通过Ullmann反应合成了4-甲氧基三苯胺(MeO-TPA)和4,4'.二甲氧基三苯胺(DMeO-TPA)两种具有良好溶解性的甲氧基取代三苯胺,通过FFIR、'H NMR和元素分析等手段对其进行了表征,并采用循环伏安(CV)结合UV-Vis吸收光谱测试了其能级结构.以甲氧基取代三苯胺为电荷传输材料,TiOPc为电荷产生材料制备了双层光电导体,测试了其光敏性.结果表明MeO-TPA和DMeO-TPA具有较三苯胺(TPA)更为优良的空穴传输性能.
参考文献
[1] | 叶坚,陈红征,施敏敏,汪茫.有机电子传输材料研究新进展[J].自然科学进展,2002(08):800-805. |
[2] | Hughes G;Bryce M R .[J].Journal of Materials Chemistry,2005,15:94-107. |
[3] | Tsang S W;So S K;Xu J B .[J].Journal of Applied Physics,2006,99(01):013706. |
[4] | Robinson J;Osteryoung R A .[J].Journal of the American Chemical Society,1980,102(13):4415-4420. |
[5] | 陈安尚,李亚明,张红兵,张华.二苯胺基均二苯乙烯的合成及光电性能研究[J].染料与染色,2004(06):376-377,372. |
[6] | 李祥高,吴安树,何莉莉,王世荣.4-(4',4'-二苯基-1',3'-丁二烯基)-N,N-二(4″-甲基苯基)苯胺的合成及性能[J].精细化工,2005(08):572-574. |
[7] | Xu Q;Chen HZ;Wang M .Synthesis and hole transport property of a novel triphenylamine substituted stilbene derivative[J].Materials Chemistry and Physics,2004(2/3):446-451. |
[8] | Bryan K. Spraul;S. Suresh;Takafumi Sassa;M. Angeles Herranz;Luis Echegoyen;Tatsuo Wada;Dvora Perahia;Dennis W. Smith Jr. .Thermally stable triaryl amino chromophores with high molecular hyperpolarizabilities[J].Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry,2004(16):3253-3256. |
[9] | Zheng M;Bai F L;Li Y L;Yu G,Yang C H,Zhu D B .[J].Synthetic Metals,1999,102(1-3):1275-1276. |
[10] | Osaheni J A;Jenekhe S A;Perlstein J .[J].Journal of Physical Chemistry,1994,98(48):12727-12736. |
[11] | 陈令武,宋金峰,刘田东,成义祥.含萘单元共聚物的合成与性质研究[J].材料科学与工程学报,2005(01):31-34. |
[12] | Amthor S .Redox properties of bis-triarylamines and ligand properties of thianthrenophane[D].Julius-Maximilians-Universitat Wurzburg,2005. |
[13] | Yu w L;Pei J;Huang W;Heeger A J.[J].Chemistry Communications,2000(08):681-682. |
[14] | Wu TY.;Chen Y. .Synthesis and characterization of novel luminescent polymers with alternate phenothiazine and divinylbenzene units[J].Journal of Polymer Science, Part A. Polymer Chemistry,2002(24):4452-4462. |
[15] | Faber R.;Rapta P.;Stasko A.;Nuyken O.;Mielke GF. .Anodic oxidation of novel hole-transporting materials derived from tetraarylbenzidines. Electrochemical and spectroscopic characterization[J].Collection of Czechoslovak Chemical Communications,2000(9):1403-1418. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%