本文基于分子间质子转移和诱导分子内电荷转移(ICT)机理,合成了以萘酰亚胺为发光基团、苯甲酰为F-检测基团的荧光单体,并采用可逆加成-断裂链转移(RAFT)聚合方法将其与N-异丙基甲基丙烯酰胺(NIPAM)进行共聚,制备了一种可以用于F-检测的共聚物荧光探针poly(NIPAMm-co-Napn)(简称PNap334),并分别在二氯甲烷-二甲基亚砜(9/1,V/V)溶液和固体薄膜中考察了聚合物PNap334对F-的响应.研究发现,聚合物溶液和聚合物膜对F-均有很好的识别作用,聚合物溶液对F-的检测限为1.05 μmol/L.
参考文献
| [1] | Bin Liu;He Tian .A selective fluorescent ratiometric chemodosimeter for mercury ion[J].Chemical communications,2005(25):3156-3158. |
| [2] | Kim, Y;Gabbai, FP .Cationic Boranes for the Complexation of Fluoride Ions in Water below the 4 ppm Maximum Contaminant Level[J].Journal of the American Chemical Society,2009(9):3363-3369. |
| [3] | Yohei Kubo;Masashi Yamamoto;Masato Ikeda;Masayuki Takeuchi;Seiji Shinkai;Shigehiro Yamaguchi;Kohei Tamao .A Colorimetric and Ratiometric Fluorescent Chemosensor with Three Emission Changes: Fluoride Ion Sensing by a Triarylborane-Porphyrin Conjugate[J].Angewandte Chemie International Edition,2003(18):2036-2040. |
| [4] | Mohand Melaimi;Frangois P.Gabbal .A Heteronuclear Bidentate Lewis Acid as a Phosphorescent Fluoride Sensor[J].Journal of the American Chemical Society,2005(27):9680-9681. |
| [5] | Hudson, Z.M.;Liu, X.-Y.;Wang, S. .Switchable three-state fluorescence of a nonconjugated donor-acceptor triarylborane[J].Organic letters,2011(2):300-303. |
| [6] | Shigehiro Yamaguchi;Seiji Akiyama;Kohei Tamao .Colorimetric fluoride ion sensing by boron-containing #pi#-electron systems[J].Journal of the American Chemical Society,2001(46):11372-11375. |
| [7] | Zhaochao Xu;Sook Kyung Kim;Su Jung Han;Chongmok Lee;Gabriele Kociok-Kohn;Tony D. James;Juyoung Yoon .Ratiometric Fluorescence Sensing of Fluoride Ions by an Asymmetric Bidentate Receptor Containing a Boronic Acid and Imidazolium Group[J].European journal of organic chemistry,2009(18):3058-3065. |
| [8] | Dorsey CL;Jewula P;Hudnall TW;Hoefelmeyer JD;Taylor TJ;Honesty NR;Chiu CW;Schulte M;Gabbai FP .Fluoride ion complexation by a B-2/Hg heteronuclear tridentate lewis acid[J].Dalton transactions: An international journal of inorganic chemistry,2008(33):4442-4450. |
| [9] | Qu, Y;Hua, JL;Jiang, YH;Tian, H .Novel Side-Chain Naphthalimide Polyphenylacetylene as a Ratiometric Fluorescent Chemosensor for Fluoride Ion[J].Journal of Polymer Science. Part A, Polymer Chemistry,2009(6):1544-1552. |
| [10] | Ping Zhao;Jianbing Jiang;Bing Leng;He Tian .Polymer Fluoride Sensors Synthesized by RAFT Polymerization[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2009(20):1715-1718. |
| [11] | Yang Li;Lifeng Cao;He Tian .Fluoride Ion-Triggered Dual Fluorescence Switch Based on Naphthalimides Winged Zinc Porphyrin[J].The Journal of Organic Chemistry,2006(21):8279-8282. |
| [12] | Eun Jin Cho;Jung Wha Moon;Seung Whan Ko;Jin Yong Lee;Sook Kyung Kim;Juyoung Yoon;Kye Chun Nam .A New Fluoride Selective Fluorescent as Well as Chromogenic Chemosensor Containing a Naphthalene Urea Derivative[J].Journal of the American Chemical Society,2003(41):12376-12377. |
