利用碱处理烟草花叶病毒的生物还原性和辅助结构导向作用,在室温下以水为溶剂直接还原氯金酸制备出三角形金纳米片.采取透射电子显微镜(TEM)、高分辨透射电子显微镜(HRTEM)、选区电子衍射(SAED)和紫外-可见光谱仪(UV-Vis)等对所制备金纳米片的结构和性能进行了表征.结果显示,所制备三角形金纳米片为单晶,三角面为{111}晶面簇,边长在40~120 nm之间,厚度约为15 nm.该材料在可见光区有两个等离子共振吸收峰,在感光成像、生物检测和催化等领域具有很好的应用前景.
参考文献
[1] | Eustis S;El-Sayed MA .Why gold nanoparticles are more precious than pretty gold: Noble metal surface plasmon resonance and its enhancement of the radiative and nonradiative properties of nanocrystals of different shapes[J].Chemical Society Reviews,2006(3):209-217. |
[2] | Sujit Kumar Ghosh;Tarasankar Pal .Interparticle Coupling Effect on the Surface Plasmon Resonance of Gold Nanoparticles:From Theory to Applications[J].Chemical Reviews,2007(11):4797-4862. |
[3] | Felidj N;Grand J;Laurent G;Aubard J;Levi G;Hohenau A;Galler N;Aussenegg FR;Krenn JR .Multipolar surface plasmon peaks on gold nanotriangles[J].The Journal of Chemical Physics,2008(9):94702-1-94702-5-0. |
[4] | Jiang Y;Horimoto N N;Imura K et al.Bioimaging with two-photon-induced luminescence from triangular nanoplates and nanopartide aggregates of gold[J].Advanced Materials,2009,21(22):2309-2313. |
[5] | Li, D.;Zheng, G.;Ding, X.;Wang, J.;Liu, J.;Kong, L..DNA functionalized gold nanorods/nanoplates assembly as sensitive LSPR-based sensor for label-free detection of mercury ions[J].Colloids and Surfaces, B. Biointerfaces,2013:485-488. |
[6] | Jiale Huang;Wenta Wang;Liqin Lin;Qingbiao Li;Wenshuang Lin;Mei Li;Stephen Mann .A General Strategy for the Biosynthesis of Gold Nanoparticles by Traditional Chinese Medicines and Their Potential Application as Catalysts[J].Chemistry, an Asian journal,2009(7):1050-1054. |
[7] | Cao B;Liu B;Yang J .Facile synthesis of single crystalline gold nanoplates and SERS investigations of 4-aminothiophenol[J].CRYSTENGCOMM,2013,15(28):5735-5738. |
[8] | Millstone JE;Metraux GS;Mirkin CA .Controlling the edge length of gold nanoprisms via a seed-mediated approach[J].Advanced functional materials,2006(9):1209-1214. |
[9] | Fan X;Guo Z R;Hong J M et al.Size-controlled growth of colloidal gold nanoplates and their high-purity acquisition[J].NANOTECHNOLOGY,2010,21(10):105602. |
[10] | Xuping Sun;Shaojun Dong;Erkang Wang .Large-scale,Solution-phase Production of Microsized,Single-crystalline,Hexagonal Gold Microplates by Thermal Reduction of HAuCl_4 with Oxalic Acid[J].Chemistry Letters,2005(7):968-969. |
[11] | Chu HC;Kuo CH;Huang MH .Thermal aqueous solution approach for the synthesis of triangular and hexagonal gold nanoplates with three different size ranges[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2006(2):808-813. |
[12] | Kundu, S;Peng, LH;Liang, H .A new route to obtain high-yield multiple-shaped gold nanoparticles in aqueous solution using microwave irradiation[J].Inorganic Chemistry,2008(14):6344-6352. |
[13] | S. Shiv Shankar;Akhilesh Rai;Balaprasad Ankamwar;Amit Singh;Absar Ahmad;Murali Sastry .Biological synthesis of triangular gold nanoprisms[J].Nature materials,2004(7):482-488. |
[14] | Mohammed Fayaz, A.;Girilal, M.;Venkatesan, R.;Kalaichelvan, P.T. .Biosynthesis of anisotropic gold nanoparticles using Maduca longifolia extract and their potential in infrared absorption[J].Colloids and Surfaces, B. Biointerfaces,2011(1):287-291. |
