以聚二甲基硅烷为分离膜材料,正庚烷为溶剂,正硅酸乙酯为交联剂,二桂酸二丁基锡为催化剂,聚四氟乙烯膜为基膜,制得聚二甲基硅氧烷/聚四氟乙烯复合膜,用于脱蜡润滑油与溶剂(甲苯和丁酮)的分离.研究了溶液配方、硫化温度、硫化时间等因素对膜性能的影响.在操作压力2.0 MPa,溶液温度20 ℃,进料溶剂质量分数85%条件下,膜对油的截留率为84%,通量为4.8 kg/(m2*h).
参考文献
[1] | Wernick D L;Elizabeth N J .Preparation cellulose acetate membrane and its use for polar sol ent-oil separation[P].US:4678555,1987. |
[2] | GOULD R M;Klocewski H A;Menon K S et al.Lubricating oil dewaxing with membrane separation[P].US 5651877,1997. |
[3] | Pasternak M;Spring alley N Y .Process for treating a charge containing dewaxing sol ent and dewaxed oil[P].US:4985138,1991. |
[4] | 毛丰吉;刘中大 .酮苯脱蜡装置挖潜增效可采用的措施[J].石油炼制与化工,1999,30(09):23-27. |
[5] | 姜忠义,徐海全,刘家祺.填充碳分子筛的PDMS膜渗透蒸发分离性能研究[J].膜科学与技术,2001(02):29-32,69. |
[6] | an Deemter J J;Zuiderweg F J;Klinkenberg A .Longitudinal diffusion and resistance to masstransfer as causes of nonideality in chromatography[J].Chemical Engineering,1956,5:271-274. |
[7] | Smidsrod O;Guillet J E .Study of polymer-polymer-solute interactions by gas chromatography[J].Macromolecules,1969,2(03):272-277. |
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