采用差示扫描量热法(DSC)研究了N,N,N',N'-四缩水甘油基-4,4'-二氨基二苯甲烷(TGDDM)与新型含氟固化剂2,2,-双(3-氨基-4-羟基苯基)六氟丙烷(BAHPFP)的固化反应动力学.结果表明:固化反应过程中出现两个明显的放热峰,第一放热峰所对应的反应活化能Ea1为65.7 kJ/mol,反应级数n1为0.91;第二放热峰所对应的反应活化能Ea2为120.2 kJ/mol,反应级数n2为0.93.
参考文献
| [1] | 虞鑫海,徐永芬,赵炯心.1,3-双（4-氨基苯氧基）苯的合成及其聚酰亚胺[J].绝缘材料,2006(03):1-4,8. |
| [2] | 虞鑫海,杨名波,徐永芬,赵炯心.4,4'-双（3-氨基苯氧基）二苯甲酮及其聚醚醚酮酰亚胺的合成[J].绝缘材料,2006(05):1-3,6. |
| [3] | Chin-Ping Yangc;Chi-Shu Wei .Synthesis and Characterization of Two Polytrimellitamideimide Series With Different Segment Order by Direct Polycondensation[J].Journal of Applied Polymer Science,2001(6):1556-1567. |
| [4] | Delvigs;Peter .Tetraglycidyl Epoxy Resins and Graphite Fiber Composites Cured with Flexibilized Aromatic Diamines[J].Polymer Composites,1986,7(02):101-105. |
| [5] | 虞鑫海 等.新型聚酰亚胺特种单体的合成及其表征[J].绝缘材料通讯,1999,32(05):1-4. |
| [6] | 虞鑫海 等.含硅聚酰亚胺及其单体[J].化工新型材料,1999,27(11):31-36. |
| [7] | 虞鑫海,胡志强.新型聚酰亚胺的合成及其性能[J].绝缘材料通讯,2000(06):10-12. |
| [8] | 虞鑫海,胡志强.2,2-双〔4-（3-氨基苯氧基）苯基〕丙烷制备及其可溶性聚酰亚胺的研究[J].绝缘材料,2001(06):3-6. |
| [9] | 陈鑫,陈武荣.双酚A型二醚二酐的合成及其表征[J].绝缘材料,2001(06):7-11. |
| [10] | 虞鑫海.聚酰亚胺硅氧烷共聚物的合成[J].化工新型材料,2002(09):1-5. |
| [11] | 虞鑫海,施沁清,徐军.双酚A型聚酰亚胺单体的合成与应用[J].绝缘材料,2002(04):3-7. |
| [12] | 虞鑫海.含氟聚酰亚胺特种单体的合成及表征[J].化工新型材料,2003(10):24-27,31. |
| [13] | Sava Mitica .Synthesis and Properties of Polyaminoamide Containing Bismaleimide[J].Materiale Plastice (Bucharest Romania),2006,43(01):46-50. |
| [14] | Hsiao Sheng Huei;Huang Perng Chih .Synthesis and Characterization of Poly(arylene ether sulfone amide)s[J].Macromolecular Chemistry and Physics,1997,198(12):4001-4009. |
| [15] | Sastri SB.;Keller TM. .Phthalonitrile cure reaction with aromatic diamines[J].Journal of Polymer Science, Part A. Polymer Chemistry,1998(11):1885-1890. |
| [16] | Gupta N.;Varma IK. .Effect of structure of aromatic diamines on curing characteristics, thermal stability, and mechanical properties of epoxy resins. I[J].Journal of Applied Polymer Science,1998(11):1759-1766. |
| [17] | Wlodarczyk Andrzej;Maher.Mixed-valence Dinuclear Molybdenum Complexes with Benzenediamido and Dianilido Bridges:Comparison with Related Phenolato and Dipyridyl Species,and with their Pentammineruthenium Analogs[J].Journal of the Chemical Society Dalton Transactions:Inorganic Chemistry,1997(18):3287-3298. |
| [18] | Tamai S.;Ohta M.;Yamaguchi A. .MELT PROCESSIBLE POLYIMIDES AND THEIR CHEMICAL STRUCTURES[J].Polymer: The International Journal for the Science and Technology of Polymers,1996(16):3683-3692. |
| [19] | Yang Chin-Ping;Chen Ya-Ping;Woo E M .Fluorinated Polyamides and Poly(amide imide)s Based on 1,4-bis(4-amino-2-trifluromethylphenoxy)benzene,Aromatic Dicarboxylic Acids,and Various Monotrimellitimides and Bistrimellitimides:Syntheses and Properties[J].Journal of POLYMER SCIENCE PART A:POLYMER CHEMISTRY,2004,42(13):3116-3129. |
| [20] | Yang CP.;Chiang HC.;Chen RS. .Synthesis and characterization of organosoluble poly(arylate-imide)s prepared from direct polycondensation of bis(trimellitimide)-diacids and various bisphenols[J].Journal of Applied Polymer Science,2003(14):3818-3825. |
| [21] | Leu TS.;Wang CS. .Synthesis and characterization of copolyimides with high solubility[J].Journal of Applied Polymer Science,2003(8):1963-1970. |
| [22] | Abraham G.;Packirisamy S.;Vijayan TM.;Ramaswamy R. .Epoxy-imide resins from 2,2-bis[4-(4-trimellitimidophenoxy)pheny1]propane: Adhesive and thermal properties[J].Journal of Applied Polymer Science,2003(7):1737-1746. |
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