微型高分子功能器件具有独特优点,发展迅速,应用广泛,是当今科学技术的重要前沿,迫切需要发展高性能多功能聚合物基微纳米复合材料,实现其微型注塑加工.介绍了近年来作者课题组在聚合物基微纳米复合材料制备及其微型注塑加工方面的研究进展:通过有机/无机杂化、固相剪切碾磨、纳米复合、分子复合及熔融共混技术等制备适合于微成型加工的高性能多功能聚合物基微纳米复合材料,如尼龙11/钛酸钡压电复合材料、聚乙烯醇/羟基磷灰石生物医用纳米复合材料、聚氨酯/碳纳米管导电复合材料等.解决了微纳米填料难分散、复合体系难加工的难题,实现了聚合物基微纳米功能复合材料的微型注塑加工,研究了其流变行为和充填行为,调控和优化了微型制品的结构与性能,为制备高性能多功能的聚合物微型器件提供了新材料、新技术和新理论.
参考文献
[1] | B. R. Whiteside;M. T. Martyn;P. D. Coates;P. S. Allan;P. R. Hornsby;G. Greenway .Micromoulding: process characteristics and product properties[J].Plastics, Rubber and Composites,2003(6):231-239. |
[2] | Heckele M;Schomburg W K .Review on Micro Molding of Thermoplastic Polymers[J].Journal of Micromechanics and Microengineering,2004,14:R1-R14. |
[3] | Giboz J;Copponnex T;Mele P .Microinjection molding of thermoplastic polymers: a review[J].Journal of Micromechanics and Microengineering,2007(6):R96-R109. |
[4] | Usama M. Attia;Silvia Marson;Jeffrey R. Alcock .Micro-injection moulding of polymer microfluidic devices[J].Microfluidics and nanofluidics,2009(1):29-43. |
[5] | B.R.Whiteside;M.T.Martyn;P.D.Coates;G.Greenway;P.Allen;P.Hornsby .Micromoulding:process measurements,product morphology and properties[J].Plastics, Rubber and Composites,2004(1):11-17. |
[6] | V. Piotter;K. Mueller;K. Plewa;R. Ruprecht;J. Hausselt .Performance and simulation of thermoplastic micro injection molding[J].Microsystem technologies,2002(6):387-390. |
[7] | Wimberger-Friedl R .Injection Molding of Sub-μ m Grating Optical Elements[J].Journal of Injection Molding Technology,2000,4(02):78-83. |
[8] | Rotting O;Ropke W;Becker H et al.Polymer Microfabrication Technologies[J].MICROSYSTEM TECHNOLOGIES,2002,8(01):32-36. |
[9] | Yao D;Kim B .Injection Molding High Aspect Ratio Microfeatures[J].Journal of Injection Molding Technology,2002,6(01):11-17. |
[10] | Yamin Pan;Suyu Shi;Wenzhong Xu;Guoqiang Zheng;Kun Dai;Chuntai Liu;Jingbo Chen;Changyu Shen .Wide distribution of shish-kebab structure and tensile property of micro-injection-molded isotactic polypropylene microparts: a comparative study with injection-molded macroparts[J].Journal of Materials Science,2014(3):1041-1048. |
[11] | Zhang J;Zhang L;Liu H et al.Study of Micro-Injection Moulding:Factors Affecting the Content of the Beta-Phase in Isotactic Polypropylene with Beta-Nucleating Agent[J].POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING,2012,51(10):1032-1037. |
[12] | Lin, X.;Caton-Rose, F.;Ren, D.;Wang, K.;Coates, P. .Shear-induced crystallization morphology and mechanical property of high density polyethylene in micro-injection molding[J].Journal of Polymer Research,2013(4):122-1-122-12. |
[13] | M. R. Kamal;J. Chu;S. Derdouri .Morphology of microinjection moulded polyoxymethylene[J].Plastics, Rubber and Composites,2010(7):332-341. |
[14] | 邓如生;魏运方;陈步宁.聚酰胺树脂及其应用[M].北京:化学工业出版社,2002 |
[15] | Choudhury A .Dielectric and Piezoelectric Properties of Polyetherimide/BaTiO3 Nanocomposites[J].Materials Chemistry and Physics,2010,121:280-285. |
[16] | 石先锐,陈英红,王琪.PA11/BaTiO3复合材料微型注塑加工中的充填行为[J].塑料,2013(04):6-10,13. |
