二环[2.2.1]庚烷二羧酸盐和二环[2.2.2]庚烷二羧酸盐是重要的分散型聚丙烯成核剂,HPN-68是最优秀的商业化产品.该类成核剂最大的特点是可以提高聚丙烯的结晶温度和改性PP收缩的各向同性.详细介绍了该类成核剂的结构、制备方法和在聚丙烯中的应用.
参考文献
| [1] | 赵艳辉,史建公,张敏宏,赵桂良,刘志坚,张毅.脂肪二元羧酸及其盐的制备和结构研究进展[J].石化技术,2010(04):54-58. |
| [2] | 史建公,赵桂良,张敏宏,刘志坚,石勤智,杨万泰,赵丽梅.脂肪二羧酸及其盐类聚丙烯β成核剂研究进展[J].中外能源,2011(04):75-82. |
| [3] | 史建公,刘志坚,张敏宏,赵桂良,石勤智,杨万泰,赵丽梅.苯甲酸钠作为热塑性材料成核剂研究及应用进展[J].科技导报,2009(16):110-115. |
| [4] | D2 L.多森;美利肯公司 .六氢化邻苯二甲酸二钠盐组合物和包括该组合物的成核聚合物[P].CN1267483C,2006-8-2. |
| [5] | D.L.多森;X.E.赵;美利肯公司 .作为成核添加剂用于结晶热塑性塑料的六氢化邻苯二甲酸金属盐[P].CN 1292018C,2006-12-27. |
| [6] | 刘志坚,史建公,张敏宏,赵桂良,张毅.单环羧酸盐聚合物成核剂研究及应用进展[J].中外能源,2011(06):74-78. |
| [7] | M.J.曼尼恩;J.R.琼斯 .改进型二环[2.2.1]庚烷二羧酸盐成核添加剂配料[P].CN 1863857A,2006-11-15. |
| [8] | Xiaodong Edward Zhao;Darin L Dotson .Biocyclo[2.2.1]heptane dicarboxylate salts as polyolefin nucleators[P].USP 6465551B1,2002-10-15. |
| [9] | Michael J.Mannion;Jeffrey R.Jones;Milliken & Company .Nucleating additive formulations of bicyclo[2.2.1]hepane dicarboxylate salts[P].USP 6946507 B2,2005-09-20. |
| [10] | Xiaodong Edward Zhao;Darin L.Dotson .Bicyclo[2.2.1]heptane dicarboxylate salts as polyolefin nuceators[P].US 6,465,551 B1,2002-10-15. |
| [11] | Morin Brian G;Royer Joe;Burkhart Brian M .Polypropylene monofilament and tape fibers exhibiting certain creep-strain characteristics and corresponding crystalline configurations[P].US 6,863,976 B2,2005-03-08. |
| [12] | Lake Jr.Kemper David;Gandhi Bhavesh Chandrakant .Methods of nucleating thermoplastics using concentrates of saturated bicyclic dicarboxylate salts[P].US 6,995,202 B2,2006-02-07. |
| [13] | Mannion Michael J;Jones Jeffrey R .Nucleating additive formulations of bicyclo[2.2.1]heptane dicarboxylate salts[P].US 6,946,507,2005-09-20. |
| [14] | Zhao Xiaodong Edward;Dotson Darin L;Burkhart;Brian M;Jones Jeffrey R .Thermoplastic nucleating compounds[P].US 6,599,968 B2,2003-07-29. |
| [15] | Zhao Xiaodong Edward;Dotson Darin L .Highly versatile thermoplastic nucleators[P].US 6,559,211,B2,2003-05-06. |
| [16] | Mannion Michael J;Jones Jeffrey R .Nucleating additive formulations of bicyclo[2.2.1]heptane dicarboxylate salts[P].US 6,936,650,2005-08-30. |
| [17] | X.E .饱和[2.2.2]二羧酸盐热塑性塑料成核剂及其热塑性塑料组合物[P].CN100365046C,2008-1-30. |
| [18] | Dotson Darin L .Highly nucleated syndiotactic polypropylene[P].US 6,887,963,B2,2005-05-03. |
| [19] | Dotson Darin L;Mehl Nathan A;Burkhart Brian M;Xu Jiannong .Bimolecular nucleation methods for thermoplastics[P].US 7,129,323B2,2006-10-31. |
