本文采用一步电化学沉积的方法在导电玻璃上先后沉积了ZnO/染料复合薄膜以及CuSCN薄层,实现仅以电沉积法制备结构为ZnO/染料/CuSCN的固态染料敏化太阳能电池,电池的光电转换效率达到0.1％.在电沉积CuSCN前,脱附电沉积制备的ZnO/染料复合薄膜中的染料以形成多孔ZnO薄膜,然后通过染料再吸附得到染料敏化ZnO纳晶多孔薄膜.在电沉积过程中,ZnO和CuSCN的晶体尺寸、晶体取向和膜层形貌都可以进行比较精准的控制.探讨了影响沉积薄膜形貌和光电转换效率的因素,如旋转圆盘电极的旋转速度、电沉积温度以及染料敏化剂的选择.本文报道的低温电沉积制备全固态太阳能电池的方法为制备柔性染料敏化太阳能电池提供了一种新的思路.
参考文献
| [1] | O'Regan B;Gr(a)tzel M .A low-cost,high-efficiency solar cell based on dye-sensitized colloidal TiO2 films[J].NATURE,1991,353:737-740. |
| [2] | Hara K.;Kinoshita T.;Sayama K.;Sugihara H.;Arakawa H.;Horiguchi T. .Highly efficient photon-to-electron conversion with mercurochrome-sensitized nanoporous oxide semiconductor solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2000(2):115-134. |
| [3] | Keita Kakiuchi;Eiji Hosono;Shinobu Fujihara .Enhanced photoelectrochemical performance of ZnO electrodes sensitized with N-719[J].Journal of Photochemistry and Photobiology, A. Chemistry,2006(1/2):81-86. |
| [4] | Hosono, E;Fujihara, S;Honna, I;Zhou, HS .The fabrication of an upright-standing zinc oxide nanosheet for use in dye-sensitized solar cells[J].Advanced Materials,2005(17):2091-2094. |
| [5] | Baxter J B;Aydil E S .Nanowire-based dye-sensitized solar cells[J].Appllied Physics Letters,2005,86:053114. |
| [6] | Law M;Greene LE;Johnson JC;Saykally R;Yang PD .Nanowire dye-sensitized solar cells[J].Nature materials,2005(6):455-459. |
| [7] | B. Szyszka .Transparent and conductive aluminum doped zinc oxide films prepared by mid-frequency reactive magnetron sputtering[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1999(1/2):164-169. |
| [8] | Tadatsugu Minami;Jun-ichi Oda;Jun-ichi Nomoto;Toshihiro Miyata .Effect of target properties on transparent conducting impurity-doped ZnO thin films deposited by DC magnetron sputtering[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2010(1):385-390. |
| [9] | Tsukasa Yoshida;Mamiko Iwaya;Hiroaki Ando;Torsten Oekermann;Kazuteru Nonomura;Derck Schlettwein;Dieter Wohrle;Hideki Minoura .Improved photoelectrochemical performance of electrodeposited ZnO/EosinY hybrid thin films by dye re-adsorption[J].Chemical communications,2004(4):400-401. |
| [10] | Tsukasa Yoshida;Thierry Pauporte;Daniel Lincot .Cathodic Electrodeposition of ZnO/Eosin Y Hybrid Thin Films from Oxygen-Saturated Aqueous Solution of ZnCl_2 and Eosin Y[J].Journal of the Electrochemical Society,2003(9):C608-C615. |
| [11] | Yoshida T;Zhang J B;Komatsu D;Sawatani S Minoura H Pauporté T Lincot D Oekermann T Schlettwein D Tada H W(o)hrle D Funabiki K Matsui M Miura H Yanagi H .Electrodeposition of inorganic/organic hybrid thin films[J].Advanced Functional Materials,2009,19:17-43. |
| [12] | Jingbo Zhang;Lina Sun;Keigo Ichinose .Effect of anchoring groups on electrochemical self-assembly of ZnO/xanthene dye hybrid thin films[J].Physical chemistry chemical physics: PCCP,2010(35):10494-10502. |
| [13] | Peng Liu;Weiying Li;Jingbo Zhang .Electrodeposition and Photocatalytic Selectivity of ZnO/Methyl Blue Hybrid Thin Films[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(32):14279-14284. |
| [14] | Yoshida T.;Minoura H. .Electrochemical self-assembly of dye-modified zinc oxide thin films[J].Advanced Materials,2000(16):1219-1222. |
| [15] | John E. Jaffe;Tiffany C. Kaspar;Timothy C. Droubay .Electronic and Defect Structures of CuSCN[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(18):9111-9117. |
| [16] | Yong Ni;Zhengguo Jin;Ke Yu;Yanan Fu;Tongjun Liu;Tao Wang .Electrochemical deposition characteristics of p-CuSCN on n-ZnO rod arrays films[J].Electrochimica Acta,2008(20):6048-6054. |
| [17] | Liu C L;Wu W B;Liu K F;Li M Hu G D Xu H Y .Orientation growth and electrical property of CuSCN films associated with the surface states[J].CRYSTENGCOMM,2012,14:6750-6754. |
| [18] | Sun L;Ichinose K;Sekiya T;Sugiura T Yoshida T .Cathodic electrodeposition of p-CuSCN nanorod and its dyesensitized photocathodic property[J].Physics Procedia,2011,14:12-24. |
| [19] | S. Peulon;D. Lincot .Mechanistic study of cathodic electrodeposition of zinc oxide and zinc hydroxychloride films from oxygenated aqueous zinc chloride solutions[J].Journal of the Electrochemical Society,1998(3):864-874. |
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