固体氧化物燃料电池(SOFCs)被誉为21世纪最具有发展潜力的能源技术之一.由于用稀土或碱土金属氧化物掺杂的CeO2在较低的温度下具有较高的氧离子电导率,是用作中低温固体氧化物燃料电池较理想的电解质材料.本文综述了近年来以掺杂的CeO2作电解质的SOFCs性能的研究情况,总结了提高、改善CeO2基固体电解质电性能的几种方法,并对今后的研究提出了自己的看法.
参考文献
[1] | 衣宝廉 .燃料电池现状与未来[J].电源技术,1998,22(05):216-221. |
[2] | Badwal SPS. .Stability of solid oxide fuel cell components[J].Solid state ionics,2001(1):39-46. |
[3] | Zhang TS;Ma J;Kong LB;Chan SH;Kilner JA .Aging behavior and ionic conductivity of ceria-based ceramics: a comparative study[J].Solid state ionics,2004(3/4):209-217. |
[4] | Panhans M A;Blumenthal R N .A thermodynamic and electrical conductivity study of nomtoichiometric cerium dioxide[J].Solid State Ionicis,1993,60(04):279-298. |
[5] | Eguchi K;Setoguchi T;Inoue T et al.Electrical properties of ceria-based oxides and their application to solid oxide fuel cells[J].Solid State Ionicis,1992,52(1-3):165-172. |
[6] | Skinner S J;Kilner J A .Oxygen ion conductors[J].Materials Today,2003,6(03):30-37. |
[7] | 蒋凯,彭程,李五聚,王琳,王鸿燕,梁宏伟,孟健.Ce1-xGdxO2-x/2的溶胶-凝胶法合成及其性质[J].高等学校化学学报,2001(08):1279-1282. |
[8] | 马志芳,梁广川,梁金生.碱土金属氧化物掺杂氧化铈基电解质材料中的晶格缺陷[J].物理化学学报,2005(06):663-667. |
[9] | Arai H;Kunisaki T;Shimizu Y et al.Electrical properties of calcia-doped ceria with oxygen ion conduction[J].Solid State Ionicis,1986,20(04):241-248. |
[10] | Yahiro H;Ohuchi T;Eguchi K et al.Electrical properties and microstructure in the system ceria-alkline earth oxide[J].Journal of Materials Science,1988,23:1036-1041. |
[11] | Hideaki Inaba;Hiroaki Tagawa .Ceria-based solid electrolytes[J].Solid state ionics,1996(1/2):1-16. |
[12] | Yahiro H;Eguchi K;Arai H .Electrical properties and reducibilities of ceria-rare earth oxide systems and their application to sohd oxide fuel cell[J].Sohd Stale lonics,1989,36(1-2):71-75. |
[13] | Kim D J .Lattice parameters,ionic conductivities and solubility limits in fluorite-structure MO,oxide(M=Hf4+,Zr4+,ce4+,Th4+,u4+)solid solutions[J].Journal of the American Ceramic Society,1989,72(08):1415-1421. |
[14] | Mogens M;Nigel M;Sammes et al.Physical,chemical and electrochemical properties of pure and doped ceria[J].Solid Stale Ionics,2000,129:63-94. |
[15] | Kim S G;Yoon S P;Nam S W et al.Fabrication and characterization of a YSZ/YDC composite electrolyte by a sol -gel coating method[J].Journal of Power Sources,2002,110:222-228. |
[16] | Tsai T.;Barnett SA. .INCREASED SOLID-OXIDE FUEL CELL POWER DENSITY USING INTERFACIAL CERIA LAYERS[J].Solid state ionics,1997(3/4):191-196. |
[17] | Zhu Bin .Functional ceria-salt-composite materials for advanced ITSOFC applications[J].Journal of Power Sources,2003,114:1-9. |
[18] | Zhu Bin .Proton and oxygen ion conduction in nonoxide cermics[J].Materials Research Bulletin,2000,35:47-52. |
[19] | Zhu Bin .New advanced ceramic fuel cell technology using MFx(M=Na,ca,Ba,La,x=1-3)based electrolytes[J].Journal of Power Sources,1999,84:39-44. |
[20] | Zhu Bin .Intermediate temperature proton conducting salt-oxide composites[J].Solid state ionics,1999(1/4):397-405. |
[21] | Mishima Y;Mitsuyash H;Ohtaki M et al.Solid oxide fuel cell wich composite electrolyte consisting of samaria-doped ceria and yttria stabilized Zirconia[J].Journal of the Electrochemical Society,1998,145(03):1004-1008. |
[22] | Navarro I.;Frade J.;Marques F. .N-TYPE CONDUCTIVITY IN GADOLINIA-DOPED CERIA[J].Journal of the Electrochemical Society,1997(1):267-273. |
[23] | Maricle D L;Swarr T E;Karavolis S .Enhanced ceria a low-temperature SOFC electrolyte[J].Solid State Ionicis,1992,52(1-3):173-182. |
[24] | Kharton VV.;Navarro L.;Naumovich EN.;Kovalevsky AV. Yaremchenko AA.;Viskup AP.;Carneiro A.;Marques FMB.;Frade JR.;Figueiredo FM. .Ceria-based materials for solid oxide fuel cells[J].Journal of Materials Science,2001(5):1105-1117. |
[25] | M. Hartmanova;K. Gmucova;M. Jergel;I. Thurzo;F. Kundracik .Structural and electrical properties of double-layer ceria/yttria stabilized zirconia deposited on silicon substrate[J].Solid state ionics,1999(1/4):85-90. |
