金属玻璃是一类具有热力学非平衡特征和亚稳特性、以金属元素为主要组分、原子排列处于无序结构的固体材料。近年来,随着金属玻璃研究领域的蓬勃发展,涌现出很多新的研究方向和热点。简要综述了近期金属玻璃在化学反应中表现出的优异催化性能和高反应速率等相关的功能性应用和基础研究进展,主要介绍了金属玻璃在降解污水中的偶氮染料方面的功能性应用和基础研究。实验结果表明,镁基和铁基金属玻璃粉降解偶氮染料的效率分别达到商业晶态铁粉的1000倍和200倍以上。而且,相对于液体雾化法制备的金属玻璃粉,用球磨粉碎法制备的金属玻璃粉反应活性更高,这可能与球磨金属玻璃粉比表面积增加、残余应力导致的反应激活能降低有关。最后对金属玻璃的功能性应用和相关基础研究的未来研究前景进行了展望。
Metallic glasses are a group of amorphous solids composed mainly of metallic elements.They stay in non-e-quilibrium states and show metastable characters.Plenty of fresh research hotspots are emerging as a result of their recent booming development.In this brief review,the excellent catalytic properties and high activity of metallic glasses in chemi-cal reactions,i.e.application in degrading azo dyes in polluted water,are overviewed.The experimental results show that the reactivity of ball-milled Mg-based and Fe-based metallic glass powders can be 1 000 and 200 times higher than the commercial Fe powders,respectively.Moreover,the reactivity also depends on the preparation methods,i.e.the ball-milled metallic glass powders are more active than the gas-atomized powders.This can be attributed to the high specific surface area and low reaction activation energy after ball-milling.The promising prospects for functional applications and related fundamental researches of metallic glasses are discussed.
参考文献
[1] | Takeshi Fujita;Pengfei Guan;Keith McKenna .Atomic origins of the high catalytic activity of nanoporous gold[J].Nature materials,2012(9):775-780. |
[2] | Haruta M .Size-and Support-Dependency in the Catalysis of Gold[J].Catalysis Today,1997,36:153-166. |
[3] | Davies R L;Etris S F .The Development and Functions of Silver in Water Purification and Disease Control[J].Catalysis Today,1997,36:107-114. |
[4] | Li W Z;Xie S S;Qian L X.Large-Scale Synthesis of A-ligned Carbon Nanotubes[J].SCIENCE,1996(274):1701-1703. |
[5] | Kang J;Qin K;Zhang H.Direct Synthesis of Fullerene-Intercalated Porous Carbon Nanofibers by Chemical Vapor Deposi-tion[J].CARBON,2012(50):5162-5166. |
[6] | Irina P.Beletskaya;Andrei V.Cheprakov .The Heck Reaction as a Sharpening Stone of Palladium Catalysis[J].Chemical Reviews,2000(8):3009-3066. |
[7] | Spiros Zafeiratos;Simone Piccinin;Detre Teschner .Alloys in catalysis: phase separation and surface segregation phenomena in response to the reactive environment[J].Catalysis science & technology,2012(9):1787-1801. |
[8] | Yu, W.;Porosoff, M.D.;Chen, J.G. .Review of Pt-based bimetallic catalysis: From model surfaces to supported catalysts (Review)[J].Chemical Reviews,2012(11):5780-5817. |
[9] | Kalme SD;Parshetti GK;Jadhav SU;Govindwar SP .Biodegradation of benzidine based dye Direct Blue-6 by Pseudomonas desmolyticum NCIM 2112[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2007(7):1405-1410. |
[10] | Amin N K .Removal of Direct Blue-106 Dye from Aqueous So-lution Using New Activated Carbons Developed from Pomegran-ate Peel:Adsorption Equilibrium and Kinetics[J].Journal of Hazardous Materials,2009,165:52-62. |
[11] | Cao J;Wei L;Huang Q et al.Reducing Degradation of Azo Dye by Zero-Valent Iron in Aqueous Solution[J].Chemo-sphere,1999,38(03):565-571. |