| [20] | Zhao Xiaodong Edward .Clarifying agent formulations for thermoplastics exhibiting very high nucleation efficacy[P].US 6,521,685 B1,2003-02-18. |
| [21] | Lake Jr.Kemper David;Gandhi Bhavesh Chandrakant .Concentrates of saturated bicyclic dicarboxylate salts to facilitate use thereof as polymer nucleation additives[P].US 7,078,450 B2,2006-07-18. |
| [22] | Zhao Xiaodong Edward;Dotson Darin L .Polymer additive compositions comprising highly versatile thermoplastic nucleators[P].US 7,094,820 B2,2006-08-22. |
| [23] | Darin L.Dotson .Methods of producing highly nucleated syndiotactic polypropylene[P].US 6,911,517 B2,2005-06-28. |
| [24] | Morin Brian G;Cowan Martin E;Smith Jack A .Low-shrink polypropylene tape fibers comprising high amounts of nucleating agents[P].US 6,794,033 B2,2004-09-21. |
| [25] | Morin Brian G;Cowan Martin E;Smith Jack A .Low-shrink polypropylene tape fibers comprising high amounts of nucleating agents[P].US 6,887,567,2005-05-03. |
| [26] | Royer Joseph R;Morin Brian G;Cowan;Martin E .Thermoplastic monofilament fibers exhibiting low-shrink,high tenacity,and extremely high modulus levels[P].US 6,759,124,2004-07-06. |
| [27] | Xiaodong Edward Zhao;Darin L.Dotson;Brian G.Morin et al.Highly nucleated thermoplastic articles[P].US 6,534,574 B1,2003-03-18. |
| [28] | Jiannong Xu;Jian Li;John David O.Anderson;Keith A.Keller .Metal carboxylate salt nucleating or clarifying agent compounds and releated polymer compositions and methods[P].US 2007/0208116 A1,2007-09-06. |
| [29] | Weihus Sonya Wolters;Kemper David Lake .Compositions comprising metal salts of hexahydrophthalic acid and methods of employing such compositions in polyolefin resins[P].US 2008/0004384 Al,2008-01-03. |
| [30] | Wouter Reyntjens;Martin Horrocks;Diederik Goyvaerts;Rob Hanssen .Polymer additive compositions and methods[P].US 2008/0139718A1,2008-06-12. |
| [31] | X.E.赵;D.L.多森 .用途非常多的新型热塑性塑料成核剂[P].CN 1511134A,2004-07-7. |
| [32] | 赵世成,辛忠,盛波扬.降冰片烯二羧酸盐类成核剂在等规聚丙烯中的成核效应[J].高分子材料科学与工程,2009(03):46-49. |
| [33] | 徐懋.[J].高分子通讯,1989(05):13-15. |
| [34] | 吴浩,徐日炜,曹宏伟,余鼎声,吴一弦.二环[2.2.1]庚烷二羧酸盐对聚丙烯的成核效果[J].北京化工大学学报（自然科学版）,2008(01):62-65. |
| [35] | Binsbergen F L .Heterogeneous nucleation in the crystallization of polyolefins:Part 1,chemical and physical nature of nucleation agents[J].Polymer,1970,11(04):253-267. |
| [36] | 许建农;李江;约翰·D·O·安德森 等.金属羧酸盐成核剂或澄清剂化合物及相关的聚合物组合物和方法[P].CN101395129 A,2009-03-25. |
| [37] | R.汉森;美利肯公司 .包括两种成核剂的热塑性聚合物组合物[P].CN101065434A,2007-10-31. |
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