欢迎登录材料期刊网

材料期刊网

高级检索

块体非晶合金因其独特的原子结构而具有许多优异的力学性能,成为近年来材料领域的研究热点之一,但是由于其在变形过程中的室温脆性和应变软化等关键问题,一直制约其大规模工程应用。为解决此问题,块体非晶合金领域的研究者们提出了多种方案,其中利用“相变诱导塑性”概念制备块体非晶合金复合材料来韧塑化非晶合金成为卓有成效的方案之一,通过此方法成功地制备出同时具有拉伸塑性和加工硬化能力的非晶合金复合材料。然而,该类块体非晶合金复合材料要求的形成条件更严格,同时具有更复杂的多相协调变形过程和更独特的性能优化方案。从该类块体非晶合金复合材料的形成、性能特点、韧塑化机理及性能优化等方面进行综述,并对其未来发展进行了简要展望。

Bulk metallic glasses (BMGs)show unique mechanical properties due to their long-range disordering atomic structure and are regarded as one of the promising engineering materials.But their room-temperature brittleness and strain-softening during deformation have been a stumbling block for practical structural applications.To solve this problem,many approaches have been developed among which the concept of“transformation-induced plasticity”(TRIP)was proved to be effective to enhance both tensile ductility and work-hardening capability of metallic glasses.BMG composites with not only tensile ductility but also work-hardening capability have been successfully fabricated by this approach.However,the TRIP-phase-reinforced BMG composites have unique formation and deformation mechanisms.In this brief review,the for-mation,deformation behavior,optimizing strategies and ductilizing mechanism were summarized and the potential develop-ments were also discussed.

