气相色谱法测定二-(4-羟基丁基)四甲基二硅氧烷的合成产物含量

合成材料老化与应用, 2003, 32(2): 21-24. doi: 10.3969/j.issn.1671-5381.2003.02.008

气相色谱法测定二-(4-羟基丁基)四甲基二硅氧烷的合成产物含量

游革新 ^1, , 赵耀明 ^2, , 严玉蓉 ^3, , 汪朝阳 ^4,

1.江汉石油学院石油工程系,湖北,荆州,434102

2.华南理工大学材料学院,广东,广州,510640

3.华南理工大学材料学院,广东,广州,510640

4.华南理工大学材料学院,广东,广州,510640

关键词：气相色谱 , 内标法 , 二-(4-羟基丁基)四甲基二硅氧烷

GC Determination of Synthesis Products of Bis-(4-hydrox ylbutyl) tetramethyldisiloxane

采用气相色谱内标法,对二-(4-羟基丁基)四甲基二硅氧烷合成产物进行定量分析,并确定了色谱操作条件和产物的重量校正因子.该方法操作简单、快速、精度高、重现性好.

参考文献

[1]	幸松民;王一路.有机硅合成工艺及产品应用[M].北京:化学工业出版社,2000
[2]	Zulfiqar S;Ahmad S .Thermal degradation of blends of PVC with polysilox ane-I[J].Polymer Degradation and Sability,1999,65:243-247.
[3]	M-olding composition having improved impact strength[S].United States,Patent 5821321,1998.
[4]	Alignmentlayer for liquid crystals[S].United,States,Patent 574 4203,1998.
[5]	Photograp hicelements having a process-surviving polysiloxane block copolymer backing[S].Un ited, States,Patent 5723271,1998.
[6]	Yilgor I;McGrath J E .[J].Advances in Polymer Science,1988,86:1.
[7]	Terpolymer having,aromatic,polyester,polysiloxane,and,polycarbonate segments[S].United,State s,Patent 5932677,1999.
[8]	Park Ho Bum;Ha Seong Yong;Lee YoungMoo .Percolation behavior of gas permeability in rigid-fiexible block copolymer memb ranes[J].Journal of Membrane Science,2000,177:143-152.
[9]	Robert P Anderson;Scotia N Y .Intercondensation of Tetrahydrofuran with Organohalosilanes[P].US 3083219,1963.
[10]	Knoth W H;Lindsey R V .1-Oxa-2-Silacycloalkanes and their Conversion to Bis-(hydroxyalkyl)disiloxanes[J].Journal of the American Chemical Society,1958(80):4106-4108.
[11]	李浩春.分析化学手册[M].北京:化学工业出版社,1999:254-260.
[12]	Kojima K;Gore C R;Marvel C S.Preparation of Polysiloxanes Having Terminal Carboxyl or Hydroxyl Groups[J].Journal of Polymer Science Part A:Polymer Chemistry,1966(04):2325-2327.
[13]	Smith Cliford L;Gooden Robert .1-Oxa-2-Silacyclohexanes:Mechanism of Formation from Magnesium Halide Catalyzed Reactions of Some D ichorosilanes and Magnes ium Metal in Tetrahydrofuran[J].Journal of Organometallic Chemistry,1974,81:33-40.

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