{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"采用氯磺酸作为磺化试剂, 在多壁碳纳米管上接枝氯磺酰基, 之后通过乙二胺的胺解反应, 制备出胺基修饰的多壁碳纳米管MWCNT-NH2, 并进一步与氯磺酰基酞菁铜反应制备出MWCNT-Pc复合物. 产物采用红外光谱,紫外可见, 拉曼光谱, X射线光电子能谱, 循环伏安, 热重分析等进行了表征. 结果表明, MWCNT-NH2上磺酰胺基接枝在MWCNT表面, 而MWCNT-Pc上的酞菁基团是通过MWCNT-NH<sub>2</sub>上的酰胺基团与Pc形成复合物, 碳纳米管上约38个碳原子结合一个磺酸基酞菁分子; 该MWCNT-Pc复合物的热稳定性较MWCNT-NH2低; 利用喷涂法构筑了ITO/MWCNT-Pc光电极, 光电性能的研究结果表明在AM1.5光照条件下, 光电压及光电流分别为0.434V和0.158mA/cm<sup>2</sup>; 在320nm处的IPCE达19.8%, 具有较优良的光电转化性能. 根据测得的MWCNT-Pc的能带结构, 推知MWCNT-Pc的光诱导电子转移过程是Pc端基发生光激发电子跃迁, 此后电子转移到MWCNTs上并进一步传递到ITO, 完成电荷分离.","authors":[{"authorName":"吴振奕","id":"97236d19-30e7-4192-ae4e-ec65731e36a2","originalAuthorName":"吴振奕"},{"authorName":"<span style=\"color:red\">杨</span><span style=\"color:red\">绳</span><span style=\"color:red\">岩</span>","id":"c9eee897-86ee-4146-b008-0027f92e0b03","originalAuthorName":"杨绳岩"}],"categoryName":"|","doi":"10.3724/SP.J.1077.2011.00785","fpage":"785","id":"a8178810-01f7-4428-a1a6-db984925d9d7","issue":"8","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"1ce24a6a-0570-4b9e-93ea-cf4f9cf43acd","keyword":"多壁碳纳米管","originalKeyword":"多壁碳纳米管"},{"id":"6b1883c8-692d-497f-a806-5f0bdb399365","keyword":" copper phthalocyanine","originalKeyword":" copper phthalocyanine"},{"id":"89aa5f85-d839-45db-83f3-17c70c410580","keyword":" photoelectric property","originalKeyword":" photoelectric property"}],"language":"zh","publisherId":"1000-324X_2011_8_1","title":"多壁碳纳米管-酞菁铜复合物的合成表征及光电性能","volume":"26","year":"2011"},{"abstractinfo":"采用氯磺酸作为磺化试剂,在多壁碳纳米管上接枝氯磺酰基,之后通过乙二胺的胺解反应,制备出胺基修饰的多壁碳纳米管MWCNT-NH2,并进一步与氯磺酰基酞菁铜反应制备出MWCNT-Pc复合物.产物采用红外光谱,紫外可见,拉曼光谱,X射线光电子能谱,循环伏安,热重分析等进行了表征.结果表明,MWCNT-NH2上磺酰胺基接枝在MWCNT表面,而MWCNT-Pc上的酞菁基团是通过MWCNT-NH2上的酰胺基团与Pc形成复合物,碳纳米管上约38个碳原子结合一个磺酸基酞菁分子；该MWCNT-Pc复合物的热稳定性较MWCNT-NH2低；利用喷涂法构筑了ITO/MWCNT-Pc光电极,光电性能的研究结果表明在AM1.5光照条件下,光电压及光电流分别为0.434V和0.158mA/cm2;在320nm处的IPCE达19.8％,具有较优良的光电转化性能.根据测得的MWCNT-Pc的能带结构,推知MWCNT-Pc的光诱导电子转移过程是Pc端基发生光激发电子跃迁,此后电子转移到MWCNTs上并进一步传递到ITO,完成电荷分离.","authors":[{"authorName":"吴振奕","id":"b9897de2-d2a5-498d-a90a-90f7c6210f7a","originalAuthorName":"吴振奕"},{"authorName":"<span style=\"color:red\">杨</span><span style=\"color:red\">绳</span><span style=\"color:red\">岩</span>","id":"9e03e67a-2917-4729-ba38-9aec28b1d7ca","originalAuthorName":"杨绳岩"}],"doi":"10.3724/SP.J.1077.2011.00785","fpage":"785","id":"7084e49c-9a45-4057-bf42-5ecc4b67f6d3","issue":"8","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"00630fc9-7a1c-4704-ae02-e9a0ca6da462","keyword":"多壁碳纳米管","originalKeyword":"多壁碳纳米管"},{"id":"654814ca-0e1e-4edd-8eb8-b19431335f29","keyword":"酞菁铜","originalKeyword":"酞菁铜"},{"id":"c52d74e8-2a44-4841-ae7a-1227344412a2","keyword":"光电性能","originalKeyword":"光电性能"}],"language":"zh","publisherId":"wjclxb201108001","title":"多壁碳纳米管-酞菁铜复合物的合成表征及光电性能","volume":"26","year":"2011"},{"abstractinfo":"采用配体取代法合成了以双二苯基膦戊烷(dpppe)及C60为配体、Pt为中心金属的C60Pt(dpppe)新型富勒烯膦金属配合物.