以三氯化磷和邻苯基苯酚为起始原料,合成有机磷化合物 9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物(DOPO), DOPO再与 1,4-对苯醌发生加成反应,最终合成反应性含磷中间体 10-(2',5'-二羟基苯基)-9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物(DOPO-BQ).通过元素分析、质谱、红外光谱、核磁共振等分析测试手段对产物结构进行了表征.热失重分析表明该化合物具有较高的热稳定性.
参考文献
[1] | Wang C S;Shieh J Y .Phosphorus-Containing Epoxy Resin for an Electronic Application[J].Journal of Applied Polymer Science,1998,70(10):353-361. |
[2] | Wang C S;Lin C H .Synthesis and Properties of Phosphorus Containing Polyarylates Derived from 2-(6-oxido-6H-dibenz kc,elk1,2l oxaphosphorin-6-yl)-1,4-dihydroxy Phenylene[J].Polymer,1999,40:4387-4398. |
[3] | Chun Shan Wang;Ching Hsuan Liu .Synthesis and Properties of Phosphorus-Containing Epoxy Resins by Novel Method[J].Journal of Polymer Science, Part A. Polymer Chemistry,1999(21):3903-3909. |
[4] | Lin CH.;Wang CS. .Synthesis and property of phosphorus-containing bismaleimide by a novel method[J].Journal of Polymer Science, Part A. Polymer Chemistry,2000(12):2260-2268. |
[5] | Ying-Ling Liu;Wen-Lung Wei;Wen-Yu Chen .Reversibility of hydration and dehydration reactions of a phosphaphenanthrene oxide (DOPO) pendent group on polyamide[J].Polymer international,2003(8):1275-1279. |
[6] | 吴俊涛;唐超;王德生;唐安斌, 杨士勇.磷系阻燃剂中间体 DOPO的合成及应用[A].海南,2003 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%