| [13] | Thorfinnur Gunnlaugsson;Anthony P. Davis;Mark Glynn .Fluorescent photoinduced electron transfer (PET) sensing of anions using charge neutral chemosensors[J].Chemical communications,2001(24):2556-2557. |
| [14] | Frederick M.Pfeffer;Kieren F.Lim;Kathryn J.Sedgwick .Indole as a scaffold for anion recognition[J].Organic & biomolecular chemistry,2007(11):1795-1799. |
| [15] | Massimo Boiocchi;Laura Del Boca;David Esteban Gomez .Nature of Urea-Fluoride Interaction:Incipient and Definitive Proton Transfer[J].Journal of the American Chemical Society,2004(50):16507-16514. |
| [16] | Han F;Bao YH;Yang ZG;Fyles TM;Zhao JZ;Peng XJ;Fan JL;Wu YK;Sun SG .Simple bisthiocarbonohydrazones as sensitive, selective, colorimetric, and switch-on fluorescent chemosensors for fluoride anions[J].Chemistry: A European journal,2007(10):2880-2892. |
| [17] | Zhang, J.F.;Lim, C.S.;Bhuniya, S.;Cho, B.R.;Kim, J.S. .A highly selective colorimetric and ratiometric two-photon fluorescent probe for fluoride ion detection[J].Organic letters,2011(5):1190-1193. |
| [18] | Bao, Y.;Liu, B.;Wang, H.;Tian, J.;Bai, R. .A "naked eye" and ratiometric fluorescent chemosensor for rapid detection of F- based on combination of desilylation reaction and excited-state proton transfer[J].Chemical communications,2011(13):3957-3959. |
| [19] | Fu, L.;Jiang, F.-L.;Fortin, D.;Harvey, P.D.;Liu, Y. .A reaction-based chromogenic and fluorescent chemodosimeter for fluoride anions[J].Chemical communications,2011(19):5503-5505. |
| [20] | CaoJ;ZhaoCC;FengP;Zhang Y ZhuWH .A colorimetric and ratiometric NIR fluorescent turn-on fluoride chemodosimeter based on BODIPY derivatives:high selectivity via specific Si-O cleavage[J].RSC Advances,2012,2:418-420. |
| [21] | Guo, ZQ;Zhu, WH;Xiong, YY;Tian, H .Multiple Logic Fluorescent Thermometer System Based on N-Isopropylmethacrylamide Copolymer Bearing Dicyanomethylene-4H-pyran Moiety[J].Macromolecules,2009(5):1448-1453. |
| [22] | Liu, G.;Zhou, W.;Zhang, J.;Zhao, P. .Polymeric temperature and pH fluorescent sensor synthesized by reversible addition-fragmentation chain transfer polymerization[J].Journal of Polymer Science, Part A. Polymer Chemistry,2012(11):2219-2226. |
| [23] | Jin P W;Guo Z Q;Chu J;Tan J Zhang S L Zhu W H .Screen-printed red luminescent copolymer film containing cyclometalated iridium(Ⅲ) complex as a high-permeability dissolved-oxygen sensor for fermentation bioprocess[J].Industrial & Engineering Chemistry Research,2013,52:3980-3987. |
| [24] | Jin P W;Chu J;Miao Y;Tan J Zhang S L Zhu W H .A NIR luminescent copolymer based on platinum porphyrin as high permeable dissolved oxygen sensor for microbioreactors[J].AICHE Journal,59(08):2743-2752. |
| [25] | Yang, G.;Li, S.;Wang, S.;Hu, R.;Feng, J.;Li, Y.;Qian, Y. .Novel fluorescent probes based on intramolecular charge- and proton-transfer compounds[J].Pure and Applied Chemistry,2013(7):1465-1478. |
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