运用质谱、元素分析、紫外-可见吸收光谱、红外吸收光谱和光电子能谱等测试技术对产物进行了表征,同时采用循环伏安法对目标产物进行氧化还原性能研究.结果表明,C60与金属Pt配位后还原电位发生负移.结合电子光谱数据确定了目标产物的能级结构,其最高占有轨道和最低非占轨道能级分别为5.635和3.815 eV.还考察了目标产物在光化学电池中的光伏效应,测试结果表明,在BQ,/H2Q介质溶液中镀层厚度为1-2 μm时,具有较好的光电转换性能,光生电压值最高达358 mV.","authors":[{"authorName":"<span style=\"color:red\">杨</span><span style=\"color:red\">绳</span><span style=\"color:red\">岩</span>","id":"611f5b3d-8599-4800-a119-5a9b9084de53","originalAuthorName":"杨绳岩"},{"authorName":"吴振奕","id":"1b435979-46a3-4081-a6df-48df0923f65a","originalAuthorName":"吴振奕"}],"doi":"10.3724/SP.J.1095.2011.00380","fpage":"272","id":"ee3eac4e-a813-4c54-a9d0-0d10e7ec75c3","issue":"3","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"e93d8e1b-57e8-41aa-bd93-b4273af04b8d","keyword":"富勒烯","originalKeyword":"富勒烯"},{"id":"cb3d20d6-2ea1-4283-8ed9-25eb5318d53e","keyword":"双二苯基膦戊烷","originalKeyword":"双二苯基膦戊烷"},{"id":"6d781546-2749-4a5a-9a69-364e4e8011cb","keyword":"金属配合物","originalKeyword":"金属配合物"},{"id":"0e08aa72-52cf-41e9-993c-9f81b7e0e605","keyword":"光伏效应","originalKeyword":"光伏效应"}],"language":"zh","publisherId":"yyhx201103006","title":"双(二苯基膦戊烷)富勒烯合铂配合物的合成及光电性能","volume":"28","year":"2011"},{"abstractinfo":"摩擦提升机在<span style=\"color:red\">岩</span>金地下开采矿山应用较普遍.介绍了3种更换摩擦提升机首<span style=\"color:red\">绳</span>的方法,即用八联<span style=\"color:red\">绳</span>卡同步更换全部首<span style=\"color:red\">绳</span>,用专用<span style=\"color:red\">绳</span>盘同步更换全部首<span style=\"color:red\">绳</span>,利用2台绞车逐根更换首<span style=\"color:red\">绳</span>;并对3种首<span style=\"color:red\">绳</span>更换方法进行了对比分析,指出其优点、缺点和适用场所.值得参考.","authors":[{"authorName":"刘应国","id":"93f2108d-edb4-4abd-8767-97503f552aac","originalAuthorName":"刘应国"},{"authorName":"沈充","id":"ac42b051-144e-4ede-ae80-40c07d13992a","originalAuthorName":"沈充"},{"authorName":"曹云志","id":"f5038e3e-c483-4791-addc-6439a32726ad","originalAuthorName":"曹云志"}],"doi":"10.3969/j.issn.1001-1277.2011.01.010","fpage":"43","id":"331b9aec-14ce-404f-92e8-0b1c1350fad5","issue":"1","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"b5cc1ae3-5996-4f93-97a5-cda11a46809e","keyword":"摩擦提升机","originalKeyword":"摩擦提升机"},{"id":"b1bd1edc-36d1-46da-9731-ed6847eb1df1","keyword":"首<span style=\"color:red\">绳</span>","originalKeyword":"首绳"},{"id":"e175b318-dc5c-41bc-a84b-0d9a915d829c","keyword":"更换","originalKeyword":"更换"}],"language":"zh","publisherId":"huangj201101010","title":"摩擦提升机首<span style=\"color:red\">绳</span>更换方法","volume":"32","year":"2011"},{"abstractinfo":"以C<SUB>60</SUB>及双齿膦dppp为配体,在氮气氛下合成出C<SUB>60</SUB>Pt(dppp)配合物，采用质谱、元素分析、红外光谱、紫外可见光谱以及光电子能谱等手段对产物进行表征.