欢迎登录材料期刊网

材料期刊网

高级检索

以LiNi0.8Co0.2O2为活性物质,炭黑为导电剂,聚偏氟乙烯为粘结剂,采用溶液浇铸法制备锂离子电池正极.本文研究了不同质量含量的聚偏氟乙烯对锂离子电池正极电性能的影响.实验结果表明:当正极材料中粘结剂聚偏氟乙烯含量为4%时,所制备的正极片的电性能最佳,首次放电容量为190mAh/g,首次充放电效率最高可达91%,循环性能良好,进一步组装的18650电池经50次循环后容量为1832mAh,为首次放电容量的97.8%.

参考文献

[1] 唐致远,阮艳莉.锂离子电池容量衰减机理的研究进展[J].化学进展,2005(01):1-7.
[2] D.Ostrovskii;F.Ronci;B.Scrosati .A FTIR and Raman study of spontaneous reactions occurring at the LiNi_yCo(1-y)O_2 electrode/non-aqueous electrolyte interface[J].Journal of Power Sources,2001(2):183-188.
[3] Balasubramanian M;Melendres CA .X-ray absorption near-edge spectroscopy study of the oxidation state of chromium in electrodeposited oxide films[J].Electrochimica Acta,1999(17):2941-2945.
[4] Matsuo Y;Kostecki R;McLarnon F .[J].Electrochimica Acta,1999,45(02):A225-A233.
[5] Rougier A.;Wen SJ.;Richardson TJ.;Reade RP.;Cairns EJ.;Striebel KA. .Characterization of pulsed laser-deposited LiMn2O4 thin films for rechargeable lithium batteries[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,1998(1/4):107-115.
[6] 黄可龙,吕正中,刘素琴.锂离子电池容量损失原因分析[J].电池,2001(03):142-145.
[7] Nam-Soon Choi;Young-Gi Lee;Jung-Ki Park .[J].Journal of Power Sources,2002,122(02):61-66.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%