合成了 N- L-丙胺酰马来酰亚胺单体,并对其进行了聚合研究,讨论了引发剂浓度、单体浓度、温度等因素对聚合反应的影响,得到了聚合反应速率表达式: Rp=k[I]0.5[M].并根据 Arrehenius方程计算不同反应温度下的 k值、 A值和 Ea 值.讨论了溶剂和温度对旋光度的影响.聚合物结构用红外光谱、旋光仪和圆二色谱进行表征.
参考文献
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