与传统的共聚物增容相比,无机粒子能够以较低的成本实现多组分高分子材料的高性能化及功能化,在新型材料的制备方面具有巨大的潜力,因此引起了学术界及产业界的广泛兴趣.该领域研究核心问题在于揭示纳米粒子对多组分高分子材料在加工条件下的形态控制机理.结合作者课题组的相关工作,从平衡增容和非平衡增容的角度,分别综述了国内外近年来在含无机粒子的多组分材料的结构形成机理及演化规律等方面的理论及实验研究进展,讨论了该领域研究中在实验现象及机理解释等方面存在的主要分歧与问题,建议下一步需要在粒子细节特性、流场条件、实验手段以及研究体系等方面深化研究.最后,对含无机粒子多组分高分子材料在导热/导电、能源、生物等功能材料制备领域中的一些潜在应用进行了简单介绍.
参考文献
| [1] | Fenouillot, F;Cassagnau, P;Majeste, JC .Uneven distribution of nanoparticles in immiscible fluids: Morphology development in polymer blends[J].Polymer,2009(6):1333-1350. |
| [2] | G. Filippone;D. Acierno;G. Romeo .Role of Interface Rheology in Altering the Onset of Co-Continuity in Nanoparticle-Filled Polymer Blends[J].Macromolecular materials and engineering,2011(7):658-665. |
| [3] | Chen, J.;Shi, Y.-Y.;Yang, J.-H.;Zhang, N.;Huang, T.;Wang, Y. .Improving interfacial adhesion between immiscible polymers by carbon nanotubes[J].Polymer: The International Journal for the Science and Technology of Polymers,2013(1):464-471. |
| [4] | Liu, L;Wang, Y;Li, YL;Wu, J;Zhou, ZW;Jiang, CX .Improved fracture toughness of immiscible polypropylene/ethylene-co-vinyl acetate blends with multiwalled carbon nanotubes[J].Polymer: The International Journal for the Science and Technology of Polymers,2009(14):3072-3078. |
| [5] | Tucker CL.;Moldenaers P. .Microstructural evolution in polymer blends [Review][J].Annual Review of Fluid Mechanics,2002(0):177-210. |
| [6] | Yuri S.Lipatov .Polymer blends and interpenetrating polymer networks at the interface with solids[J].Progress in Polymer Science,2002(9):1721-1801. |
| [7] | Yajiang Huang;Sujun Jiang;Guangxian Li .Effect of fillers on the phase stability of binary polymer blends: A dynamic shear rheology study[J].Acta materialia,2005(19):5117-5124. |
| [8] | Du, M.;Wu, Q.;Zuo, M.;Zheng, Q. .Filler effects on the phase separation behavior of poly (methyl methacrylate)/poly (styrene-co-acrylonitrile) binary polymer blends[J].European Polymer Journal,2013(9):2721-2729. |
| [9] | Huang, C.;Gao, J.;Yu, W.;Zhou, C. .Phase separation of poly(methyl methacrylate)/poly(styrene-co- acrylonitrile) blends with controlled distribution of silica nanoparticles[J].Macromolecules,2012(20):8420-8429. |
| [10] | Gao, J.;Huang, C.;Wang, N.;Yu, W.;Zhou, C. .Phase separation of poly (methyl methacrylate) / poly (styrene-co- acrylonitrile) blends in the presence of silica nanoparticles[J].Polymer: The International Journal for the Science and Technology of Polymers,2012(8):1772-1782. |
| [11] | Xia, T.;Huang, Y.;Peng, X.;Li, G. .Morphological transition induced by nanoparticles in dynamically asymmetric PS/PVME blends[J].Macromolecular chemistry and physics,2010(20):2240-2247. |
| [12] | Valeriy V.Ginzburg .Influence of Nanoparticles on Miscibility of Polymer Blends.A Simple Theory[J].Macromolecules,2005(6):2362-2367. |
| [13] | 李楠,黄亚江,夏天,杨其,李光宪.振荡剪切流场下PS/PVME/SiO2复合物的相行为[J].高等学校化学学报,2013(12):2896-2902. |
| [14] | Yurekli K.;Karim A.;Amis EJ.;Krishnamoorti R. .Influence of layered silicates on the phase-separated morphology of PS-PVME blends[J].Macromolecules,2003(19):7256-7267. |
| [15] | Li, L.;Miesch, C.;Sudeep, P.K.;Balazs, A.C.;Emrick, T.;Russell, T.P.;Hayward, R.C. .Kinetically trapped co-continuous polymer morphologies through intraphase gelation of nanoparticles[J].Nano letters,2011(5):1997-2003. |
