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利用荧光探针法和表面张力法测定了新型双子型阳离子表面活性剂的临界胶团浓度(cmc)、最低表面张力(γcmx)、胶团微极性和胶团聚集数(Nagg),探讨了连接基团对此类表面活性剂在水溶液中聚集行为的影响.结果表明,当连接基团增长时,cmc和胶团微极性增加,ycmc增大,Nagg减少,表面活性降低,在溶液中自发形成胶团的能力减弱.

参考文献

[1] Rosen M J.Sur factants and Inter facial Phenomena[M].New York:John Wiley and Sons,Inc,2004
[2] Yaxun F;Yanbo H;Junfeng X .Synthesis and aggregation behavior of a hexameric quaternary ammonium surfactant[J].Langmuir,2011,27(04):10570.
[3] Chung-Feng Jeffery Kuo;Li-Huei Lin;Min-Yan Dong .Preparation and Properties of New Ester-Linked Cleavable Gemini Surfactants[J].Journal of Surfactants and Detergents,2011(2):195-201.
[4] Alessandro Zaggia;Lino Conte;Gennifer Padoan .Synthesis and Application of Perfluoroalkyl Quaternary Ammonium Salts in Protein-Based Fire-Fighting Foam Concentrates[J].Journal of Surfactants and Detergents,2010(1):33-40.
[5] Pei X L;Chu C D;Robert K et al.Neutron reflectometry of quaternary Gemini surfactants as a function of alkyl chain length anomalies arising from ion association and premicellar aggregation[J].Langmuir,2011,27(04):2575.
[6] Pei X L;Chu C D;Robert K et al.Adsorption of Gemini surfactants with partially fluorinated chains at three different surfaces:neutron reflectometry results[J].Langmuir,2011,27(11):656.
[7] Suresh Chavda;Ketan Kuperkar;Prashant Bahadur .Formation and Growth of Gemini Surfactant (12-s-12) Micelles as a Modulate by Spacers: A Thermodynamic and Small-Angle Neutron Scattering (SANS) Study[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,2011(5):2647-2654.
[8] Yang, JP;Xie, JY;Chen, GM;Chen, XC .Surface, Interfacial and Aggregation Properties of Sulfonic Acid-Containing Gemini Surfactants with Different Spacer Lengths[J].Langmuir: The ACS Journal of Surfaces and Colloids,2009(11):6100-6105.
[9] LU Ting,HUANG JianBin.Synthesis and properties of novel gemini surfactant with short spacer[J].科学通报(英文版),2007(19):2618-2620.
[10] Sikiric A;Primozic Y;Talmonc N et al.Effect of the spacer length on the association and adsorption behavior[J].Journal of Colloid and Interface Science,2005,28(03):473-481.
[11] 姜小明,宋磊,赵濉.荧光探针法研究双子型阳离子表面活性剂与明胶的相互作用[J].影像科学与光化学,2012(03):175-181.
[12] 姜小明,赵濉,宫清涛.新型易降解的季铵盐型Gemini表面活性剂的合成[J].合成化学,2012(01):49-51.
[13] 姜小明,于晓翠,赵濉,安静仪.荧光探针法和电子自旋共振技术研究干扰基团对烷基苯磺酸钠聚集行为的影响[J].影像科学与光化学,2011(05):383-388.
[14] Zana R.Surfactant Solutions:New Methods of Investigation[M].New York,USA:Marcel Dekker,Inc,1987
[15] 姜小明,张路,安静仪,赵濉,俞稼镛.多烷基苯磺酸钠水溶液的表面性质[J].物理化学学报,2005(12):1426-1430.
[16] Joydeep Biswas;Avinash Bajaj;Santanu Bhattacharya .Membranes of Cationic Gemini Lipids based on Cholesterol with Hydroxyl Headgroups and their Interactions with DNA and Phospholipid[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2011(3):478-486.
[17] 游毅,郑欧,邱羽,郑叶鸿,赵剑曦,韩国彬.Gemini阳离子表面活性剂的合成及其胶束生成 Gemini阳离子表面活性剂的合成及其胶束生成[J].物理化学学报,2001(01):74-78.
[18] 唐世华,黄建滨,李子臣,王传忠,李锰.Gemini(孪联)表面活性剂的界面性质与应用[J].日用化学工业,2001(06):26-29.
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