同时研究了产物的光电性能及氧化还原性能.光伏效应研究结果表明：产物具有优良的光电转化性能，尤其是在BQ/H<SUB>2</SUB>Q介质电对中，光生电压最大达到371mV；当C<SUB>60</SUB>Pt(dppp)薄膜厚度为1μm时，光伏效应值最大.","authors":[{"authorName":"<span style=\"color:red\">杨</span><span style=\"color:red\">绳</span><span style=\"color:red\">岩</span>","id":"1937ae92-b479-4722-b10e-83e34bc7312e","originalAuthorName":"杨绳岩"},{"authorName":"张娜","id":"b61d9dc3-0def-4432-a337-3f57a0250f72","originalAuthorName":"张娜"},{"authorName":"吴振奕","id":"ff597e22-10c7-4f16-8091-3028b472e2a1","originalAuthorName":"吴振奕"}],"categoryName":"|","doi":"10.3724/SP.J.1077.2009.00018","fpage":"18","id":"0089fb13-42e6-4bc9-ac1b-ea58e5e9280a","issue":"1","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"004dd1f3-9f89-4937-b4c9-db58ccd3ee17","keyword":"富勒烯","originalKeyword":"富勒烯"},{"id":"e78a46b3-e15c-4984-9033-d963a4947543","keyword":" platinum complex","originalKeyword":" platinum complex"},{"id":"8e657c87-4548-48ac-9941-7d4be7681aeb","keyword":" photoelectric properties","originalKeyword":" photoelectric properties"}],"language":"zh","publisherId":"1000-324X_2009_1_9","title":"新型太阳能材料C<SUB>60</SUB>Pt(dppp)配合物的合成及性能","volume":"24","year":"2009"},{"abstractinfo":"以C60及双齿膦dppp为配体,在氮气氛下合成出C60Pt(dppp)配合物,采用质谱、元素分析、红外光谱、紫外可见光谱以及光电子能谱等手段对产物进行表征.同时研究了产物的光电性能及氧化还原性能.光伏效应研究结果表明:产物具有优良的光电转化性能,尤其是在BQ/H2Q介质电对中,光生电压最大达到371mV;当C60Pt(dppp)薄膜厚度为1μm时,光伏效应值最大.","authors":[{"authorName":"<span style=\"color:red\">杨</span><span style=\"color:red\">绳</span><span style=\"color:red\">岩</span>","id":"1de1206e-c290-47a2-9699-52a9fecf498c","originalAuthorName":"杨绳岩"},{"authorName":"张娜","id":"b2a3d5bb-cf93-4296-aca0-a91f7bbcd158","originalAuthorName":"张娜"},{"authorName":"吴振奕","id":"320cb5b2-9b53-46aa-8e89-104f75b74ff3","originalAuthorName":"吴振奕"}],"doi":"","fpage":"18","id":"2ed48dfb-ed5b-4cd5-9f5e-36b9879f7562","issue":"1","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"886e3dbd-1ae9-4ffc-aef1-158dba64adab","keyword":"富勒烯","originalKeyword":"富勒烯"},{"id":"f3ac5dae-a5a4-482e-8c8b-2dcca951709a","keyword":"铂配合物","originalKeyword":"铂配合物"},{"id":"135340f9-b7f4-49b7-b710-b54324197156","keyword":"光电性能","originalKeyword":"光电性能"}],"language":"zh","publisherId":"wjclxb200901004","title":"新型太阳能材料C60Pt(dppp)配合物的合成及性能","volume":"24","year":"2009"},{"abstractinfo":"<span style=\"color:red\">杨</span>坪金矿床赋存于下古生界丹凤群大草坝组变火山—沉积建造中,金矿化严格受层间挤压破碎(片理化)带控制,赋矿<span style=\"color:red\">岩</span>性为蚀变的二云石英片<span style=\"color:red\">岩</span>、绢云母石英片<span style=\"color:red\">岩</span>、绿泥石英片<span style=\"color:red\">岩</span>等变质<span style=\"color:red\">岩</span>及黄铁矿化石英脉,金矿化受变质、构造及次生氧化三重作用控制.