| [16] | Li-Tang Yan;Xu-Ming Xie .Computational modeling and simulation of nanoparticle self-assembly in polymeric systems: Structures, properties and external field effects[J].Progress in Polymer Science,2013(2):369-405. |
| [17] | Peng G;Qiu F;Ginzburg V V et al.Forming Supramolecular Networks from Nanoscale Rods in Binary,Phase-Separating Mixtures[J].SCIENCE,2000,288(5472):1802-1804. |
| [18] | Yajiang Huang;Rui Wang;Yajie Sun .Simulation on the phase behavior of binary blends contacted with external surfaces under two-step quench conditions[J].Acta materialia,2008(6):1173-1181. |
| [19] | Xia, T.;Huang, Y.;Jiang, X.;Lv, Y.;Yang, Q.;Li, G. .The molecular mechanism of the morphology change in PS/PVME/silica blends based on rheology[J].Macromolecules,2013(20):8323-8333. |
| [20] | Picketing S U;CXCVI .Emulsions[J].J Chem Soc Trans,1907,91:2001-2021. |
| [21] | Hunter TN;Pugh RJ;Franks GV;Jameson GJ .The role of particles in stabilising foams and emulsions[J].Advances in colloid and interface science,2008(2):57-81. |
| [22] | E. M. HERZIG;K. A. WHITE;A. B. SCHOFIELD .Bicontinuous emulsions stabilized solely by colloidal particles[J].Nature materials,2007(12):966-971. |
| [23] | Hong JS;Namkung H;Ahn KH;Lee SJ;Kim C .The role of organically modified layered silicate in the breakup and coalescence of droplets in PBT/PE blends[J].Polymer: The International Journal for the Science and Technology of Polymers,2006(11):3967-3975. |
| [24] | Hong JS;Kim YK;Ahn KH;Lee SJ;Kim C .Interfacial tension reduction in PBT/PE/clay nanocomposite[J].Rheologica Acta: An International Journal of Rheology,2007(4):469-478. |
| [25] | Vandebril, S.;Vermant, J.;Moldenaers, P. .Efficiently suppressing coalescence in polymer blends using nanoparticles: Role of interfacial rheology[J].Soft matter,2010(14):3353-3362. |
| [26] | Thareja P;Velankar S .Particle-induced bridging in immiscible polymer blends[J].Rheologica Acta: An International Journal of Rheology,2007(3):405-412. |
| [27] | Wei Tong;Yajiang Huang;Chenglei Liu .The morphology of immiscible PDMS/PIB blends filled with silica nanoparticles under shear flow[J].Colloid and polymer science,2010(7):753-760. |
| [28] | 刘成蕾,佟伟,黄亚江,程小莲,侯康,杨其.纳米SiO_2对PDMS/PIB不相容共混物在低剪切速率下凝聚行为的影响[J].高分子学报,2009(12):1219-1225. |
| [29] | Yusong He;Yajiang Huang;Qiong Li .Morphological hysteresis in immiscible PIB/PDMS blends filled with fumed silica nanoparticles[J].Oil Mill Gazetteer,2012(11):997-1004. |
| [30] | Qiong Li;Yajiang Huang;Shuting Xi .Double Emulsions of Immiscible Polymer Blends Stabilized by Interfacially Active Nanoparticles[J].AIChE Journal,2013(11):4373-4382. |
| [31] | 彭小娟,黄亚江,何郁嵩,罗勇,杨其,李光宪.SiO2纳米粒子对受限流场下聚异丁烯/聚二甲基硅氧烷共混物相形态的影响[J].高等学校化学学报,2011(12):2896-2901. |
| [32] | Kong, M.;Huang, Y.;Chen, G.;Yang, Q.;Li, G. .Retarded relaxation and breakup of deformed PA6 droplets filled with nanosilica in PS matrix during annealing[J].Polymer: The International Journal for the Science and Technology of Polymers,2011(22):5231-5236. |
| [33] | 孔米秋,黄亚江,刘文娟,李光宪.SiO2纳米粒子对PMMA/PS共混物共连续相结构退火粗化过程的影响[J].高分子学报,2010(09):1070-1076. |
| [34] | 刘文娟,黄亚江,吴冬生,高灵强,杨其,李光宪.纳米SiO2填充PMMA/PS复合物共连续范围的研究[J].高分子学报,2009(06):553-559. |
