欢迎登录材料期刊网

材料期刊网

高级检索

质子交换膜作为燃料电池和液流电池的关键材料之一,近二十年来得到世界各国科学家的广泛关注和深入研究,先后研究开发出含氟高分子类、碳氢聚合物类、芳香烃聚合物类,以及有机/无机杂化材料的质子交换膜.在总结归纳这一领域的研究成果基础上,结合本课题组在液流电池领域的质子交换膜研究进展,论述质子交换膜技术在新能源技术领域未来若干年的研究开发重大需求,展望质子交换膜材料设计与可能的绿色合成技术路线.

Proton exchange membranes regarded as a key materials in the processes of developing fuel cell and flow battery have obtained widely attention and extensive study during last two decades, many sorts of mem-branes were proposed in the world, such as fluorinated polymer, aromatic backbone and organic/inorganic hy-results of proton conductive membrane for flow battery in our group, this paper clarifies the potential demand of proton exchange membrane in the renewable energy market in the future, and gives a perspective in developing proton exchange membranes with environmental friendly approaches.

参考文献

[1] Ostwald W .Elektrische Eigenschaften halbdurchlassiger Scheidewande[J].Zeitschrift für Physikalische Chemie,1890,6:71-82.
[2] Donnan F G .The theory of membrane equilibrium in oresence of a non-dialyzable electrolyte[J].Zeitschrift Fur Elektrochemie,1911,17:572-581.
[3] 徐铜文;黄川徽.离子交换膜技术及其应用[M].北京:化学工业出版社,2008
[4] Devanathan R .Recent developments in proton exchange membranes for fuel cells[J].Energy Environmental Science,2008,1(01):101-119.
[5] Hamrock SJ;Yandrasits MA .Proton exchange membranes for fuel cell applications[J].Polymer reviews,2006(3):219-244.
[6] Smitha B;Sridhar S;Khan AA .Solid polymer electrolyte membranes for fuel cell applications - a review[J].Journal of Membrane Science,2005(1/2):10-26.
[7] 黄倬;屠海令;张冀强.质子交换膜燃料电池的研究开发与应用[M].北京:冶金工业出版社,2000
[8] Savadogo O .Emerging membranes for electrochernical systems (Ⅰ) Solid polymer electrolyte membranes for fuel cell systems[J].Journal of New Materials for Electrochemical Systems,1998,1:47-66.
[9] Yu JR.;Yi BL.;Xing DM.;Liu FQ.;Shao ZG.;Fu YZ. .Degradation mechanism of polystyrene sulfonic acid membrane and application of its composite membranes in fuel cells[J].Physical chemistry chemical physics: PCCP,2003(3):611-615.
[10] Yang C;Srinivasan S;Arico A S et al.Composite nafion/zirconium phosphate membranes for direct methanol fuel cell operation at high temperature[J].Electrochemical and Solid-State Letters,2001,4(04):A31-A34.
[11] Peled E;Duvdevani T;Aharon A et al.A direct methanol fuel cell based on a novel low-cost nanoporous proton-oonduaing membrane[J].Electrochemical and Solid-State Letters,2000,3:525-528.
[12] Liu BJ;Robertson GP;Kim DS;Guiver MD;Hu W;Jiang ZH .Aromatic poly(ether ketone)s with pendant sulfonic acid phenyl groups prepared by a mild sulfonation method for proton exchange membranes[J].Macromolecules,2007(6):1934-1944.
[13] Rychak M;Skyllas-Kazacos M .Characteristics of a new all-vanadium redox flow battery[J].Journal of Power Sources,1988,22(01):59-67.
[14] Zhao P;Zhang H M;Zhou H T et al.Charactetistics and performance of 10 kW class all-vanadium redox-flow battery stack[J].Journal of Power Sources,2006,162(02):1 416-1 420.
[15] Mohammadi T;Skyllas-Kazacos M .Evaluation of the chemical stability of some membranes m vanadium solution[J].Journal of Applied Electrochemistry,1997,27:153-158.
[16] Vafiadis H;Skyllas-Kazacos M .Evaluation of membranes for the novel vanadium bromine redox flow cell[J].Journal of Membrane Science,2006(1/2):394-402.
[17] Xi JY;Wu ZH;Teng XG;Zhao YT;Chen LQ;Qiu XP .Self-assembled polyelectrolyte multilayer modified Nafion membrane with suppressed vanadium ion crossover for vanadium redox flow batteries[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2008(11):1232-1238.
