欢迎登录材料期刊网

材料期刊网

高级检索

研究合成了一种含有反应活性端基的聚乙二醇,并用FTIR和1H NMR对其进行表征,将合成产物对不饱和聚酯交联网络进行改性.结果证明,含有反应性马来酸酐端基的聚乙二醇参与不饱和聚酯的固化反应后,在交联网络中构成不同长度的柔性链段,阻止了聚乙二醇链段向不饱和聚酯表面的迁移.

参考文献

[1] L Suspene.Morphology of unsaturated polyester resin-additive blends[J].Polymer Engineering and Science,1990(30):1585-1590.
[2] M Maspoch.Toughening of unsaturated polyester with rubber paticles: Part 1: Morphological study[J].Polymer Engineering and Science,1998(38):282-289.
[3] M Maspoch.Toughening of unsaturated polyester with rubber particles[J].Part 2:Fracture behavior Polym Eng Sci,1998(38):290-298.
[4] J Ullett.Toughening of unsaturated polyester and vinyl ester resins with liquid rubbers[J].Polymer Engineering and Science,1995(35):1086-1094.
[5] S Tong.Supertough unsaturated polyester and its SMC[J].Journal of Reinforced Plastics and Composites,1990(09):299-311.
[6] U Schulze.Modification of unsaturated polyesters by poly(ethylene glycol)end groups[J].Journal OF APPLIED POLYMER SCIENCE,1997(64):527-535.
[7] S Pandit.Toughening of Unsaturated Polyesters by Reactive Liquid Polymers:1.Synthesis and Characterization of the Modifiers[J].Industrial and Engineering Chemistry Research,1993(32):3089-3095.
[8] S Pandit.Toughening of Unsaturated Polyesters by Reactive Liquid Polymers:2.Processibility and Mechanical Properties[J].Industrial and Engineering Chemistry Research,1994(33):2778-2784.
[9] E Martuscelli.Reactive rubbers as toughening agents for thermost polyester resins Molecular analysis by FTIR and fracture behavior of the resulting blends[J].Journal of Polymer Science,1993(31):619-627.
[10] M Abbate.Maleated polyisobutylene: a novel toughener for unstaurated polyester resins[J].Journal OF APPLIED POLYMER SCIENCE,1995(58):1825-1837.
[11] M Abbate.A novel reactive liquid rubber with maleimide and groups for the toughening of unstaurated polyester resins[J].Journal OF APPLIED POLYMER SCIENCE,1996(62):2107-2199.
[12] D Kim.Toughening mechanisms of modified unsaturated polyester with novel liquid polyurethane rubber[J].Journal of Materials Science,1994(29):1854-1861.
[13] S Lee.Analysis of unsaturated polyester-polyurethane interpenetrating polymer networks:1.Reaction kinetics and viscosity model[J].Polymer Engineering and Science,1991(31):1182-1188.
[14] S Lee.Analysis of unsaturated polyester-polyurethane interpenetrating polymer networks:2. Phase separation behavior[J].Polymer Engineering and Science,1993(33):598-606.
[15] K Hsieh.Interpenetrating polymer network of polyurethane and unsaturated polyester:Mechanical properties[J].Journal of Materials Science,1991(26):5877-5882.
[16] Y Chou.Mechanical properties of polyurethane-unsaturated polyester interpenetrating polymer networks[J].Polymer Engineering and Science,1995(35):976-988.
[17] M Xu.Study on phase behavior-Impact strength relationship of unsaturated polyester/polyurethane hybrid polymer network[J].Polymer International,1995(38):205-209.
[18] Ludovic Valette;Chih-Pin Hsu .Polyurethane and unsaturated polyester hybrid networks: 2. Influence of hard domains on mechanical properties[J].Polymer: The International Journal for the Science and Technology of Polymers,1999(8):2059-2070.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%