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用中等气压空气中均匀介质阻挡放电(DBD)产生的低温等离子体对聚丙烯(PP)薄膜进行表面改性.通过接触角和表面能测量、扫描电子显微镜(SEM)和全反射傅里叶红外光谱(ATR-FTIR)等方法,研究了等离子体改性时间和功率密度对PP薄膜表面水接触角、表面能、表面粗糙度以及表面化学成分等的影响.结果表明:PP表面水接触角和表面能先是随处理时间增加分别下降和增加,然后达到饱和状态;当处理时间一定时,功率密度越大,接触角下降的越多,表面能上升的越多;增大DBD处理的功率密度,利用更少的处理时间就能得到同样的处理效果.表面样貌及化学成分分析表明,随功率密度的增大,处理后薄膜表面的粗糙度增加,表面引入的含氧基团增多.

参考文献

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