对<span style=\"color:red\">杨</span>坪金矿床的地质特征及控矿特征进行了系统的研究,总结了找矿标志,并指出了找矿方向.","authors":[{"authorName":"张银斗","id":"8764fff0-6afd-4f47-8cbb-a0bc3aebc5e3","originalAuthorName":"张银斗"}],"doi":"","fpage":"24","id":"7c98a968-7112-4917-9271-e00b77970427","issue":"1","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"5034aee0-cb40-4bd0-b883-2eb1d15eac4b","keyword":"地质特征","originalKeyword":"地质特征"},{"id":"5f6b6235-c284-4a52-a713-e0bb3ac50aa3","keyword":"控矿特征","originalKeyword":"控矿特征"},{"id":"1e4733d3-52c3-4c63-9072-ff2e17cf002e","keyword":"找矿标志","originalKeyword":"找矿标志"},{"id":"f0b2ed2b-45f9-4bad-aba9-8b696a60102b","keyword":"找矿方向","originalKeyword":"找矿方向"},{"id":"abe0bc7e-b8e2-4095-a867-8c7cbb45a24f","keyword":"<span style=\"color:red\">杨</span>坪金矿床","originalKeyword":"杨坪金矿床"}],"language":"zh","publisherId":"huangj201301006","title":"甘肃<span style=\"color:red\">杨</span>坪金矿床控矿特征及找矿方向","volume":"","year":"2013"},{"abstractinfo":"用芳纶纤维制备了编织<span style=\"color:red\">绳</span>和加捻<span style=\"color:red\">绳</span>,测试拉伸性能,对拉伸曲线进行分析.结果表明,编织<span style=\"color:red\">绳</span>和加捻<span style=\"color:red\">绳</span>的载荷-位移曲线明显不同,前者在断裂前出现小锯齿状,后者在断裂后出现大锯齿状,二者断裂之前的载荷-位移曲线之间有很大的空白地带,表明编织<span style=\"color:red\">绳</span>的拉伸初始模量远远高于加捻<span style=\"color:red\">绳</span>.","authors":[{"authorName":"昝修平","id":"d40abcdb-f3d8-4f26-b8ba-43ac815073b2","originalAuthorName":"昝修平"},{"authorName":"<span style=\"color:red\">杨</span>彩云","id":"f11fa2f1-891d-4fda-a6d2-527057e1b7c4","originalAuthorName":"杨彩云"}],"doi":"10.3969/j.issn.1003-0999.2011.04.004","fpage":"17","id":"1468157c-a70e-4f9b-a1a3-79b73338b9ca","issue":"4","journal":{"abbrevTitle":"BLGFHCL","coverImgSrc":"journal/img/cover/BLGFHCL.jpg","id":"6","issnPpub":"1003-0999","publisherId":"BLGFHCL","title":"玻璃钢/复合材料"},"keywords":[{"id":"9887daa9-c582-42d0-94f8-92ece41df944","keyword":"芳纶<span style=\"color:red\">绳</span>","originalKeyword":"芳纶绳"},{"id":"095a9311-fff5-4c69-8b1f-3b2ae150ef2b","keyword":"编织<span style=\"color:red\">绳</span>","originalKeyword":"编织绳"},{"id":"5a7e53c0-4259-4008-bcaf-1074f6b1f065","keyword":"加捻<span style=\"color:red\">绳</span>","originalKeyword":"加捻绳"},{"id":"2690d1c5-345a-4e31-88cc-cea5e8716371","keyword":"拉伸载荷-位移曲线","originalKeyword":"拉伸载荷-位移曲线"}],"language":"zh","publisherId":"blgfhcl201104004","title":"芳纶编织<span style=\"color:red\">绳</span>与加捻<span style=\"color:red\">绳</span>的拉伸曲线比较分析","volume":"","year":"2011"},{"abstractinfo":"<span style=\"color:red\">杨</span>砦峪金矿床为河南灵宝小秦岭地区一重要大型石英脉型金矿床,矿床空间产出受太华群变质地层、岩浆<span style=\"color:red\">岩</span>及断裂构造控制,层间断裂为主要容矿构造.