]	Engel M;Steiner M;Lombardo A et al.Light-matter interac-tion in a microcavity-controlled graphene transistor[J].Nat Commun,2012,3:906.
[42]	Furchi, M.;Urich, A.;Pospischil, A.;Lilley, G.;Unterrainer, K.;Detz, H.;Klang, P.;Andrews, A.M.;Schrenk, W.;Strasser, G.;Mueller, T. .Microcavity-integrated graphene photodetector[J].Nano letters,2012(6):2773-2777.
[43]	Pospischil, A.;Humer, M.;Furchi, M.M.;Bachmann, D.;Guider, R.;Fromherz, T.;Mueller, T. .CMOS-compatible graphene photodetector covering all optical communication bands[J].Nature photonics,2013(11):892-896.
[44]	Wang, X.;Cheng, Z.;Xu, K.;Tsang, H.K.;Xu, J.-B. .High-responsivity graphene/silicon-heterostructure waveguide photodetectors[J].Nature photonics,2013(11):888-891.
[45]	Gan, X.;Shiue, R.-J.;Gao, Y.;Meric, I.;Heinz, T.F.;Shepard, K.;Hone, J.;Assefa, S.;Englund, D. .Chip-integrated ultrafast graphene photodetector with high responsivity[J].Nature photonics,2013(11):883-887.
[46]	L. Britnelt;R. M. Ribeiro;A. Eckmann;R. Jalil;B. D. Belle;A. Mishchenko;Y.-J. Kim;R. V. Gorbachev;T. Georgiou;S. V. Morozov;A. N. Grigorenko;A. K. Geim;C. Casiraghi;A. H. Castro Neto;K. S. Novoselov .Strong Light-Matter Interactions in Heterostructures of Atomically Thin Films[J].Science,2013(Jun.14 TN.6138):1311-1314.
[47]	Roy, K.;Padmanabhan, M.;Goswami, S.;Sai, T.P.;Ramalingam, G.;Raghavan, S.;Ghosh, A. .Graphene-MoS 2 hybrid structures for multifunctional photoresponsive memory devices[J].Nature nanotechnology,2013(11):826-830.
[48]	Yu W J;Liu Y;Zhou H et al.Highly efficient gate-tunable photocurrent generation in vertical heterostructures of layered materials[J].Nature Nanotechnology,2013,8(12):952-958.
[49]	Hwang EH;Das Sarma S .Dielectric function, screening, and plasmons in two-dimensional graphene[J].Physical review, B. Condensed matter and materials physics,2007(20):5418-1-5418-6-0.
[50]	Ju, Long;Geng, Baisong;Horng, Jason;Girit, Caglar;Martin, Michael;Hao, Zhao;Bechtel, Hans A;Liang, Xiaogan;Zettl, Alex;Shen, Y. Ron;Wang, Feng .Graphene plasmonics for tunable terahertz metamaterials[J].Nature nanotechnology,2011(10):630-634.
[51]	Yan, H.;Li, X.;Chandra, B.;Tulevski, G.;Wu, Y.;Freitag, M.;Zhu, W.;Avouris, P.;Xia, F. .Tunable infrared plasmonic devices using graphene/insulator stacks[J].Nature nanotechnology,2012(5):330-334.
[52]	Fei, Z.;Andreev, G.O.;Bao, W.;Zhang, L.M.;S. McLeod, A.;Wang, C.;Stewart, M.K.;Zhao, Z.;Dominguez, G.;Thiemens, M.;Fogler, M.M.;Tauber, M.J.;Castro-Neto, A.H.;Lau, C.N.;Keilmann, F.;Basov, D.N. .Infrared nanoscopy of dirac plasmons at the graphene-SiO_2 interface[J].Nano letters,2011(11):4701-4705.
[53]	Fei, Z.;Rodin, A.S.;Gannett, W.;Dai, S.;Regan, W.;Wagner, M.;Liu, M.K.;McLeod, A.S.;Dominguez, G.;Thiemens, M.;Castro Neto, A.H.;Keilmann, F.;Zettl, A.;Hillenbrand, R.;Fogler, M.M.;Basov, D.N. .Electronic and plasmonic phenomena at graphene grain boundaries[J].Nature nanotechnology,2013(11):821-825.
[54]	Popov, V.V.;Polischuk, O.V.;Davoyan, A.R.;Ryzhii, V.;Otsuji, T.;Shur, M.S. .Plasmonic terahertz lasing in an array of graphene nanocavities[J].Physical review, B. Condensed matter and materials physics,2012(19):195437-1-195437-6.
[55]	Tamagnone M;Gómez-Díaz J S;Mosig J R et al.Reconfigu-rable terahertz plasmonic antenna concept using a graphene stack[J].Applied Physics Letters,2012,101:214102.
[56]	Ashkan Vakil;Nader Engheta .Transformation Optics Using Graphene[J].Science,2011(Jun.10 TN.6035):1291-1294.
[57]	Christensen, J.;Manjavacas, A.;Thongrattanasiri, S.;Koppens, F.H.L.;García De Abajo, F.J. .Graphene plasmon waveguiding and hybridization in individual and paired nanoribbons[J].ACS nano,2012(1):431-440.
[58]	Bao, Q.;Zhang, H.;Wang, B.;Ni, Z.;Lim, C.H.Y.X.;Wang, Y.;Tang, D.Y.;Loh, K.P. .Broadband graphene polarizer[J].Nature photonics,2011(7):411-415.
[59]	Wu, J.;Agrawal, M.;Becerril, H.A.;Bao, Z.;Liu, Z.;Chen, Y.;Peumans, P. .Organic light-emitting diodes on solution-processed graphene transparent electrodes[J].ACS nano,2010(1):43-48.
[60]	T. Sun;Z. L. Wang;Z. J. Shi;G. Z. Ran;W. J. Xu;Z. Y. Wang;Y. Z. Li;L. Dai;G. G. Qin .Multilayered graphene used as anode of organic light emitting devices[J].Applied physics letters,2010(13):133301-1-133301-3.
[61]	Han, T.-H.;Lee, Y.;Choi, M.-R.;Woo, S.-H.;Bae, S.-H.;Hong, B.H.;Ahn, J.-H.;Lee, T.-W. .Extremely efficient flexible organic light-emitting diodes with modified graphene anode[J].Nature photonics,2012(2):105-110.

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