在金属微粒催化的条件下探索了用直流电弧放电法制备内包金属纳米洋葱状富勒烯(Onionlike Fullerenes OLFs)的过程和工艺.用扫描电镜(SEM)和高分辨透射电镜(HRTEM)等实验手段对生成的OLFs进行了形貌、结构的观察和表征.研究结果表明:调整工艺参数,并辅以催化剂掺杂可大量制备内包金属的OLFs;对个别工艺参数的影响进行了探讨.
参考文献
[1] | Croto H W;Heath J R;O' Brien S C et al.C,0:buck-mingstedullerene[J].Nature,1985,318(01):162. |
[2] | Chai Y;GuoT;Jin CH et al.Fullerenes With Metals Inside[J].Journal of Physical Chemistry,1991(95):7564-7568. |
[3] | Majetich S A;Artman J O;Mcery M E et al.Preparation and properties of carbon-coated magnetic nanocrystallites[J].Physical Review B,1993,48:16845-16848. |
[4] | Brunsman E M;Sutton R;Bortz E et al.Magnetic properties of carbon-coated,ferromagnetic nanoparticles produced by a carbon-arc method[J].Journal of Applied Physics,1994,75:5882-5884. |
[5] | Xu B S;Tanaka S I .Pt cluster bonding and fullerene formation in HRTEM[J].Nanostructured Materials,1995,6:727. |
[6] | Xu B S;Tanaka S I .Formation of giant onion-like fullerenes under Al nanoparticles by electron irradiation[J].Acta Materialia,1998(46):5249. |
[7] | Iijima S .Helical Microtubules of Griphitic Carbon[J].Nature,1991,354:56-58. |
[8] | Shi ZJ.;Jin ZX.;Gu ZN.;Wang J.;Feng SQ.;Xu XL.;Liu ZQ.;Zhou XH. .HIGH YIELD SYNTHESIS AND GROWTH MECHANISM OF CARBON NANOTUBES[J].Solid State Communications,1996(5):371-375. |
[9] | 朱宏伟;吴德海;徐才录.碳纳米管[M].北京:机械工业出版社,2003 |
[10] | O'Reefe .[J].Chemical Physics,1987,111:327. |
[11] | Bethune D s;Johson R D;Salem J R et al.Atomsin carbon cages:the structure and properties of endohedralfullerenes[J].Nature,1993,366:123. |
[12] | 王志兴;李新海;李晶 等.电弧法制备富勒烯的条件[J].中南工业大学学报(自然科学版),1995,26:279. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%