[26] | Lee JH;Kim J;Kim SW;Lee HW;Song HS .Characterization of the electrical properties of Y2O3-doped CeO2-rich CeO2-ZrO2 solid solutions[J].Solid state ionics,2004(1/2):45-52. |
[27] | Mori T;Yamamura H .Preparation of an alkali-element or alkali-earth-element doped CeO2-Sm2O3 system and its operation properties as the electrolyte in planar sohd oxide fuel cells[J].Journal of Materials Synthesis and Processing,1998,3(03):175-179. |
[28] | Toshiyuki Mori;Takayasu Ikegami;Hiroshi Yamamura .Application of a crystallographic index for improvement of the electrolytic properties of the CeO{sub}2-Sm{sub}2O{sub}3 system[J].Journal of the Electrochemical Society,1999(12):4380-4385. |
[29] | Zhang TS;Ma J;Kong LB;Chan SH;Kilner JA .Aging behavior and ionic conductivity of ceria-based ceramics: a comparative study[J].Solid state ionics,2004(3/4):209-217. |
[30] | Mori T.;Drennan J.;Lee JH.;Li JG.;Ikegami T. .Oxide ionic conductivity and microstructures of Sm- or La-doped CeO2-based systems[J].Solid state ionics,2002(Pt.B):461-466. |
[31] | Toshiyuki Mori;John Drennan;Yarong Wang;Graeme Auchterlonie;Ji-Guang Li;Anya Yago .Influence of nano-structural feature on electrolytic properties in Y_2O_3 doped CeO_2 system[J].Science and technology of advanced materials,2003(3):213-220. |
[32] | V. Gil;J. Tartaj;C. Moure .Rapid densification by using Bi_2O_3 as an aid for sintering of gadolinia-doped ceria ceramics[J].CERAMICS INTERNATIONAL,2007(3):471-475. |
[33] | Zhang T S;Ma J;Kong L B et al.Iron oxide as an effective sintefing aid and a grain boundary scavenger for ceria-based electrolytes[J].Sohd State lonics,2004,167:203-207. |
[34] | Nicholas JD;De Jonghe LC .Prediction and evaluation of sintering aids for Cerium Gadolinium Oxide[J].Solid state ionics,2007(19/20):1187-1194. |
[35] | Rahaman M N;Zhou Y C .Effect of solid solution additives on the sintering of ultra-fine CeO2 powders[J].Journal of the European Ceramic Society,1995,15:939-950. |
[36] | Kleinlogel C.;Gauckler LJ. .Sintering and properties of nanosized ceria solid solutions[J].Solid state ionics,2000(1/4):567-573. |
[37] | Zhang T s;Zeng Z Q;Hnang H T et al.Effect of alumina addition on the electrical and mechanical properties of Ce0.8Gd0.2O2-δ ceramics[J].Materials Letters,2002,57:124-129. |
[38] | ZhangT S;Ma J;Kong L B et al.Sintembility and ionic conductivity of coprecipitated Ce0.8Gd0.2O2-δ powders treated via a high-energy ball-milling process[J].Journal of Power Sources,2003,124:26-33. |
[39] | Haibin Li;Changrong Xia;Minhui Zhu .Increasing the sinterability of tape cast oxalate-derived doped ceria powder by ball milling[J].CERAMICS INTERNATIONAL,2007(1):201-205. |
[40] | 汤根土,骆仲泱,余春江,倪明江,岑可法.溶胶-凝胶低温燃烧合成法制备Sm0.15Gd0.05Ce0.8O1.9纳米粉体[J].硅酸盐学报,2004(09):1121-1127. |
[41] | Ranran Peng;Changrong Xia;Qingxi Fu .Sintering and electrical properties of (CeO_2)_(0.8)(Sm_2O_3)_(0.1) powders prepared by glycine-nitrate process[J].Materials Letters,2002(6):1043-1047. |
[42] | Mori T;Wang Y R;Drennan J et al.Influence of partied morphology on nanostructural feature and conducting property in Sm-doped CeO2 sintered body[J].Sohd State Ionics,2004,175:641-649. |
[43] | Cheng Peng;Zhen Zhang .Nitrate-citrate combustion synthesis of Ce_(1_x)Gd_xO_(2_x/2) powder and its characterization[J].CERAMICS INTERNATIONAL,2007(6):1133-1136. |
[44] | Chinarro E;Jurado J R;Colomer M T .Synthesis of ceria-based electrolyte nanometric powders by urea-combustion technique[J].Journal of the European Ceramic Society,2007,27:3619-3623. |
[45] | T. Mahata;G. Das;R.K. Mishra .Combustion synthesis of gadolinia doped ceria powder[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2005(1/2):129-135. |
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