针对磺化聚砜质子交换膜用于PEMFC,研究了它的物理化学性能和电化学性能,实验结果表明:与Nafion膜相比,磺化聚砜(EW=900)作为质子交换膜材料,具有较好的热稳定性、水化性能和尺寸稳定性,溶液浇铸法制得的磺化聚砜膜在机械强度、气体渗透性能方面与Nafion膜相近,用磺化聚砜膜组装的PEMFC的电池性能与Nafion膜相比存在一定的差距,但从电池运行稳定性来看,还是有希望用于质子交换膜燃料电池的.
参考文献
[1] | SAVADOGO O .Emerging membrane for electrochemical systems (1) solid polymer electrolyte membranes for fuel cell systems[J].New Materials for Electrochemical Systems,1998,1(01):47-66. |
[2] | Prater K B .Polymer electrolyte fuel cells:A review of recent developments[J].Journal of Power Sources,1994,51:129-144. |
[3] | 蔡年生 .质子交换膜在燃料电池中的应用[J].膜科学与技术,1996,16(04):1-6. |
[4] | Doughty D H;Nazar L F.New materials for batteries and fuel cells[A].,2000:253-279. |
[5] | Li Qingfeng;Hans A. Hjuler;Niels J. Bjerrum.Polymer Electrolyte Membranes for Advanced Fuel Cells Using Impure Hydrogen[A].北京,2000:723-728. |
[6] | Scherer G G .Polymer membranes for fuel cells[J].Berichte der Bunsen Gesellschaft physical Chemistry Chemical Physics,1990,94:1008-1014. |
[7] | Jochen A. Kerres .Development of ionomer membranes for fuel cells[J].Journal of Membrane Science,2001(1):3-27. |
[8] | K.D. Krueuer .On the development of proton conducting polymer membranes for hydrogen and methanol fuel cells[J].Journal of Membrane Science,2001(1):29-39. |
[9] | Deborah J. Jones;Jacques Roziere .Recent advances in the functionalisation of polybenzimidazole and polyetherketone for fuel cell applications[J].Journal of Membrane Science,2001(1):41-58. |
[10] | Lufrano F.;Patti A.;Passalacqua E.;Squadrito G. .Sulfonated polysulfone as promising membranes for polymer electrolyte fuel cells[J].Journal of Applied Polymer Science,2000(6):1250-1256. |
[11] | Juana Benavente;Jose M. Garcia;Robert Riley .Sulfonated poly(ether ether sulfones) Characterization and study of dielectrical properties by impedance spectroscopy[J].Journal of Membrane Science,2000(1):43-52. |
[12] | Guo Qunhui;Tang Hao;O'Connor Sally;Pintauro Peter N. .Sulfonated and crosslinked polyphosphazene-based proton-exchange membranes[J].Journal of Membrane Science,1999(2):175-181. |
[13] | Hinatsu J T;Mizuhata M;Takenaka H .Water uptake of perfluorosulfonic acid membranes from liquid water and water vapor[J].Journal of the Electrochemical Society:Electrochemical Science and Technology,1994,141(06):1493-1498. |
[14] | Noshay A;Robeson L M .Sulfonated polysulfone[J].Journal of Applied Polymer Science,1976,20:1885-1903. |
[15] | Pourcelly G;Oikonomou A;Gavach C et al.Influence of the water content the kinetics of counter-ion transport in perfluorosulphonic membranes[J].Journal of Electroanalytical Chemistry,1990,287:43-59. |
[16] | Zawodzinski T A Jr;Derouin C et al.Water uptake by and transport through Nafion117 membranes[J].Journal of the Electrochemical Society:Electrochemical Science and Technology,1993,140:1041-1047. |
[17] | Sakai T;Takenaka H;Torikai E .Gas diffusion in the dried and hydrated Nafions[J].Journal of the Electrochemical Society:Electrochemical Science and Technology,1986,133(01):88-92. |
[18] | Savadogo O.Status on the development of membranes for polyemr electrolyte fuel cells(PEMFCs)[A].北京,2000:756-764. |
[19] | WAKIZOE M;Velev O A;Srinivasan S .Analysis of proton exchange membrane fuel cell performance with alternate membranes[J].Electrochimica Acta,1995,40(03):335-344. |
[20] | MURPHY O J;Hitchens G D;Manko D J .High power density proton-exchange membrane fuel cells[J].Journal of Power Sources,1994,47:353-368. |
[21] | TICIANELLI E A;Derounin C R;Redondo A et al.Methods to advance technology of proton exchange membrane fuel cells[J].Journal of the Electrochemical Society:Electrochemical Science and Technology,1988,135:2209-2214. |
[22] | Kopitzke R W;Linkous C A;Anderson H R et al.Conductivity and water uptake of aromatic-besed proton exchange membrane electrolytes[J].Journal of the Electrochemical Society:Electrochemical Science and Technology,2000,147:1677-1681. |
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