[12] | Jing Guo;Danjun Jiang;Yong Wu;Pei Zhou;Yeqing Lan.Degradation of methyl orange by Zn(0) assisted with silica gel[J].Journal of hazardous materials,2011:290-296. |
[13] | Patel R;Suresh S .Decolorization of Azo Dyes Using Magnesi-um-Palladium System[J].Journal of Hazardous Materials,2006,137:1729-1741. |
[14] | Wang C B;Zhang W X .Synthesizing Nanoscale Iron Particles for Rapid and Complete Dechlorination of TCE and PCBs[J].Environmental Science and Technology,1997,31:2154-2156. |
[15] | Wang WH;Dong C;Shek CH .Bulk metallic glasses[J].Materials Science & Engineering, R. Reports: A Review Journal,2004(2/3):45-89. |
[16] | Inoue A .Stabilization of Metallic Supercooled Liquid and Bulk Amorphous Alloys[J].Acta Materialia,2000,48:279-316. |
[17] | A. Lindsay Greer .Metallic glasses ... on the threshold[J].Materials Today,2009(1/2):14-22. |
[18] | Chen H S .Glassy Metals[J].Reports Progress in Physics,1980,43:353-432. |
[19] | Johnson W L .Bulk Glass-Forming Metallic Alloys:Science and Technology[J].MRS Proceedings,1999,554:311-340. |
[20] | 汪卫华.非晶态物质的本质和特性[J].物理学进展,2013(05):177-351. |
[21] | Massalski T B;Mizutani U .Electronic Structure of Hume-Roth-ery Phases[J].Progress in Materials Science,1978,22:151-262. |
[22] | Tratnyek P G;Johnson R L .Nanotechnologies for Environmen-tal Cleanup[J].Nanotoday,2006,1(02):44-48. |
[23] | Wei-xian Zhang .Nanoscale iron particles for environmental remediation: An overview[J].Journal of nanoparticle research: An interdisciplinary forum for nanoscale science and technology,2003(3/4):323-332. |
[24] | Zhang W X;Wang C B;Lien H L .Treatment of Chlorinated Organic Contaminants with Nanoscale Bimetallic Particles[J].Catalysis Today,1998,40:387-395. |
[25] | Lu Z P;Liu C T;Thompson J R et al.Structural Amorphous Steels[J].Physical Review Letters,2004,92:245503. |
[26] | Michael E. McHenry;Matthew A. Willard;David E. Laughlin .Amorphous and nanocrystalline materials for applications as soft magnets[J].Progress in materials science,1999(4):291-433. |
[27] | Zhang, C.;Zhang, H.;Lv, M.;Hu, Z. .Decolorization of azo dye solution by Fe-Mo-Si-B amorphous alloy[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2010(33/34):1703-1706. |
[28] | Zhang, C.;Zhu, Z.;Zhang, H.;Hu, Z. .On the decolorization property of Fe-Mo-Si-B alloys with different structures[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2012(1):61-64. |
[29] | Bao Lin;Xiufang Bian;Pan Wang;Guanping Luo .Application of Fe-based metallic glasses in wastewater treatment[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2012(1):92-95. |
[30] | Wang J Q;Liu Y H;Chen M W et al.Rapid Degradation of Azo Dye by Fe-Based Metallic Glass Powder[J].Advanced Functional Materials,2012,22:2567-2570. |
[31] | Wang J Q;Liu Y H;Chen MW et al.Excellent Capability in Degrading Azo Dyes by MgZn-Based Metallic Glass Powders[J].Scientific Reports,2012,2:418. |
[32] | Y.F.Zhao;J.J.Si;J.G. Song.Synthesis of Mg-Zn-Ca metallic glasses by gas-atomization and their excellent capability in degrading azo dyes[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2014:46-55. |