| [35] | Binks BP.;Lumsdon SO. .Catastrophic phase inversion of water-in-oil emulsions stabilized by hydrophobic silica[J].Langmuir: The ACS Journal of Surfaces and Colloids,2000(6):2539-2547. |
| [36] | Sumita M;Sakata K;Asai S et al.Dispersion of Fillers and the Electrical Conductivity of Polymer Blends Filled with Carbon Black[J].Polymer Bulletin,1991,25(02):265-271. |
| [37] | Thareja, P;Moritz, K;Velankar, SS .Interfacially active particles in droplet/matrix blends of model immiscible homopolymers: Particles can increase or decrease drop size[J].Rheologica Acta: An International Journal of Rheology,2010(3):285-298. |
| [38] | Mei, Y.;Huang, Y.;Yang, Q.;Li, G. .Improved shape stability of nanosilica-filled PBT fibrils in PS matrix: Effects of accelerated crystallization and enhanced viscoelasticity[J].Polymer: The International Journal for the Science and Technology of Polymers,2012(23):5413-5422. |
| [39] | Peng Li;Yajiang Huang;Miqiu Kong .Fractionated crystallization and morphology of PP/PS blends in the presence of silica nanoparticles with different surface chemistries[J].Colloid and polymer science,2013(7):1693-1704. |
| [40] | Peter J. Yunker;Tim Still;Matthew A. Lohr;A. G. Yodh .Suppression of the coffee-ring effect by shape-dependent capillary interactions[J].Nature,2011(Aug.18 TN.7360):308-311. |
| [41] | Kalashnikova, I.;Bizot, H.;Bertoncini, P.;Cathala, B.;Capron, I. .Cellulosic nanorods of various aspect ratios for oil in water Pickering emulsions[J].Soft matter,2013(3):952-959. |
| [42] | G?ldel, A.;Marmur, A.;Kasaliwal, G.R.;P?tschke, P.;Heinrich, G. .Shape-dependent localization of carbon nanotubes and carbon black in an immiscible polymer blend during melt mixing[J].Macromolecules,2011(15):6094-6102. |
| [43] | Jing Hu;Shuxue Zhou;Yangyi Sun .Fabrication, properties and applications of Janus particles[J].Chemical Society Reviews,2012(11):4356-4378. |
| [44] | Nagarkar, S.;Velankar, S.S. .Rheology and morphology of model immiscible polymer blends with monodisperse spherical particles at the interface[J].Journal of Rheology,2013(3):901-926. |
| [45] | Li, W.;Dong, B.;Yan, L.-T. .Janus nanorods in shearing-to-relaxing polymer blends[J].Macromolecules,2013(18):7465-7476. |
| [46] | Huang, M.;Guo, H. .The intriguing ordering and compatibilizing performance of Janus nanoparticles with various shapes and different dividing surface designs in immiscible polymer blends[J].Soft matter,2013(30):7356-7368. |
| [47] | Mulligan, M.K.;Rothstein, J.P. .Deformation and breakup of micro- and nanoparticle stabilized droplets in microfluidic extensional flows[J].Langmuir: The ACS Journal of Surfaces and Colloids,2011(16):9760-9768. |
| [48] | Wang F;Meng XF;Xu XF;Wen B;Qian ZZ;Gao XW;Ding YF;Zhang SM;Yang MS .Inhibited transesterification of PET/PBT blends filled with silica nanoparticles during melt processing[J].Polymer Degradation and Stability,2008(8):1397-1404. |
| [49] | Wu LC;Chen P;Zhang J;He JS .Inhibited transesterification and enhanced fibrillation of TLCP by nano-SiO2 in polycarbonate matrix[J].Polymer: The International Journal for the Science and Technology of Polymers,2006(1):448-456. |
| [50] | Mary Hongying Cheng;Anna C. Balazs;Chuck Yeung;Valeriy V. Ginzburg .Modeling reactive compatibilization of a binary blend with interacting particles[J].The Journal of Chemical Physics,2003(19):9044-9052. |
