采用溶液-浇铸法用商业化Nafion膜的溶解液制备再铸Nafion膜,对再铸Nafion膜进行了氧气渗透系数测试和电池性能评价,并与厚度相近的商业化Nafion膜进行比较,同时对再铸Nafion膜组装的PEMFC进行了短期稳定性考查.实验结果表明:通过溶液-浇铸法制备的再铸Nafion膜可以应用于质子交换膜燃料电池;再铸Nafion膜的氧气渗透系数和电池性能与商业化Nafion膜相近;再铸Nafion膜组装PEMFC在150 h之内未见电池性能下降.
参考文献
| [1] | 衣宝廉.燃料电池--高效、环境友好的发电方式[M].北京:化学工业出版社,2000 |
| [2] | Ralph T R .Proton cxchange membrane fuel cells[J].Platinum Metals Review,1997,41(03):102-113. |
| [3] | PRATER K .The renaissance of the solid polymer fuel cell[J].Journal of Power Sources,1990,29:239-250. |
| [4] | Prater K B .Polymer electrolyte fuel cells a review of recent developments[J].Journal of Power Sources,1994,51:129-144. |
| [5] | SAVADOGO O .Emerging membranes for electrochemical systems(I)solid polymer electrolyte membrancs for fuel cell systems[J].Journal of New Materials for Electrochemical Systems,1998,1(01):47-66. |
| [6] | 黄倬;屠海令;张翼强.质子交换膜燃料电池的研究开发与应用[M].北京:冶金工业出版社,2000:34-35. |
| [7] | Martin C R;Rhoades T A;Ferguson J A .Dissolution of perfluorinated ion containing polymers[J].Analytical Chemistry,1982,54:1639-1641. |
| [8] | Moore R B Ⅲ;Martin C R .Procedure for preparing solution-cast perfluorosulfonate ionomer films and membranes[J].Analytical Chemistry,1986,58(12):2569-2570. |
| [9] | Moore R B Ⅲ;Martin C R .Chemical and morphological properties of solution-cast perfluorosulfonate ionomers[J].MACROMOLECULES,1988,21:1334-1339. |
| [10] | Gebel G;Aldebert P;Pineri M .Strcture and related properties of solution-cast perfluorosulfonated ionomer films[J].Macromolecules,1987,20:1425-1428. |
| [11] | YOSHITAKE M;Tamura M;Yoshida N et al.Studies of perfluorinated ion exchange membrane for polymer electrolyte fuel cells[J].Denki Kagaku Kogyo Kabushiki Kaisha,1996,64(06):727-736. |
| [12] | Raistrick I D .Electrode assembly for use in a solid polymer electrolyte fuel cell[P].US:4876115,1989. |
| [13] | 于景荣,衣宝廉,韩明,邵志刚,程晓亮.高功率密度质子交换膜燃料电池研究[J].电源技术,2000(03):131-134. |
| [14] | WAKIZOE M;Velev O A;Srinivasan S .Analysis of proton exchange membrane fuel cell performance with alternate membranes[J].Electrochimica Acta,1995,40(03):335-344. |
| [15] | 贺高红;徐仁贤;朱葆琳.膜分离过程.中国科学院研究生教材[M].中国科学院研究生教材,1995:53-54. |
| [16] | MURPHY O J;Hitchens G D;Manko D J .High power density proton exchange menbrane fuel cells[J].Journal of Power Sources,1994,47:353-368. |
| [17] | TICIANELLI E A;Derounin C R;Redono A et al.Methods to advance technology of proton exchange membrane fuel cells[J].Journal of the Electrochemical Society,1988,135:2209-2214. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%