[33] | Wang, D.J.;Li, Z.H.;Rahman, M.A.;Shen, J. .Nanosized metal oxide and nanobelts prepared by selective dealloying of Ti-based amorphous powders[J].Langmuir: The ACS Journal of Surfaces and Colloids,2013(25):8108-8115. |
[34] | Luo, Q;Wang, WH .Rare earth based bulk metallic glasses[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2009(13):759-775. |
[35] | Wang W H .Bulk Metallic Glasses with Functional Physical Properties[J].Advanced Materials,2009,21:4524-4544. |
[36] | Axinte E A;Chirileanu MP I .Recent Progress in the Industri-aliazation of Metallic Glasses[J].Recent Patents on Materials Science,2012,5:213-221. |
[37] | Inoue A;Takeuchi A .Recent Development and Application Products of Bulk Glass Alloys[J].Acta Materialia,2011,59:2243-2267. |
[38] | Oak, Jeong-Jung;Louzguine-Luzgin, Dmitri V.;Inoue, Akihisa .Investigation of glass-forming ability, deformation and corrosion behavior of Ni-free Ti-based BMG alloys designed for application as dental implants[J].Materials science & engineering, C. Biomimetic and supramolecular systems,2009(1):322-327. |
[39] | Guoqiang Xie;Fengxiang Qin;Shengli Zhu.Ni-free Ti-based bulk metallic glass with potential for biomedical applications produced by spark plasma sintering[J].Intermetallics,2012:99-103. |
[40] | Li, J.;Shi, L.-L.;Zhu, Z.-D.;He, Q.;Ai, H.-J.;Xu, J. .Zr_(61)Ti_2Cu_(25)Al_(12) metallic glass for potential use in dental implants: Biocompatibility assessment by in vitro cellular responses[J].Materials science & engineering, C. Biomimetic and supramolecular systems,2013(4):2113-2121. |
[41] | L. Liu;C.L. Qiu;C.Y. Huang .Biocompatibility of Ni-free Zr-based bulk metallic glasses[J].Intermetallics,2009(4):235-240. |
[42] | Lu X;Huang L;Pang S et al.Formation and Biocorrosion Be-havior of Zr-Al-Co-Nb Bulk Metallic Glasses[J].Chinese Sci-ence Bulletin,2012,57:1723-1727. |
[43] | Y.B. Wang;H.F. Li;Y.F. Zheng;M. Li .Corrosion performances in simulated body fluids and cytotoxicity evaluation of Fe-based bulk metallic glasses[J].Materials science & engineering, C. Biomimetic and supramolecular systems,2012(3):599-606. |
[44] | Bruno Zberg;Peter J. Uggowitzer;Jorg F. Loffler .MgZnCa glasses without clinically observable hydrogen evolution for biodegradable implants[J].Nature materials,2009(11):887-891. |
[45] | Gu X;Zheng Y;Zhong .Corrosion of, and cellular responses to Mg-Zn-Ca bulk metallic glasses.[J].Biomaterials,2010(6):1093-1103. |
[46] | Hai-Jun Yu;Jun-Qiang Wang;Xue-Tao Shi;Dmitri V. Louzguine-Luzgin;Hong-Kai Wu;John H. Perepezko .Ductile Biodegradable Mg-Based Metallic Glasses with Excellent Biocompatibility[J].Advanced functional materials,2013(38):4793-4800. |
[47] | Li J F;Zhao D Q;Zhang ML et al.CaLi-Based Bulk Metallic Glasses with Multiple Superior Properties[J].Applied Physics Letters,2008,93:171907. |
[48] | LI JianFu,WANG JunQiang,LIU XiaoFeng,ZHAO Kun,ZHANG Bo,BAI HaiYang,PAN MingXiang,WANG WeiHua.Glassy metallic plastics[J].中国科学:物理学 力学 天文学(英文版),2010(03):409-414. |
[49] | K. Zhao;J.F. Li;D.Q. Zhao .Degradable Sr-based bulk metallic glasses[J].Scripta materialia,2009(11):1091-1094. |