| [51] | Wu, D.;Sun, Y.;Lin, D.;Zhou, W.;Zhang, M.;Yuan, L. .Selective localization behavior of carbon nanotubes: Effect on transesterification of immiscible polyester blends[J].Macromolecular chemistry and physics,2011(15):1700-1709. |
| [52] | Zhang MQ.;Zeng HM.;Zhang HB.;Hen YH.;Yu G. .Two-step percolation in polymer blends filled with carbon black[J].Macromolecules,1998(19):6724-6726. |
| [53] | Dai K;Xu XB;Li ZM .Electrically conductive carbon black (CB) filled in situ microfibrillar poly(ethylene terephthalate) (PET)/polyethylene (PE) composite with a selective CB distribution[J].Polymer: The International Journal for the Science and Technology of Polymers,2007(3):849-859. |
| [54] | Song Y;Xu C;Zheng Q.Styrene-Butadiene-Styrene Copolymer Compatibilized Carbon Black/Polypropylene/Polystyrene Composites with Tunable Morphology,Electrical Conduction and Rheological Stabilities[J].SOFT MATTER,2014 |
| [55] | Jie-Feng Gao;Ding-Xiang Yan;Bo Yuan;Hua-Dong Huang;Zhong-Ming Li .Large-scale fabrication and electrical properties of an anisotropic conductive polymer composite utilizing preferable location of carbon nanotubes in a polymer blend[J].Composites science and technology,2010(13):1973-1979. |
| [56] | Xiang Gao;Shuangmei Zhang;Fang Mai .Preparation of high performance conductive polymer fibres from double percolated structure[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2011(17):6401-6408. |
| [57] | Huang J;Zhu Y;Jiang W.Parallel Carbon Nanotube Stripes in Polymer Thin Film with Remarkable Conductive Anisotropy[J].ACS Applied Materials & Interfaces,2014 |
| [58] | Cao J P;Zhao X;Zhao J et al.Improved Thermal Conductivity and Flame Retardancy in PS/PVDF Blends by Controlling Selective Localization and Surface Modification of SiC Nanoparticles[J].ACS Applied Materials & lnterfaces,2013,5(15):6915-6924. |
| [59] | Yibing Cai;Huizhen Ke;Ju Dong;Qufu Wei;Jiulong Lin;Yong Zhao;Lei Song;Yuan Hu;Fenglin Huang;Weidong Gao;Hao Fong .Effects of nano-SiO_2 on morphology, thermal energy storage, thermal stability,and combustion properties of electrospun lauric acid/PET ultrafine composite fibers as form-stable phase change materials[J].Applied energy,2011(6):2106-2112. |
| [60] | Mhike, W.;Focke, W.W.;Mofokeng, J.P.;Luyt, A.S..Thermally conductive phase-change materials for energy storage based on low-density polyethylene, soft Fischer-Tropsch wax and graphite[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2012:75-82. |
| [61] | Le, H.H.;Scho?, M.;Ilisch, S.;Gohs, U.;Heinrich, G.;Pham, T.;Radusch, H.-J. .CB filled EOC/EPDM blends as a shape-memory material: Manufacturing, morphology and properties[J].Polymer: The International Journal for the Science and Technology of Polymers,2011(25):5858-5866. |
| [62] | Zhang, W;Yao, DG;Zhang, QW;Zhou, JG;Lelkes, PI .Fabrication of interconnected microporous biomaterials with high hydroxyapatite nanoparticle loading[J].Biofabrication,2010(3):035006:1-035006:10. |
| [63] | Zhang, M.;Huang, Y.;Kong, M.;Zhu, H.;Chen, G.;Yang, Q. .Morphology and rheology of poly(l-lactide)/polystyrene blends filled with silica nanoparticles[J].Journal of Materials Science,2012(3):1339-1347. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%