以透明导电玻璃(TCO)、纳米TiO2/TCO、CNTs/TCO、铜片分别为工作电极,用简单铜盐通过阴极还原制备了Gu2O薄膜,并研究了溶液温度和衬底对电化学沉积Gu2O薄膜形貌的影响.结果表明:以TCO和铜片为衬底时,由于表面微粒为微米级,不管溶液温度高低,只能得到微米级的Cu2O薄膜;以纳米TiO2/TCO和CNTs/TCO为衬底,池温高于30℃只能得到微米级的Cu2O薄膜,而池温降到0℃时,都可得到纳米Cu2O.
参考文献
| [1] | de Jongh P E;Vanmaekelbergh D;Kelly J J.[J].Journal of the Electrochemical Society:486-489. |
| [2] | Bertocci U.[J].Journal of the Electrochemical Society:1598-1602. |
| [3] | Jayewardena C.;Wijewardena DLA.;Guruge H.;Hewaparakrama KP. .Fabrication of n-Cu2O electrodes with higher energy conversion efficiency in a photoelectrochemical cell[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,1998(1):29-33. |
| [4] | Sanka K;Chatterjee P;Sen GuptaS P.[J].Solar Energy Materials and Solar Cells,1999:345-358. |
| [5] | N Fernando C A;Wethasinghe S K.[J].Solar Energy Materials and Solar Cells:299-308. |
| [6] | Musa A O;Akomolafe T;Carter M J.[J].Solar Energy Materials and Solar Cells:305-316. |
| [7] | SantraK;Sarkar C K;Mukherjee M K et al.[J].Thin Solid Films,1992,213:226-236. |
| [8] | Georgieva V.;Ristov M. .Electrodeposited cuprous oxide on indium tin oxide for solar applications[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2002(1):67-73. |
| [9] | YoonKH;ChoiWJ;KangD H .[J].Thin Solid Films,2000,372:250-256. |
| [10] | Rothenberger G;Moser J;Gratzel M.[J].Journal of the American Chemical Society:8054-8059. |
| [11] | Nazeeruddin M K;Kay A;Rodicio I.[J].Journal of the American Chemical Society:6382-6390. |
| [12] | 陈志钢;唐一文;贾志杰.[J].无机材料学报,2005 |
| [13] | Mahalingam T.;Rajendran S.;Jayachandran M.;Chockalingam MJ.;Chitra JSP. .Galvanostatic deposition and characterization of cuprous oxide thin films[J].Journal of Crystal Growth,2000(1/4):304-310. |
| [14] | 周延春;Switzer J.[J].材料研究学报(05):512-516. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%