参考文献

[1] William L. Johnson .Bulk Glass-Forming Metallic alloys: Science and Technology[J].MRS bulletin,1999(10):42-56.
[2] A.Inoue .Stabilization of metallic supercooled liquid and bulk amorphous alloys[J].Acta materialia,2000(1):279-306.
[3] Christopher A. Schuh;Todd C. Hufnagel;Upadrasta Ramamurty .Mechanical behavior of amorphous alloys[J].Acta materialia,2007(12):4067-4109.
[4] Ashby MF;Greer A L .Metallic Glasses as Structural Materials[J].Scripta Materialia,2006,54:321-326.
[5] Chen MW .Mechanical behavior of metallic glasses: Microscopic understanding of strength and ductility[J].Annual review of materials research,2008(0):445-469.
[6] Z.F. Zhang;J. Eckert;L. Schultz .Difference in compressive and tensile fracture mechanisms of Zr_(59)Cu_(20)Al_(10)Ni_8Ti_3 bulk metallic glass[J].Acta materialia,2003(4):1167-1179.
[7] Wu F F;Zhang Z F;Mao S X et al.Effect of Annealing Temper-ature on the Mechanical Properties and Fracture Mechanisms of Zr56.2Ti13.8 Nb5.0 Cu6.9 Ni5.6 Be12.5 Bulk-Metallic-Glass Composite[J].Physical Review B,2007,75:134201.
[8] Bruck H.A.;Rosakis A.J. .The dynamic compressive behavior of beryllium bearing bulk metallic glasses[J].Journal of Materials Research,1996(2):503-511.
[9] Dandliker R B;Conner R D;Johnson W L .Melt Infiltration Casting of Bulk Metallic-Glass Matrix Composites[J].Journal of Materials Research,1998,13(10):2896-2901.
[10] Choi-Yim H.;Johnson WL.;Busch R. .The effect of silicon on the glass forming ability of the Cu47Ti34Zr11Ni8 bulk metallic glass forming alloy during processing of composites[J].Journal of Applied Physics,1998(12):7993-7997.
[11] H. Choi-Yim;R.D. Conner;F. Szuecs .Processing, microstructure and properties of ductile metal particulate reinforced Zr_(57)Nb_5Al_(10)Cu_(15.4)Ni_(12.6) bulk metallic glass composites[J].Acta materialia,2002(10):2737-2745.
[12] Y.F. Xue;H.N. Cai;L. Wang;F.C. Wang;H.F. Zhang;Z.Q. Hu .Deformation And Failure Behavior Of A Hydrostatically Extruded Zr_(38)Ti_(17)Cu_(10.5)Co_(12)Be_(22.5) Bulk Metallic Glass/porous Tungsten Phase Composite Under Dynamic Compression[J].Composites science and technology,2008(15/16):3396-3400.
[13] Kim YC;Fleury E;Lee JC;Kim DH .Origin of the simultaneous improvement of strength and plasticity in Ti-based bulk metallic glass matrix composites[J].Journal of Materials Research,2005(9):2474-2479.
[14] F. SZUECS;C. P. KIM;W. L. JOHNSON .MECHANICAL PROPERTIES OF Zr_(56.2)Ti_(13.8)Nb_(5.0)Cu_(6.9)Ni_(5.6)Be_(12.5) DUCTILE PHASE REINFORCED BULK METALLIC GLASS COMPOSITE[J].Acta materialia,2001(9):1507-1513.
[15] M.L. Lee;Y. Li;C.A. Schuh .Effect of a controlled volume fraction of dendritic phases on tensile and compressive ductility in La-based metallic glass matrix composites[J].Acta materialia,2004(14):4121-4131.
[16] H. Tan;Y. Zhang;Y. Li .Synthesis of La-based in-situ bulk metallic glass matrix composite[J].Intermetallics,2002(11/12):1203-1205.
[17] U. Kuhn;J. Eckert;N. Mattern .Microstructure and mechanical properties of slowly cooled Zr-Nb-Cu-Ni-Al composites with ductile bcc phase[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2004(0):322-326.
[18] Cang Fan;R. T. Ott;T. C. Hufnagel .Metallic glass matrix composite with precipitated ductile reinforcement[J].Applied physics letters,2002(6):1020-1022.
[19] U. Kuehn;J. Eckert;N. Mattern;L. Schultz .ZrNbCuNiAl bulk metallic glass matrix composites containing dendritic bcc phase precipitates[J].Applied physics letters,2002(14):2478-2480.
[20] Hays CC.;Johnson WL.;Kim CP. .Microstructure controlled shear band pattern formation and enhanced plasticity of bulk metallic glasses containing in situ formed ductile phase dendrite dispersions[J].Physical review letters,2000(13):2901-2904.
[21] Fan C;Li HQ;Kecskes LJ;Tao KX;Choo H;Liaw PK;Liu CT .Mechanical behavior of bulk amorphous alloys reinforced by ductile particles at cryogenic temperatures[J].Physical review letters,2006(14):5506-1-5506-4-0.
[22] Chen G;Bei H;Cao Y et al.Enhanced Plasticity in a Zr-Based Bulk Metallic Glass Composite with in Situ Formed Inter-metallic Phases[J].Applied Physics Letters,2009,95:081908.
[23] Hofmann DC;Suh JY;Wiest A;Duan G;Lind ML;Demetriou MD;Johnson WL .Designing metallic glass matrix composites with high toughness and tensile ductility.[J].Nature,2008(7182):1085-1089.
[24] Hofmann, DC;Suh, JY;Wiest, A;Lind, ML;Demetriou, MD;Johnson, WL .Development of tough, low-density titanium-based bulk metallic glass matrix composites with tensile ductility[J].Proceedings of the National Academy of Sciences of the United States of America,2008(51):20136-20140.
[25] Z. Zhu;H. Zhang;Z. Hu .Ta-particulate reinforced Zr-based bulk metallic glass matrix composite with tensile plasticity[J].Scripta materialia,2010(5):278-281.
[26] Qiao J W;Wang S;Zhang Y et al.Large Plasticity and Ten-sile Necking of Zr-Based Bulk-Metallic-Glass-Matrix Composites Synthesized by the Bridgman Solidification[J].Applied Physics Letters,2009,94:151905.
[27] Zackay V F;Parker E R;Fahr D et al.The Enhancement of Ductility in High-Strength Steels[J].Trans ofASM,1967,60:252-259.
[28] P.J. Jacques;Q. Furnemont;F. Lani;T. Pardoen;F. Delannay .Multiscale mechanics of TRIP-assisted multiphase steels: I. Characterization and mechanical testing[J].Acta materialia,2007(11):3681-3693.
