单体4,8-二溴-1,5-二正丁氧基萘(M-I)分别与1,4-二乙烯基-2,5-二正丁氧基苯(M-Ⅱ)和4,4′-二乙烯基联苯(M-Ⅲ),在钯催化下通过Heck耦合反应得到共轭聚合物P-1、P-2.单体和聚合物进行了1H,13C NMR、质谱、FT-IR、UV、循环伏安和荧光光谱等测试.萘基团是一种很好的荧光团,侧链上引入了丁氧基醚链,使得聚合物具有适当的溶解度.聚合物P-1、P-2具有较强的绿色荧光,它们将是一类潜在的光电高分子材料.
参考文献
| [1] | GermG;Leditzky G .[J].Advanced Materials,1:36. |
| [2] | YangZ;Sokolik I;Karasz F E .[J].Macromolecules,1993,26:1188. |
| [3] | 黄宗浩;谢德民;王荣顺;郎远涛 .[J].功能材料,1993,24(02):97. |
| [4] | YangZ;Sokolik I;Karasz FE .[J].Macromolecules,1993,26:1188. |
| [5] | WangH;Yu LP .[J].Polymeric Preprints(American Chemical Society Division of Polymer Chemistry),1999,40:1072. |
| [6] | ChengE;Chen SA .[J].Journal of Applied Physics,1999,85:2057. |
| [7] | Eldo J.;Arunkumar E.;Ajayaghosh A. .Fluorescent bispyrroles. New building blocks for novel #pi#-conjugated polymers[J].Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry,2000(32):6241-6244. |
| [8] | CarrenoM;Garcia RJL;Sanz G .[J].Journal of Organic Chemistry,1995,60(16):5328. |
| [9] | PengZH;Gharavi AR;Yu LP .[J].Journal of the American Chemical Society,1997,119:4622. |
| [10] | AnnaH;David H;George M .[J].Journal of the American Chemical Society,1992,114:6227. |
| [11] | GunterW;Ahmed A .[J].Makromolekulare Chemie,1979,179:2647. |
| [12] | LiuTD;Cheng YX;Yang XL .[J].Chemical Research in Chinese Universities,2003,19(02):235. |
| [13] | ChenZK;Meng H;Lai YH;Huang W .[J].Macromolecules,1999,32:43511. |
| [14] | JianP;Wang LY;Jing N;Huang W .[J].Macromolecules,2001,34:7241. |
| [15] | JenAKY;Liu YQ;Hu QS;Lin P .[J].Applied Physics Letters,1999,759(94):3745. |
| [16] | 张志明,李国文,马於光,吴芳,田文晶,沈家骢.含噻吩环（ ）二唑衍生物的合成及电化学性能研究[J].高等学校化学学报,2000(11):1719-1722. |
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