[17] | Wang Q;Xia H S;Zhang J.RCUK Bradford Science Bridges China[A].Chengdu:Sichuan University,2013 |
[18] | Chen Y H;Shi X R;Wang Q.Proceedings of Polymer Processing Society Asia[A].Mumbai:Indian Institute of Technology,2013:8-11. |
[19] | 徐僖;王琪 .力化学反应器[P].China,95111258.9,2001-04-19. |
[20] | Xu X;Wang Q;Kong X A .A Pan-Mill Type Equipment Designed for Polymer Stress Reactions:Theoretical Analysis of Structure and Milling Process of the Equipment[J].Plastics Rubber and Composites,1996,25(03):152-158. |
[21] | 王琪,卢灿辉,夏和生.高分子力化学研究进展[J].高分子通报,2013(09):35-49. |
[22] | Zhe chen;Changsheng liu;Qi wang .Solid-Phase preparation of Ultra-Fine PA6 powder Through Pan-Milling[J].Polymer engineering and science,2001(7):1187-1195. |
[23] | Xia HS;Wang Q;Li KS;Hu GH .Preparation of polypropylene/carbon nanotube composite powder with a solid-state mechanochemical pulverization process[J].Journal of Applied Polymer Science,2004(1):378-386. |
[24] | Shao WG;Wang Q;Wang F;Chen YH .Polyamide-6/natural clay mineral nanocomposites prepared by solid-state shear milling using pan-mill equipment[J].Journal of Polymer Science, Part B. Polymer Physics,2006(1):249-255. |
[25] | Wang GL;Chen YH;Wang Q .Structure and properties of poly(ethylene terephthalate)/Na+-montmorillonite nanocomposites prepared by solid state shear milling ((SM)-M-3) method[J].Journal of Polymer Science, Part B. Polymer Physics,2008(8):807-817. |
[26] | Shao W G;Wang Q;Wang F et al.The Cutting of MultiWalled Carbon Nanotubes and Their Strong Inteffacial Interaction with Polyamide 6 in the Solid State[J].CARBON,2006,44(13):2708-2714. |
[27] | 陈晓,陈宁,王琪.聚乙烯醇/纳米羟基磷灰石复合材料微型注塑研究[J].高分子通报,2013(06):26-32. |
[28] | 王郗,杨玉军,李莉.热塑性聚乙烯醇/纳米羟基磷灰石复合材料的结构与性能[J].高分子学报,2013(10):1247-1252. |
[29] | 王琪,李莉,陈宁,刘渊,白时兵.通过分子复合超分子方法制备高性能高分子材料[J].高分子学报,2011(09):932-938. |
[30] | Wang R;Wang Q;Li L .Evaporation Behavior of Water and Its Plasticizing Effect in Modified PVA Systems[J].Polymer International,2003,52:1820-1826. |
[31] | N. Chen;L. Li;Q. Wang .New technology for thermal processing of poly(vinyl alcohol)[J].Plastics, Rubber and Composites,2007(7/8):283-290. |
[32] | L. Li;L. Mulvaney-Johnson;N. Chen .Small scale injection moulding of modified poly(vinyl alcohol)[J].Plastics, Rubber and Composites,2010(9):411-418. |
[33] | 王琪,李莉,陈宁,白时兵.聚乙烯醇热塑加工的研究[J].高分子材料科学与工程,2014(02):192-197. |
[34] | Wang B;Wang Q;Li L .Morphology and Properties of Poly (Vinyl Alcohol)/MMT Nano-Composite Prepared by Solid State Shear Milling (S3M)[J].Journal of Macromolecular Science Part B:Physics,2014,53(01):78-92. |
[35] | 王郗,李莉,陈宁,王琪.山梨醇改性聚乙烯醇体系的氢键作用及对水状态的影响[J].高等学校化学学报,2012(04):813-817. |
[36] | 夏和生;菲尔寇茨;李东旭 et al.高导电聚合物碳纳米管复合材料及其微型加工方法[P].China,W02012/089998A2,GB1108161.9,ZL201010611646.5,2013-01-23. |
[37] | Fei G X;Tuinea-Bobe C;Li D X et al.Electro-Activated Surface Micropattem Tuning for Microinjection Molded Electrically Conductive Shape Memory Polyurethane Composites[J].RSC Adv,2013,3:24132-24139. |
[38] | Xia H S.[A].Nurnberg:University of Bayreuth,2013 |
[39] | 龚启春;卢锡立;夏和生.[A].Shanghai:Donghua University,2013 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%