[50] | Jiao, W.;Zhao, K.;Xi, X.K.;Zhao, D.Q.;Pan, M.X.;Wang, W.H. .Zinc-based bulk metallic glasses[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2010(35/36):1867-1870. |
[51] | Zhang B;Zhao DQ;Pan MX;Wang WH;Greer AL .Amorphous metallic plastic[J].Physical review letters,2005(20):5502-1-5502-4-0. |
[52] | N. Li;Y. Chen;M.Q. Jiang .A thermoplastic forming map of a Zr-based bulk metallic glass[J].Acta materialia,2013(6):1921-1931. |
[53] | William L. Johnson;Georg Kaltenboeck;Marios D. Demetriou;Joseph P. Schramm;Xiao Liu;Konrad Samwer;C. Paul Kim;Douglas C. Hofmann .Beating Crystallization in Glass-Forming Metals by Millisecond Heating and Processing[J].Science,2011(TN.6031):828-833. |
[54] | Golden Kumar;Hong X. Tang;Jan Schroers .Nanomoulding With Amorphous Metals[J].Nature,2009(7231):868-872. |
[55] | Jan Schroers .Processing of Bulk Metallic Glass[J].Advanced Materials,2010(14):1566-1597. |
[56] | Sekol, R.C.;Kumar, G.;Carmo, M.;Gittleson, F.;Hardesty-Dyck, N.;Mukherjee, S.;Schroers, J.;Taylor, A.D. .Bulk metallic glass micro fuel cell[J].Small,2013(12):2081-2085. |
[57] | Mohammad Hassan Loghmani;Abdollah Fallah Shojaei.Synthesis and characterization of Co-La-Zr-B quaternary amorphous nano alloy: Kinetic study for hydrogen generation from hydrolysis of sodium borohydride[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2013:61-66. |
[58] | N. Chen;R. Frank;N. Asao .Formation and properties of Au-based nanograined metallic glasses[J].Acta materialia,2011(16):6433-6440. |
[59] | K. Zhao;K.S. Liu;J.F. Li .Superamphiphobic CaLi-based bulk metallic glasses[J].Scripta materialia,2009(4):225-227. |
[60] | Jinshan Yu;Yi Ding;Caixia Xu .Nanoporous Metals by Dealloying Multicomponent Metallic Glasses[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(14):4548-4550. |
[61] | Thorp J C;Sieradzki K;Tang L et al.Formation of Nanopo-rous Noble Metal Thin Films by Electrochemical Dealloying of PtxSi1-x[J].Applied Physics Letters,2006,88:033110. |
[62] | Xuekun Luo;Ran Li;Zengqian Liu;Lu Huang;Minjie Shi;Tao Xu;Tao Zhang.Three-dimensional nanoporous copper with high surface area by dealloying Mg-Cu-Y metallic glasses[J].Materials Letters,2012:96-99. |
[63] | Aburada T;Fitz-Gerald J M;Scully J R .Synthesis of Nanopo-rous Copper by Dealloying of Al-Cu-Mg Amorphous Alloys in A-cidic Solution:the Effect of Nickel[J].Corrosion Science,2011,53:1627-1632. |
[64] | Ding Y;Cheng MW .Nanoporous Metals for Catalytic and Opti-cal Applications[J].MRS Bulletin,2009,34:569-576. |
[65] | Lang, X.;Hirata, A.;Fujita, T.;Chen, M. .Nanoporous metal/oxide hybrid electrodes for electrochemical supercapacitors[J].Nature nanotechnology,2011(4):232-236. |
[66] | Qian L H;Yan X Q;Fujita T et al.Surface Enhanced Raman Scattering of Nanoporous Gold:Smaller Pore Sizes Stronger En-hancements[J].Applied Physics Letters,2007,90:153120. |
[67] | Sundeep Mukherjee;Ryan C. Sekol;Marcelo Carmo;Eric I. Altman;Andre D. Taylor;Jan Schroers .Tunable Hierarchical Metallic-Glass Nanostructures[J].Advanced functional materials,2013(21):2708-2713. |
