在40 Hz~10 MHz频率范围测量了纳滤膜在8种电解质溶液中的介电谱,发现了两个随电解质浓度而变化的弛豫,建立了由膜内支撑层和分离层以及溶液相构筑的三相体系介电模型,并利用严格的数值解析法计算了体系中各组成相的电参数,聚焦于10<'3>Hz左右因膜内层间界面极化而引起的低频弛豫,考察了两层电参数与电解质种类和浓度的关系,计算得到膜内各层的介电性质,并获得了关于不同电解质在膜内支撑层和分离层中的分布的信息.
参考文献
[1] | A.W.Mohammad;N.Hilal;H.Al-Zoubi .Modelling the effects of nanofiltration membrane properties on system cost assessment for desalination applications[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2007(1/3):215-225. |
[2] | Richard Bowen W;Julian S Welfoot .Modelling the per formance of membrane nanofihration-critical assessment and model development[J].Chemical Engineering Science,2002,57:1121-1137. |
[3] | Yaroshchuk A E;Makovetskiy A L;Boiko Y P et al.Non-steady-state membrane potential:theory and measurements by a novel technique to determine the ion transport numbers in active layers of nanofiltration membranes[J].Journal of Membrane Science,2000,172:203-221. |
[4] | B. Chaufer;M. Rabiller-Baudry;L. Guihard;G. Daufin .Retention of ions in nanofiltration at various ionic strength[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,1996(1/2):37-46. |
[5] | Schaep J;Van der Bruggen B;Vandecasteele C et al.Influence of ion size and charge in nanofiltration[J].Separation and Purification Technology,1998,14:155-162. |
[6] | J. M. M. Peeters;M. H. V. Mulder;H. Strathmann .Streaming potential measurements as a characterization method for nanofiltration membranes[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,1999(1/3):247-259. |
[7] | K.C.Khulbe;F.Hamad;C.Feng;T.Matsuura;M.Khayet .Study of the surface of the water treated cellulose acetate membrane by atomic force microscopy[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2004(3):259-262. |
[8] | Khayet M .Membrane surface modification and characterization by X-ray photoelectron spectroscopy, atomic force microscopy and contact angle measurements[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2004(1/4):269-272. |
[9] | Szymczyk A;Fatin-Rouge N;Fievet P .Tangential streaming potential as a tool in modeling of ion transport through nanoporous membranes[J].Journal of Colloid and Interface Science,2007(2):245-252. |
[10] | Shang WJ;Wang XL;Yu YX .Theoretical calculation on the membrane potential of charged porous membranes in 1-1, 1-2, 2-1 and 2-2 electrolyte solutions[J].Journal of Membrane Science,2006(1/2):362-375. |
[11] | Xu T W;Fu Y Q .Wang X L Membrane potential model for an asymmetrical nanofiltration membraneconsideration of noncontinuous concentration at the interface[J].Desalination,2004,171:155-165. |
[12] | Ernst Mathias;Bismarck Alexander .Zeta-potential and rejection rates of a polyethersulfone nanofiltration membrane in single salt solutions[J].Journal of Membrane Science,2000(2):251-259. |
[13] | Asami Koji .Characterization of heterogeneous systems by dielectric spectroseopy[J].Progress in Polymer Science,2002,27:1617-1659. |
[14] | 赵孔双.介电谱方法及其应用[M].北京:化学工业出版社,2008:59-101. |
[15] | Y.H.Li;K.S.Zhao .Dielectric analysis of nanofiltration membrane in electrolyte solutions:influences of electrolyte concentration and species on membrane permeation[J].Journal of Colloid and Interface Science,2004(1):68-76. |
[16] | Zhao K S;Li Y H .Dielectric characterization of a nanofihration membrane in electrolyte solutions:Its Double-Layer Structure and Ion Permeation[J].Journal of Physical Chemistry B,2006,110:2755-2763. |
[17] | Qing Lu;Kongshuang Zhao .Dielectric Spectroscopy of a Nanofiltration Membranes—Electrolyte Solution System: I. Low-Frequency Dielectric Relaxation from the Counterion Polarization in Pores and Model Development[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2010(50):16783-16791. |
[18] | Torben Smith Sorensen.Interfacial electrodynamics of membranes and polymer films[A].New York:623-747. |
[19] | Hanai T;Zhang H Z;Sekine K et al.The number of interfaces and the associated dielectric relaxations in heterogeneous systms[J].Ferroelectrics,1988,86:191-204. |
[20] | Kiyohara K;Zhao K S;Asaka K et al.Determination of capacitances and conductances of the constituent phases from dielectric observations on terlamellar composite systems[J].Japanese Journal of Applied Physics,1990,29(09):1751-1756. |
[21] | Asami K;Irimajiri A;Hanai T et al.A method for estimating residual inductance in high frequency A.C.Measurements[J].Bull Ist Chem Res Kyoto Univ,1973,51:231-245. |
[22] | Alexander Yu;Zasetsky et al.Svishchev.Dielectric response of concentrated naCl aqueous solutions:Molecular Dynamics Simulations[J].Journal of Chemical Physics,2001,115:1448-1454. |
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