采用钛酸酯偶联剂(NDZ-105)对纳米β-碳化硅晶须([β-SiCw)进行表面改性处理,通过粉末共混-模压成型制备PS/SiCw纳米复合材料.探讨了SiCw用量和NDZ-105处理对复合材料力学、耐热性和介电性能的影响.结果表明,复合材料的力学性能随SiCw用量的增加而提高,当SiCw的质量分数为3%时,综合力学性能最佳;表面改性有助于进一步提高材料的力学性能;热失重分析表明SiCw的加入使PS的耐热性提高;介电性能分析表明复合材料的介电常数随SiCw用量的增加而增加.
参考文献
[1] | 辛洁波.塑料合金及塑橡共混改性[M].北京:中国轻工业出版社,2000:95-147. |
[2] | D. Qian;E. C. Dickey;R. Andrews .Load transfer and deformation mechanisms in carbon nanotube-polystyrene composites[J].Applied physics letters,2000(20):2868-2870. |
[3] | Lin Y.;Zhou B.;Fernando KAS.;Liu P.;Allard LF.;Sun YP. .Polymeric carbon nanocomposites from carbon nanotubes functionalized with matrix polymer[J].Macromolecules,2003(19):7199-7204. |
[4] | Chart Chiming;Wu Jingshen;Li Jianxiong et al.Polypropylene / calcium Carbonate Nanocomposite[J].POLYMER,2002,43(02):2981-2992. |
[5] | Kuljanin-Jakovljevic, J;Marinovic-Cincovic, M;Stojanovic, Z;Krkljes, A;Abazovic, ND;Comor, MI .Thermal degradation kinetics of polystyrene/cadmium sulfide composites[J].Polymer Degradation and Stability,2009(6):891-897. |
[6] | Junrong Yu;Kangbo Lu;Erwan Sourty .Characterization of conductive multiwall carbon nanotube/polystyrene composites prepared by latex technology[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(15):2897-2903. |
[7] | Selvin P. Thomas;Sabu Thomas;Sri Bandyopadhyay .Mechanical, atomic force microscopy and focussed ion beam studies of isotactic polystyrene/titanium dioxide composites[J].Composites, Part A. Applied science and manufacturing,2009(1):36-44. |
[8] | Devaux E.;Pak SH.;Caze C. .Effects of the structure of styrene-co-maleic anhydride oligomers on the interfacial properties in a glass fibre reinforced polystyrene composite material[J].Polymer Testing,2002(7):773-779. |
[9] | Bin Zhang;Ruo Wen Fu;Ming Qiu Zhang;Xian Ming Dong;Pei Liang Lan;Jie Shan Qiu .Preparation and characterization of gas-sensitive composites from multi-walled carbon nanotubes/polystyrene[J].Sensors and Actuators, B. Chemical,2005(2):323-328. |
[10] | M. Mukherjee;C. K. Das;A. P. Kharitonov;K. Banik;G. Mennig;T. N. Chung .Properties of syndiotactic polystyrene composites with surface modified short Kevlar fiber[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2006(1/2):206-214. |
[11] | 宋祖伟,李旭云,赵茹,戴长虹.催化剂对合成碳化硅晶须的影响[J].中国陶瓷,2005(02):28-30. |
[12] | 戴长虹,赵茹,孟永强.碳化硅纳米晶须的研究进展[J].中国陶瓷,2003(01):29-31. |
[13] | 高家化;沈志坚;丁子上 .陶瓷基纳米复合材料[J].复合材料学报,1994,11(01):1-7. |
[14] | Junwei Gu;Qiuyu Zhang;Yusheng Tang et al.Studies on the Preparation and Effect of the Mechanical Properties of Titanate Coupling Reagent Modified β-SiC Whisker Filled Celluloid Nano-composites[J].Surface and Coatings Technology,2008,202(13):2891-2896. |
[15] | 顾军渭,张秋禹,党婧,王小强,张军平,郭飞鸽.碳化硅-线性低密度聚乙烯导热复合材料的制备与性能[J].现代化工,2008(09):42-45. |
[16] | 顾军渭,张秋禹,李洪春,张军平,孔杰,唐玉生,张广成.钛酸酯改性纳米β-SiCw/赛璐珞复合材料的结构与性能研究[J].现代化工,2007(07):38-41. |
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