矿脉内矿体产出表现出\"尖灭再现\"、\"尖灭侧现\"规律.综合研究表明,小秦岭地区金矿床深部具有存在第二矿化富集段的可能性,在<span style=\"color:red\">杨</span>砦峪矿区,矿脉东段深部仍存在较好的成矿远景和找矿潜力.","authors":[{"authorName":"张庆超","id":"bab17d0e-bafb-4b0d-a46c-af63e0f92041","originalAuthorName":"张庆超"}],"doi":"10.3969/j.issn.1001-1277.2004.10.006","fpage":"19","id":"a5e01dd1-9aa0-45a0-bbfc-dc367c2a13db","issue":"10","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"96b81f72-8929-4e32-a794-35b0f3908133","keyword":"<span style=\"color:red\">杨</span>砦峪金矿床","originalKeyword":"杨砦峪金矿床"},{"id":"6027da23-6ddc-4696-b051-89c13227848a","keyword":"石英脉型","originalKeyword":"石英脉型"},{"id":"0cb416f8-b21f-4ff8-b599-e31978de5af7","keyword":"地质特征","originalKeyword":"地质特征"},{"id":"1379a96f-cb9d-492f-9621-dd980419d399","keyword":"深部成矿远景","originalKeyword":"深部成矿远景"}],"language":"zh","publisherId":"huangj200410006","title":"<span style=\"color:red\">杨</span>砦峪金矿床地质特征及深部成矿远景评价","volume":"25","year":"2004"},{"abstractinfo":"在剖析多<span style=\"color:red\">绳</span>摩擦提升机首<span style=\"color:red\">绳</span>张力平衡装置原理的基础上,研究首<span style=\"color:red\">绳</span>终端负荷和首<span style=\"color:red\">绳</span>运动差异对首<span style=\"color:red\">绳</span>长度变化的影响,找出了张力平衡装置最大调<span style=\"color:red\">绳</span>距离与井筒深度的关系.通过应用张力平衡装置的实例,对理论分析的正确性进行了验证,根据张力平衡装置的产品现状和使用情况,提出了对张力平衡装置设计和选型的建议.","authors":[{"authorName":"刘应国","id":"673cf4f4-3da0-489b-845c-c040fb3a8403","originalAuthorName":"刘应国"},{"authorName":"朱延宾","id":"fe643e9d-db2d-45b2-be9a-91e8b589768d","originalAuthorName":"朱延宾"}],"doi":"10.3969/j.issn.1001-1277.2010.06.009","fpage":"36","id":"0c5264f3-13fd-4f0f-be14-36bf7698b4a1","issue":"6","journal":{"abbrevTitle":"HJ","coverImgSrc":"journal/img/cover/HJ.jpg","id":"44","issnPpub":"1001-1277","publisherId":"HJ","title":"黄金"},"keywords":[{"id":"971b64d7-0f93-4004-be36-50f89aa019a0","keyword":"多<span style=\"color:red\">绳</span>摩擦提升机","originalKeyword":"多绳摩擦提升机"},{"id":"9ea2a30a-8903-44ef-984c-5fa6cfef1562","keyword":"钢丝绳张力","originalKeyword":"钢丝绳张力"},{"id":"030cff07-6edd-488e-9b4b-e4215274f80c","keyword":"平衡装置","originalKeyword":"平衡装置"}],"language":"zh","publisherId":"huangj201006009","title":"多<span style=\"color:red\">绳</span>提升张力平衡装置的研究","volume":"31","year":"2010"}],"totalpage":98,"totalrecord":976}