[18] 滕祥国,赵永涛,席靖宇,武增华,邱新平,陈立泉.全钒氧化还原液流电池用Nafion/有机硅复合膜[J].化学学报,2009(06):471-476.
[19] 宋文生,李磊,王宇新,许莉.磺化聚醚醚酮与聚砜共混膜导电与传质特性研究[J].膜科学与技术,2004(03):15-19.
[20] 刘晨光,钟双玲,赵成吉,那辉,吴忠文.不同侧基对磺化聚醚醚酮质子交换膜的影响[J].吉林大学学报(理学版),2006(01):101-104.
[21] 任素贞,孙公权,吴智谋,李辰楠,金巍,辛勤,杨学锋.磺化聚醚醚酮/聚偏氟乙烯共混膜的研究[J].电源技术,2006(03):200-202.
[22] T. Mohammadi;M. Skyllas-Kazacos .Preparation of sulfonated composite membrane for vanadium redox flow battery applications[J].Journal of Membrane Science,1995(1/2):35-45.
[23] Gab-Jin Hwang;H. Ohya .Preparation of cation exchange membrane as a separator for the all-vanadium redox flow battery[J].Journal of Membrane Science,1996(1):55-67.
[24] Mohammadi T.;Skyllaskazacos M. .CHARACTERISATION OF NOVEL COMPOSITE MEMBRANE FOR REDOX FLOW BATTERY APPLICATIONS[J].Journal of Membrane Science,1995(1/2):77-87.
[25] Mohammadi T.;Kazacos MS.;Chieng SC. .WATER TRANSPORT STUDY ACROSS COMMERCIAL ION EXCHANGE MEMBRANES IN THE VANADIUM REDOX FLOW BATTERY[J].Journal of Membrane Science,1997(2):151-159.
[26] Theresa Sukkar;Maria Skyllas-Kazacos .Modification of membranes using polyelectrolytes to improve water transfer properties in the vanadium redox battery[J].Journal of Membrane Science,2003(1/2):249-264.
[27] Tian B;Yan C W;Wang F H .Proton conducting compcsite membrane from Daramic/Nafion for vanadium redox flow battery[J].Journal of Membrane Science,2004,234(1-2):51-54.
[28] Tian B;Yan CW;Wang FH .Modification and evaluation of membranes for vanadium redox battery applications[J].Journal of Applied Electrochemistry,2004(12):1205-1210.
[29] Luo QT;Zhang HM;Chen J;Qian P;Zhai YF .Modification of Nafion membrane using interfacial polymerization for vanadium redox flow battery applications[J].Journal of Membrane Science,2008(1/2):98-103.
[30] Erdogan T;Unveren E E;Inan T Y et al.Well-defined block copolymer ionomers and their blend membranes for proton exchange membrane fuel cell[J].Journal of Membrane Science,2009,344(1-2):172-181.
[31] Qiu J Y;Zhai M L;Chen J H et al.Performance of vanadium redox flow battery with a novel amphoteric ion exchange membrane synthesized by two-step grafting method[J].Journal of Membrane Science,2009,342(1-2):215-220.
[32] Preparation of PVdF/PSSA composite membranes using supercritical carbon dioxide for direct methanol fuel cells[J].International journal of hydrogen energy,2009(15):6437.
[33] Zhang ZC;Chalkova E;Fedkin M;Wang CM;Lvov SN;Komarneni S;Chung TCM .Synthesis and Characterization of Poly(vinylidene fluoride)-g-sulfonated Polystyrene Graft Copolymers for Proton Exchange Membrane[J].Macromolecules,2008(23):9130-9139.
[34] Chen JH;Asano M;Maekawa Y;Yoshida M .Suitability of some fluoropolymers used as base films for preparation of polymer electrolyte fuel cell membranes[J].Journal of Membrane Science,2006(1/2):249-257.
[35] Shao Y Y;Yin G P;Wang Z B et al.Proton exchange membrane fuel cell from low temperature to high temperature:Material challenges[J].Journal of Power Sources,2007,167(02):235-242.
[36] Schiraldi DA .Perfluorinated polymer electrolyte membrane durability[J].Polymer reviews,2006(3):315-327.
[37] Xu TW .Ion exchange membranes: State of their development and perspective[J].Journal of Membrane Science,2005(1/2):1-29.
[38] 王保国;龙飞;范永生 等.一种质子传导膜的制备方法[P].CN Pat:200910077024.6,2009-07-08.
[39] 王保国;青格乐图;刘平 等.一种聚离子液体的互穿网络型导电膜制备方法[P].CN Pat:200910088228,2009-12-30.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%