[68] | Wang J Q;Wang W H;Liu Y H et al.Characterization of Ac-tivation Energy for Flow in Metallic Glasses[J].Physical Re-view B,2011,83:012201. |
[69] | Debenedetti,PG;Stillinger,FH .Supercooled liquids and the glass transition.[J].Nature,2001(6825610):259-267. |
[70] | L. Wang;H. Bei;Y.F. Gao .Effect of residual stresses on the hardness of bulk metallic glasses[J].Acta materialia,2011(7):2858-2864. |
[71] | Meng F;Tsuchiya K;Yokoyama Y .Reversible Transition of Deformation Mode by Structural Rejuvenation and Relaxation in Bulk Metallic Glass[J].Applied Physics Letters,2012,101:121914. |
[72] | A. Slipenyuk;J. Eckert .Correlation between enthalpy change and free volume reduction during structural relaxation of Zr_(55)Cu_(30)Al_(10)Ni_5 metallic glass[J].Scripta materialia,2004(1):39-44. |
[73] | Wei Hua Wang .The elastic properties, elastic models and elastic perspectives of metallic glasses[J].Progress in materials science,2012(3):487-656. |
[74] | Spiros Zafeiratos;Simone Piccinin;Detre Teschner .Alloys in catalysis: phase separation and surface segregation phenomena in response to the reactive environment[J].Catalysis science & technology,2012(9):1787-1801. |
[75] | Yu, W.;Porosoff, M.D.;Chen, J.G. .Review of Pt-based bimetallic catalysis: From model surfaces to supported catalysts (Review)[J].Chemical Reviews,2012(11):5780-5817. |
[76] | Turnbull D .Under what Conditions can a Glass be Formed[J].CONTEMPORARY PHYSICS,1969,10:473-488. |
[77] | J.Q. Wang;Y.H. Liu;S. Imhoff.Enhance the thermal stability and glass forming ability of Al-based metallic glass by Ca minor-alloying[J].Intermetallics,2012:35-40. |
[78] | Lu Z P;Liu C T .A New Glass-Forming Ability Criterion for Bulk Metallic Glasses[J].Acta Materialia,2002,50:3501-3512. |
[79] | Dong B S;Zhou S X;Li D R et al.A New Criterion for Pre-dicting Glass Forming Ability of Bulk Metallic Glasses and Some Critical Discussions[J].Progress in Natural Science:Materials International,2011,21:164-172. |
[80] | Du XH;Huang JC;Liu CT;Lu ZP .New criterion of glass forming ability for bulk metallic glasses[J].Journal of Applied Physics,2007(8):86108-1-86108-3-0. |
[81] | Wang L M;Tian Y J;Liu R P et al.A Universal Criterion for Metallic Glass Formation[J].Applied Physics Letters,2012,100:261913. |
[82] | Y. Li;Q. Guo;J. A. Kalb;C. V. Thompson .Matching Glass-forming Ability With The Density Of The Amorphous Phase[J].Science,2008(5909):1816-1819. |
[83] | Bendert J C;Gangopadhyay A K;Mauro N A et al.Volume Expansion Measurements in Metallic Liquids and Their Relation to Fragility and Glass Forming Ability:An Energy Landscape Interpretation[J].Physical Review Letters,2012,109:185901. |
[84] | A. Hirata;L. J. Kang;T. Fujita;B. Klumov;K. Matsue;M. Kotani;A. R. Yavari;M. W. Chen .Geometric Frustration of Icosahedron in Metallic Glasses[J].Science,2013(Jul.26 TN.6144):376-379. |
[85] | Chunguang Tang;Peter Harrowell .Anomalously slow crystal growth of the glass-forming alloy CuZr[J].Nature materials,2013(6):507-511. |
[86] | Perepezko J H;Santhaweesuk C;Wang J Q.Kinetic Com-petition During Glass Formation[J].Journal ofAlloys and Com-pounds,2013 |
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