[29] S. Pauly;J. Das;J. Bednarcik .Deformation-induced martensitic transformation in Cu-Zr-(Al,Ti) bulk metallic glass composites[J].Scripta materialia,2009(6):431-434.
[30] Sun YF;Wei BC;Wang YR;Li WH;Cheung TL;Shek CH .Plasticity-improved Zr-Cu-Al bulk metallic glass matrix composites containing martensite phase[J].Applied physics letters,2005(5):1905-1-1905-3-0.
[31] Pauly S;Das J;Duhamel C et al.Martensite Formation in a Ductile Cu47.5 Zr47.5 Al5 Bulk Metallic Glass Composite[J].Advanced Engineering Materials,2007,9:487-491.
[32] S. Pauly;G. Liu;G. Wang .Microstructural heterogeneities governing the deformation of Cu_(47.5)Zr_(47.5)Al_5 bulk metallic glass composites[J].Acta materialia,2009(18):5445-5453.
[33] S. Pauly;G. Liu;S. Gorantla .Criteria for tensile plasticity in Cu-Zr-Al bulk metallic glasses[J].Acta materialia,2010(14):4883-4890.
[34] Y. Wu;H. Wang;H.H. Wu .Formation of Cu-Zr-Al bulk metallic glass composites with improved tensile properties[J].Acta materialia,2011(8):2928-2936.
[35] Bulk Metallic Glass Composites with Transformation-Mediated Work-Hardening and Ductility[J].Advanced Materials,2010(25):2770-773,2725.
[36] Wu Y;Zhou D Q;Song W L et al.Ductilizing Bulk Metallic Glass Composite by Tailoring Stacking Fault Energy[J].Physi-cal Review Letters,2012,109:245506.
[37] Choongnyun Paul Kim;Yoon S. Oh;Sunghak Lee;Nack J. Kim .Realization of high tensile ductility in a bulk metallic glass composite by the utilization of deformation-induced martensitic transformation[J].Scripta materialia,2011(4):304-307.
[38] P. Gargarella;S. Pauly;K.K. Song .Ti-Cu-Ni shape memory bulk metallic glass composites[J].Acta materialia,2013(1):151-162.
[39] Yoon S. Oh;Choongnyun Paul Kim;Simghak Lee .Microstructure and tensile properties of high-strength high-ductility Ti-based amorphous matrix composites containing ductile dendrites[J].Acta materialia,2011(19):7277-7286.
[40] Schryvers D;Firstov G S;Seo J W et al.Unit Cell Determina-tion in CuZr Martensite by Electron Microscopy and X-Ray Dif-fraction[J].Scripta Materialia,1997,36(10):1119-1125.
[41] Seo J W;Schryvers D .TEMInvestigation of the Microstructure and Defects of CuZr Martensite.Part I:Morphology and Twin Systems[J].Acta Materialia,1998,46(04):1165-1175.
[42] Kozachkov H;Kolodziejska J;Johnson W L et al.Effect of Cooling Rate on the Volume Fraction of B Phases in a CuZrAlCo Metallic Glass Matrix Composite[J].INTERMETALLICS,2013,39:89-93.
[43] Song K K;Pauly S;Zhang Y et al.Strategy for Pinpointing the Formation of B2 CuZr in Metastable CuZr-Basrd Shape Mem-ory Alloys[J].Acta Materialia,2011,59:6620-6630.
[44] 胡壮麒,张海峰.块状非晶合金及其复合材料研究进展[J].金属学报,2010(11):1391-1421.
[45] Wu Y;Song W L;Zhang Z Y et al.Relationship between Composite Structures and Compressive Properties in CuZr-Based Bulk Metallic Glass System[J].Chinese Science Bulletin,2011,56(36):3960-3964.
[46] Simon Pauly;Jozef Bednarcik;Uta Kuhn;Jurgen Eckert .Plastically deformable Cu-Zr intermetallics[J].Scripta materialia,2010(3):336-338.
[47] Pauly S;Liu G;Wang G et al.Modeling Deformation Behav-ior of Cu-Zr-Al Bulk Metallic Glass Matrix Composites[J].Ap-plied Physics Letters,2009,95:101906.
[48] Liu Z Q;Liu G;Qu R T et al.Microstructural Percolation As-sisted Breakthrough of Trade-Off between Strength and Ductility in CuZr-Based Metallic Glass Composites[J].Scientific Re-ports,2014,4:4167.
[49] Louzguine-Luzgin, DV;Vinogradov, A;Xie, GQ;Li, S;Lazarev, A;Hashimoto, S;Inoue, A .High-strength and ductile glassy-crystal Ni-Cu-Zr-Ti composite exhibiting stress-induced martensitic transformation[J].Philosophical magazine: structure and properties of condensed matter,2009(32):2887-2901.
[50] Douglas C. Hofmann .Shape Memory Bulk Metallic Glass Composites[J].Science,2010(Sep.10 TN.5997):1294-1295.
[51] K.K. Song;S. Pauly;Y. Zhang .Triple yielding and deformation mechanisms in metastable Cu_(47.5)Zr_(47.5)Al_5 composites[J].Acta materialia,2012(17):6000-6012.
[52] Liu Z Q;Li R;Liu G et al.Pronounced Ductility in CuZrAl Ternary Bulk Metallic Glass Composites with Optimized Micro-structure through Melt Adjustment[J].AIP Advances,2012,2:032176.
[53] Zengqian Liu;Ran Li;Gang Liu .Microstructural tailoring and improvement of mechanical properties in CuZr-based bulk metallic glass composites[J].Acta materialia,2012(6/7):3128-3139.
[54] Song K K;Pauly S;Wang Z et al.Effect of TaW particles on the microstructure and mechanical properties of metastable Cu47.5 Zr47.5 Al5 alloys[J].Materials Science and Engineering A,2013,587:372-380.
[55] Z.Y. Zhang;Y. Wu;J. Zhou.Effects of Sn addition on phase formation and mechanical properties of TiCu-based bulk metallic glass composites[J].Intermetallics,2013:68-76.
[56] Z.Y. Zhang;Y. Wu;J. Zhou .Strong work-hardening behavior in a Ti-based bulk metallic glass composite[J].Scripta materialia,2013(1):73-76.
[57] Ogata S;Li J;Yip S .Ideal Pure Shear Strength of Aluminum and Copper[J].SCIENCE,2002,298:807-811.
[58] Wang XQ .Twinned structure for shape memory: First-principles calculations[J].Physical review, B. Condensed matter and materials physics,2008(9):092103-1-092103-4-0.
[59] Zhou, D.Q.;Wu, Y.;Wang, H.;Hui, X.D.;Liu, X.J.;Lu, Z.P..Alloying effects on mechanical properties of the Cu-Zr-Al bulk metallic glass composites[J].Computational Materials Science,2013:187-192.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%