基于Nernst-Planck方程建立了EDI过程的传质动力学微分方程.根据此传质模型方程获知,EDI过程中在阴阳离子交换膜/树脂表面与溶液接触的界面层中发生的水解离的差异性,是在于离子交换界面电势梯度的差异,而这种差异又与膜和树脂的结构、性能以及阴阳离子在水溶液中的迁移数的差异有关.
参考文献
[1] | Burns G;Glueckauf E.Second United Nations Conference on Peaceful Uses of Atomic Energy[C].,1958:308. |
[2] | Gluekauf E;Sc M;Sc D.Electro-deionisation through a packed bed[J].British Chemical Engineering,1959(12):646-651. |
[3] | Sammon D C;Watts R E .An experimental study of electrodeionization and it's application to the treatment of radioactive wastes (June,1960)[Z].Rep UK'Atom Energy Auth |
[4] | Gittens G J;Watts R E .Some experimental studies of electrodeionization through resin packed beds (March,1964)[Z].Rep UK Atom Energy Auth |
[5] | Ganzi G C;Egozy Y;Giuffrida A J .High purity water by electrodeionization:performance of the Ionpure continuous deionization systems[J].Ultrapure Water,1987,4(03):43-50. |
[6] | Ganzi G C .Electrodeionization for high purity water production[J].AICHE Symposium Series,1988,84(261):73-83. |
[7] | Helfferich F G.Ion exchange[M].New York:McGraw-Hill Book Company,1962:250-322. |
[8] | Gluekauf E;Sc M;Sc D.Electro-deionisation through a packed bed[J].British Chemical Engineering,1959(12):646-651. |
[9] | Ganzi G C.IonpureTM CDI electrodeionization systems.New product and process development for high purity water production[A].,1991:317. |
[10] | IP Holding Corporation .Electrodeionization apparatus[P].US 5308466,1994-05-03. |
[11] | Elyanow I D;Mcrae W A;Sims K J .Ionics Incorporated.Electrodialysis including filled cell electrodialysis (electrodeionization)[P].US 5679228,1997-10-21. |
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