[15] | Jiang, X.;Sun, D.;Zhang, G.;He, N.;Liu, H.;Huang, J.;Odoom-Wubah, T.;Li, Q. .Investigation of active biomolecules involved in the nucleation and growth of gold nanoparticles by Artocarpus heterophyllus Lam leaf extract[J].Journal of nanoparticle research: An interdisciplinary forum for nanoscale science and technology,2013(6):1741-1-1741-10. |
[16] | G.S. Ghodake;N.G. Deshpande;Y.P. Lee;E.S. Jin .Pear fruit extract-assisted room-temperature biosynthesis of gold nanoplates[J].Colloids and Surfaces, B. Biointerfaces,2010(2):584-589. |
[17] | Jianping Xie;Jim Yang Lee;Daniel I.C.Wang .High-Yield Synthesis of Complex Gold Nanostructures in a Fungal System[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(45):16858-16865. |
[18] | Jianping Xie;Jim Yang Lee;Daniel I.C. Wang .Synthesis of Single-Crystalline Gold Nanoplates in Aqueous Solutions through Biomineralization by Serum Albumin Protein[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(28):10226-10232. |
[19] | Lim, J.-S.;Kim, S.-M.;Lee, S.-Y.;Stach, E.A.;Culver, J.N.;Harris, M.T. .Biotemplated aqueous-phase palladium crystallization in the absence of external reducing agents[J].Nano letters,2010(10):3863-3867. |
[20] | Liu, Z.;Gu, J.;Wu, M.;Jiang, S.;Wu, D.;Wang, Q.;Niu, Z.;Huang, Y. .Nonionic block copolymers assemble on the surface of protein bionanoparticle[J].Langmuir: The ACS Journal of Surfaces and Colloids,2012(33):11957-11961. |
[21] | Fraenkel-Conrat H;Colloms M .Reactivity of tobacco mosaic virus and its protein toward acetic anhydride[J].Biochemistry,1967,6(09):2740-2745. |
[22] | Shenton W.;Young M.;Stubbs G.;Mann S.;Douglas T. .Inorganic-organic nanotube composites from template mineralization of tobacco mosaic virus[J].Advanced Materials,1999(3):253-256. |
[23] | Michael A. Bruckman;Jie Liu;Goutam Koley .Tobacco mosaic virus based thin film sensor for detection of volatile organic compounds[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2010(27):5715-5719. |
[24] | Yong Shao;Yongdong Jin;Shaojun Dong .Synthesis of gold nanoplates by aspartate reduction of gold chloride[J].Chemical communications,2004(9):1104-1105. |
[25] | Bhargava SK;Booth JM;Agrawal S;Coloe P;Kar G .Gold nanoparticle formation during bromoaurate reduction by amino acids[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(13):5949-5956. |
[26] | Choi CW;Park SH;Choi JK;Ryu KH;Park WM .Chemical degradation of tobacco mosaic virus followed by infectivity assay, reverse transcription-polymerase chain reaction and gel electrophoresis.[J].Acta Virologica: International Journal,2000(3):145-149. |
[27] | Sanghi R;Verma P .Biomimetic synthesis and characterisation of protein capped silver nanoparticles[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2009(1):501-504. |
[28] | S. Veeraapandian;Shilpa N. Sawant;Mukesh Doble .Antibacterial and Antioxidant Activity of Protein Capped Silver and Gold Nanoparticles Synthesized with Escherichia coli[J].Journal of biomedical nanotechnology,2012(1):140-148. |
[29] | Yuan Lin;Elizabeth Balizan;L. Andrew Lee .Self-Assembly of Rodlike Bio-nanoparticles in Capillary Tubes[J].Angewandte Chemie,2010(5):868-872. |
[30] | Nikoobakht B.;El-Sayed MA. .Preparation and growth mechanism of gold nanorods (NRs) using seed-mediated growth method[J].Chemistry of Materials,2003(10):1957-1962. |
[31] | Jin R;Cao Y;Mirkin C A et al.Photoinduced conversion of silver nanospheres to nanoprisms[J].SCIENCE,2001,294(5548):1901-1903. |
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