研究以四水合乙酸锰为锰源,单质硫粉为硫源,分别以乙醇、乙二醇及丙三醇为溶剂,在不添加任何表面修饰剂的条件下采用溶剂热反应制备出MnS材料.用X射线粉末衍射仪(XRD)和扫描电镜(SEM)对产物进行了物相和形貌表征.结果表明,通过控制溶剂类型、反应物的投料比、溶剂热温度及反应时间,可以控制合成α-MnS和γ-MnS.丙三醇为溶剂时所得的α-MnS材料粒度更细,光催化效果最好.
参考文献
| [1] | Gajanan Pandey;Harendra K. Sharma;S.K. Srivastava;R.K. Kotnala.γ-MnS nano and micro architectures: Synthesis, characterization and optical properties[J].Materials Research Bulletin,201111(11):1804-1810. |
| [2] | Yu, JG;Tang, H.Solvothermal synthesis of novel flower-like manganese sulfide particles[J].The journal of physics and chemistry of solids,20085/6(5/6):1342-1345. |
| [3] | 辛宇;黄剑锋;曹丽云;刘佳;李嘉胤;吴建鹏.pH值对微波水热法制备γ-MnS微晶形貌及光学性能的影响[J].人工晶体学报,2012(2):312-317. |
| [4] | Mu J;Gu ZF;Wang L;Zhang ZQ;Sun H;Kang SZ.Phase and shape controlling of MnS nanocrystals in the solvothermal process[J].Journal of nanoparticle research: An interdisciplinary forum for nanoscale science and technology,20081(1):197-201. |
| [5] | Tian Xi Wang;Wei Wei Chen.Low-temperature synthesis of pure rock-salt structure manganese sulfide using a single-source molecular precursor[J].Chemical engineering journal,20081(1):146-148. |
| [6] | 徐舸;刘公召.溶剂热法可控合成α-,β-MnS纳米材料和γ-MnS纳米线[J].人工晶体学报,2013(6):1126-1131,1165. |
| [7] | 祁元春;赵彦保;许红涛.形貌可控γ-硫化锰纳米晶的制备及表征[J].化学研究,2006(4):60-62. |
| [8] | Yange Zhang;Zude Zhang;Shutao Wang;Xuchu Ma;Yitai Qian.Synthesis and characterization of α-MnS polyhedrons and spheres[J].Materials Chemistry and Physics,20062/3(2/3):365-370. |
| [9] | Pingtang Zhao;Qiumei Zeng;Xianliang He;Hao Tang;Kaixun Huang.Preparation of γ-MnS hollow spheres consisting of cones by a hydrothermal method[J].Journal of Crystal Growth,200818(18):4268-4272. |
| [10] | Fan DB.;Yang XD.;Wang H.;Zhang YC.;Yan H..Photoluminescence of MnS thin film prepared by chemical bath deposition[J].Physica, B. Condensed Matter,20031/4(1/4):165-169. |
| [11] | 李成威;亢淑梅;李慧玉;孙源龙;王贵玉;赵蓉蓉;薛娟琴.自蔓延高温合成MnS粉末[J].有色金属（冶炼部分）,2007(5):43-45. |
| [12] | Liu, Xin;Wang, Jia;Yue, Lei;Xin, Baoping;Chen, Shi;Dai, Jiulan;Wang, Renqing;Wang, Yutao.Biosynthesis of high-purity gamma-MnS nanoparticle by newly isolated Clostridiaceae sp and its properties characterization[J].Bioprocess and biosystems engineering,20152(2):219-227. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%