本文对溶胶凝胶法在聚合物/无机纳米复合材料中的应用进行了综述.并对溶胶凝胶法在橡胶增强、光学仪器、功能化涂层以及其它领域中的应用进行了具体的讨论.指出溶胶凝胶过程工艺条件的优化以及分散介质范围的扩大将是溶胶凝胶法在聚合物/无机纳米复合材料中应用的发展方向.
参考文献
| [1] | 夏和生,王琪.聚合物纳米材料研究进展--Ⅱ.聚合物/无机纳米复合材料[J].化学研究与应用,2002(02):127-132. |
| [2] | 贺鹏,赵安赤.聚合物改性中纳米复合新技术[J].高分子通报,2001(01):74-82. |
| [3] | Jacques Livage .Sol-gel processes[J].Current Opinion in Solid State and Materials Science,1997,2:132-138. |
| [4] | 张立群,吴友平,王益庆,王一中,张慧峰,余鼎声,贺建芸.橡胶的纳米增强及纳米复合技术[J].合成橡胶工业,2000(02):71-77. |
| [5] | Ikeda Y;Tanaka A;Kohjiya S .Reinforcement of styrene-butadiene rubber vulcanizate by in situ silica prepared by the sol-gel reaction of tetraethoxysilane[J].Journal of Materials Chemistry,1997,7(08):1497-1503. |
| [6] | Sugiya M;Terakawa K;Miyamoto Y et al.Dynamic mechanical properties and morphology of silica-reinforced butadiene rubber by the sol-gel process[J].Kautschuk und Gummi Kunststoffe,1997,50(07):538. |
| [7] | Yuan QW;Mark JE .Reinforcement of poly(dimethysiloxane) networks by blended and in-situ generated silica fillers having various sizes, size distributions, and modified surface[J].Macromolecular Chemistry and Physics,1999,200(01):206. |
| [8] | H. Tanahashi;S. Osanai;M. Shigekuni;K. Murakami;Y. Ikeda;S. Kohjiya .Reinforcement of Acrylonitrile-butadiene rubber by silica generated in situ[J].Rubber Chemistry and Technology,1998(1):38-52. |
| [9] | Payne JT;Reuschle DA;Brister LB .Inorganic modification of elastomeric poly (styrene-b-isobutylene) block copolymerionomers via in situ sol-gel reactions of tetraethoxysilane[J].Polymeric Preprints(American Chemical Society Division of Polymer Chemistry),1997,38(01):249. |
| [10] | Landry CJT;Coltrain BK;Landry MR et al.Poly (vinylacetate)silica filled Materials:Material properties of in-situ vs fumed silica particles[J].Macromolecules,1993,26(14):3702. |
| [11] | Michalcyzyk MJ;Sharp KG;Stewart CW .Fluoropolymer nanocomposites for coating and their manu facture[P].PCT Int Appl,WO 97/01599A1,1997. |
| [12] | Gerard JF;Kaddami H;Pascaukt JP.Nanocomposites prepared by sol-gel process:In-situ synthesis of silica particles in polyurethanes[A].London,UK:Bristish Plast Fedn,1997:407-410. |
| [13] | Abe Y;Honda Y;Gunji T .Preparation and properties of silicon-containing polymr hybrids from 3-methacryloxypropyl trimethoxysilane[J].Applied Organometallic Chemistry,1998,12(10-11):749. |
| [14] | Novak BM .Hybrid nanocomposite materials:Between inorganic glasses and organi cpolymers[J].Advanced Materials,1993,5(06):422. |
| [15] | M. Ochi;R. Takahashi;A. Terauchi .Phase structure and mechanical and adhesion properties of epoxy/silica hybrids[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(12):5151-5158. |
| [16] | Jae Whan Cho;Kyung Il Sul .Characterization and properties of hybrid composites prepared from poly(vinylidene fluoride-tetrafluoroethylene) and SiO_2[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(2):727-736. |
| [17] | Maoping Zheng;Minyuan Gu;Yanping Jin .Preparation,structure and properties of TiO2-PVP hybrid films[J].Materials Science and Engineering B,2000,77:55-59. |
| [18] | A. Jitianu;M. Gartner;M. Zaharescu;D. Cristea;E. Manea .Experiments for inorganic–organic hybrid sol–gel films for micro- and nano-photonics[J].Materials science & engineering, C. Biomimetic and supramolecular systems,2003(1/2):301-306. |
| [19] | Julien Zaccaro;Nathalie Sanz;Estelle Botzung Appert.Baldeck,Alain Ibanez.Organic nanocrystals grown in sol-gel matrices: a new type of hybrid material for optics[J].C R Physique,2002(03):463-478. |
| [20] | S Frings;H.A.Meinema;C.F.van Nostrum;R.van der Linde .Organic-inorganic hybrid coatings for coil coating application based on polyesters and tetraethoxysilane[J].Progress in organic Coatings,1998,33:126-130. |
| [21] | Chen Q;Miyaji F;Kokubo T;Nakamura T .Apatite formation on PDMS-modified CaO-SiO2-TiO2 hybrids prepared by sol-gel process.[J].Biomaterials,1999(12):1127-1132. |
| [22] | C.Ohtsuki;T.Miyazaki;M.Tanihara .Synthesis of Bioactive Organic-Inorganic Hybrid from Methacryloxypropyltrimethoxysilane and 2-Hydroxyethylmethacrylate[J].Key engineering materials,2001(192/195):39-42. |
| [23] | 马洪洋,王静媛,于晓强,汤钧,汤心颐.溶胶-凝胶法合成聚（甲基丙烯酸乙酯-甲基丙烯酸环氧丙酯）/SiO2杂化聚合物材料[J].高分子学报,2000(04):402-406. |
| [24] | Kao CP.;Mou CY.;Lin HP. .Synthesis of elastic macrospheres of silica-surfactant nanocomposites[J].The journal of physics and chemistry of solids,2001(9/10):1555-1559. |
| [25] | Nishio K.;Tsuchiya T. .Organic-inorganic hybrid ionic conductor prepared by sol-gel process[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2001(3/4):295-306. |
| [26] | Cheng-Kuang Chan;Shu-Ling Peng;I-Ming Chu;Sheng-Chung Ni .Effects of heat treatment on the properties of poly(methyl methacrylate)/silica hybrid materials prepared by sol-gel process[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(9):4189-4196. |
| [27] | Zoppi RA.;Nunes SP.;das Neves S. .Hybrid films of poly(ethylene oxide-b-amide-6) containing sol-gel silicon or titanium oxide as inorganic fillers: effect of morphology and mechanical properties on gas permeability[J].Polymer: The International Journal for the Science and Technology of Polymers,2000(14):5461-5470. |
| [28] | Huang ZH;Dong JH;Qiu KY .New hybrid materials incorporating tetrabutyltitanate and tetraethoxysilane with functional SEBS elastomer via sol-gel process[J].JAPS,1997,66(05):863. |
| [29] | Wang SB;Mark JE .Reinforcing zirconia particles precipitated into an elastomeric material[J].Journal of Macromolecular Science:Chemistry,1991,28:185. |
| [30] | Machenzie JD;Chung YJ;Hu Y .Rubbery ormosils and their applications[J].Journal of Non-Crystalline Solids,1992,147:271. |
| [31] | 张超灿,孙江勤,李曦,李华智.溶胶-凝胶法制备PMMA/SiO2透明纳米复合材料的研究[J].玻璃钢/复合材料,2000(04):18-20. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%