2-叔丁基-6-(3-叔丁基-2-羟基-5-甲苯甲基)-4-甲基苯酚丙烯酸酯(GM)是一种新型双酚单丙烯酸酯类抗氧剂,其在聚合物加工过程中的热稳定性能尤为显著.本文通过测定添加不同含量的抗氧剂2246和抗氧剂GM的ABS树脂的氧化诱导参数及其经热氧老化后的力学性能以及色差值AE,分析研究了抗氧剂2246和抗氧剂GM在抗热氧老化方面的性能差异.结果表明,相较于传统受阻酚类抗氧剂2246,GM由于结构上特有的丙烯酸酯基团和分子内氢键作用,可以使ABS在长期热氧老化的过程中体现出更为优越的热氧稳定性能和耐黄变性能.
参考文献
| [1] | 申屠宝卿;解孝林;蔡启振 .ABS的老化及其防老化[J].工程塑料应用,1997,25(01):53-56. |
| [2] | Shin' ichi Yachigo;Toyonaka;Tamaki Ishii et al.Stabilizer for polymeric substance and polymeric substance composition containing the same[P].US Patent 4525514,1985. |
| [3] | Shin' ichi Yachigo;Manji Sasaki;Yukoh Takahashi et al.Studies on Polymer Stabilizers:Part Ⅰ-A novel thermal stabiliser for butadiene polymers[J].Polymer Degradation and Stability,1988,22(01):63-77. |
| [4] | Shin' ichi Yachigo;Fumitoshi Kojima;Manji Sasaki et al.Studies on Polymer Stabilizers:Part IV-Prevention of oxidative discoloration[J].Polymer Degradation and Stability,1992,37(02):107-113. |
| [5] | 韦春,孙海波,戴培邦.GM橡胶防老剂的研究[J].桂林工学院学报,2000(03):256. |
| [6] | 朱继芳,周彦宇,杜飞.双酚单丙烯酸酯抗氧剂KY-500的制备[J].合成材料老化与应用,2006(02):18-20. |
| [7] | 杜飞.双酚单丙烯酸酯类抗氧剂GM的合成[J].精细化工,2006(10):1007-1010. |
| [8] | 王娜,郝殿成,朱学多,高春晶,曹志臣,张会轩.抗氧剂对ABS树脂加工稳定性的影响[J].合成材料老化与应用,2008(01):22-25. |
| [9] | Shin' ichi Yachigo;Manji Sasaki;Kanado Ida et al.Studies on Polymer Stabilizers:Part Ⅵ-Relationship between performance and molecular conformation[J].Polymer Degradation and Stability,1993,39(03):329-343. |
| [10] | 王克智,李训刚.聚合物稳定化助剂技术进展[J].中国塑料,2001(04):1-6. |
| [11] | 郑元林,杨淑蕙,周世生,曹从军.CIE 1976LAB色差公式的均匀性研究[J].包装工程,2005(02):48-49,65. |
| [12] | Shin' ichi Yachigo;Kanado Ida;Manji Sasaki et al.Studies on Polymer Stabilizers:Part Ⅴ-Influences of structural factors on oxidative discoloration and thermal stability of polymers[J].Polymer Degradation and Stability,1993,39(03):317-328. |
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