针对目前陶瓷膜工程设计偏重工艺参数设计所存在的问题,分析了陶瓷膜材料微结构特性对膜过程影响的重要性,提出了目前以工艺为主的陶瓷膜工程设计向以膜微结构参数为主设计转变的新思路.在前期工作的基础上,建立了胶体体系过滤的陶瓷膜性能与微结构关系模型,并结合工程应用实例就膜材料微结构设计方法进行探索,在颗粒悬浮液、中药水提液、乳化废水等工程应用中得到了很好地实施,理论计算和工程应用结果表明,微结构优化设计的陶瓷膜具有更好的分离性能.陶瓷膜工程设计方法从工艺到微结构的转变为陶瓷膜应用提供了新的模式.
参考文献
| [1] | 徐南平.无机膜的发展现状与展望[J].化工进展,2000(04):5-9. |
| [2] | Franken T.Membrane selection-more than material properties alone[J].Membrane Technology,1998:7-10. |
| [3] | Trettin D R;Doshi M R .Limiting flux in ultrafiltration of macromolecular solutions[J].Chemical Engineering Communications,1980,4:507-522. |
| [4] | Drew D A;Schonberg J A;Belfort G .Lateral inertial migration of a small sphere in fast laminar flow through a membrane duct[J].Chemical Engineering Science,1991,46:3219-3224. |
| [5] | Romero C A;Davis R H .Experimental verification of the shear-induced hydrodynamic diffusion model of crossflow microfiltration[J].Journal of Membrane Science,1991,62:249-273. |
| [6] | Davis R H;Birdsell S A .Hydrodynamic model and experiments for cross-flow microfiltration[J].Chemical Engineering Communications,1987,49:217-234. |
| [7] | 徐南平,李卫星,赵宜江,邢卫红,时钧.面向过程的陶瓷膜材料设计理论与方法（Ⅰ）膜性能与微观结构关系模型的建立[J].化工学报,2003(09):1284-1289. |
| [8] | 李卫星,赵宜江,刘飞,邢卫红,徐南平,时钧.面向过程的陶瓷膜材料设计理论与方法（Ⅱ）颗粒体系微滤过程中膜结构参数影响预测[J].化工学报,2003(09):1290-1294. |
| [9] | 赵宜江,李卫星,张伟,邢卫红,徐南平,时钧.面向过程的陶瓷膜材料设计理论与方法（Ⅲ）钛白分离用陶瓷膜的优化设计与制备[J].化工学报,2003(09):1295-1299. |
| [10] | Gebauer K H;Thommes J;Kula M R .Breakthrough performance of high-capacity membrane adsorbers in protein chromatography[J].Chemical Engineering Science,1996,52:405-419. |
| [11] | Vernhet A;Bellon-Fontaine M N;Brillouet J M et al.Wetting properties of the capillary rise technique and incidence on the adsorption of wine polysaccharide and tannins[J].Journal of Membrane Science,1997,128:164-174. |
| [12] | Reichert U.;Linden T.;Belfort G.;Kula MR.;Thommes J. .Visualising protein adsorption to ion-exchange membranes by confocal microscopy[J].Journal of Membrane Science,2002(1/2):161-166. |
| [13] | Nakamura K.;Matsumoto K. .Adsorption behavior of BSA in microfiltration with porous glass membrane[J].Journal of Membrane Science,1998(1):119-128. |
| [14] | Gekas V;Aimar P;Lafaille J P et al.A simulation study of the adsorption-concentration polarization interplay in protein ultrafiltration[J].Chemical Engineering Science,1993,48(15):2754-2765. |
| [15] | Ruizbevia F.;Fernandezsempere J.;Fernandeztorres MJ.;Gomisyagues V. .AN IMPROVED MODEL WITH TIME-DEPENDENT ADSORPTION FOR SIMULATING PROTEIN ULTRAFILTRATION[J].Chemical Engineering Science,1997(14):2343-2352. |
| [16] | 徐南平;范益群;向柠 .无机膜集成技术超细粉体的制备方法[P].CN 00119077.6,2003. |
| [17] | 沈晓林;杨晶.超滤技术处理轧钢含油废水[J].冶金环境保护,2002(02):29-31. |
| [18] | Sang H.Hyun... .Synthesis of ceramic microfiltration membranes for oil/water separation[J].Separation Science and Technology,1997(18):2927-2943. |
| [19] | Villarroel L R;Elmaleh S;Ghaffor N .Cross-flow ultra-filtration of hydrocarbon emulsion[J].Journal of Membrane Science,1995,102:55-64. |
| [20] | Chen Abraham S.C.;Ferguson David;Stencel Nicholas .Using ceramic membranes to recycle two nonionic alkaline metal-cleaning solutions[J].Journal of Membrane Science,1999(1):219-234. |
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