以聚乙烯醇(PVA)为粘胶剂,将四苯基乙烯(TPE)及其衍生物聚集体固载在滤纸上,以有效发挥AIE的特性.为了考察PVA浓度对四苯基乙烯及其衍生物聚集态下发光性能的影响规律,本文研究了PVA浓度分别与TPE、1,1,2,2-四-(4-(5-溴戊氧基)苯基)乙烯(TPE-OR)、(4-二苯基)苯基二苯并富烯(BpPDBF)三种化合物荧光强度之间的关系.实验结果表明,即使水含量不同,三种化合物均对PVA浓度依赖性存在着荧光强度极大值.说明提高PVA浓度,增加溶液粘度,将会使TPE及其衍生物分子内旋转进一步受限,但同时也会妨碍TPE及其衍生物形成更大的聚集体,即荧光强度的变化是这两种作用的综合体现.另外,固载于滤纸上的TPE、TPE-OR、BpPDBF薄膜可以用于检测特定有机溶剂及硝基化合物的挥发气氛,并具有比较灵敏的响应.
参考文献
| [1] | jingdong Luo;Zhiliang Xie;Jacky W.Y.Lam;Lin Cheng;Haiying Chen;Chengfeng Qiu;Hoi Sin Kwok;Xiaowei Zhan;Daoben Zhu;Ben Zhong Tang .Aggregation-Induced Emission of 1-Methyl-1,2,3,4,5-Pentaphenylsilole[J].Chemical communications,2001(18):1740-1741. |
| [2] | Han T Y;Feng X;Shi J B;Tong B Dong Y F Lam J W Y Dong Y P Tang B Z .DMF-induced emission of an arylsubstituted pyrrole derivative:a solid thermo-responsive material to detect temperature in a specific range[J].Journal of Materials Chemistry C,2013,1(45):7534-7539. |
| [3] | Han T Y;Hong Y N;Xie N;Chen S J Zhao N Zhao E G Lam J W Y Sung H H Y Dong Y P Tong B Tang B Z .Defect sensitive crystals based on diaminomaleonitrilefunctionalized Sehiff base with aggregation-enhanced emission[J].Journal of Materials Chemistry C,2013,1(44):7314-7320. |
| [4] | Han, T.;Zhang, Y.;Feng, X.;Lin, Z.;Tong, B.;Shi, J.;Zhi, J.;Dong, Y. .Reversible and hydrogen bonding-assisted piezochromic luminescence for solid-state tetraaryl-buta-1,3-diene[J].Chemical communications,2013(63):7049-7051. |
| [5] | Xiao Feng;Bin Tong;Jinbo Shen .Aggregation-Induced Emission Enhancement of Aryl-Substituted Pyrrole Derivatives[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2010(50):16731-16736. |
| [6] | Xiaoliang Lucy;Weijun Zhao;Junqing Shi .Reversible Switching Emissions of Tetraphenylethene Derivatives among Multiple Colors with Solvent Vapor, Mechanical, and Thermal Stimuli[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2012(41):21967-21972. |
| [7] | Sanji, T.;Nakamura, M.;Kawamata, S.;Tanaka, M.;Itagaki, S.;Gunji, T. .Fluorescence "turn-on" detection of melamine with aggregation-induced-emission-active tetraphenylethene[J].Chemistry: A European journal,2012(48):15254-15257. |
| [8] | Shi, J.;Wu, Y.;Sun, S.;Tong, B.;Zhi, J.;Dong, Y. .Tunable fluorescence conjugated copolymers consisting of tetraphenylethylene and fluorene units: From aggregation-induced emission enhancement to dual-channel fluorescence response[J].Journal of Polymer Science, Part A. Polymer Chemistry,2013(2):229-240. |
| [9] | Wang, J.;Mei, J.;Hu, R.;Sun, J.Z.;Qin, A.;Tang, B.Z. .Click synthesis, aggregation-induced emission, E/Z isomerization, self-organization, multiple chromisms of pure stereoisomers of a tetraphenylethene-cored luminogen[J].Journal of the American Chemical Society,2012(24):9956-9966. |
| [10] | Wang, J.;Mei, J.;Zhao, E.;Song, Z.;Qin, A.;Sun, J.Z.;Tang, B.Z. .Ethynyl-capped hyperbranched conjugated polytriazole: Click polymerization, clickable modification, and aggregation-enhanced emission[J].Macromolecules,2012(19):7692-7703. |
| [11] | 荧光增强型共轭聚电解质的合成及对肝素的双通道检测[J].高分子学报,2012(12):1482-1490. |
| [12] | Leung, C.W.T.;Hong, Y.;Chen, S.;Zhao, E.;Lam, J.W.Y.;Tang, B.Z. .A photostable AIE luminogen for specific mitochondrial imaging and tracking[J].Journal of the American Chemical Society,2013(1):62-65. |
| [13] | Kai Li;Zhenshu Zhu;Pingqiang Cai .Organic Dots with Aggregation-Induced Emission (AIE Dots) Characteristics for Dual-Color Cell Tracing[J].Chemistry of Materials: A Publication of the American Chemistry Society,2013(21):4181-4187. |
| [14] | Wei Qin;Dan Ding;Jianzhao Liu;Wang Zhang Yuan;Yong Hu;Bin Liu;Ben Zhong Tang .Biocompatible Nanoparticles with Aggregation-Induced Emission Characteristics as Far-Red/Near-Infrared Fluorescent Bioprobes for In Vitro and In Vivo Imaging Applications[J].Advanced functional materials,2012(4):771-779. |
| [15] | Wang, Z.;Chen, S.;Lam, J.W.Y.;Qin, W.;Kwok, R.T.K.;Xie, N.;Hu, Q.;Tang, B.Z. .Long-term fluorescent cellular tracing by the aggregates of AIE bioconjugates[J].Journal of the American Chemical Society,2013(22):8238-8245. |
| [16] | Zhu Z F;Zhao X Y;Qin W;Chen G D Qian J Xu Z P .Fluorescent AIE dots encapsulated organically modified silica (ORMOSIL) nanopartides for two-photon cellular imaging[J].Science China Chemistry,2013,56(09):1247-1252. |
| [17] | DAN DING;KAI LI;BIN LIU .Bioprobes Based on AIE Fluorogens[J].Accounts of Chemical Research,2013(11):2441-2453. |
| [18] | Dong YQ;Lam JWY;Qin AJ;Li Z;Sun JZ;Sung HHY;Williams ID;Tang BZ .Switching the light emission of (4-biphenylyl)phenyldibenzofulvene by morphological modulation: crystallization-induced emission enhancement[J].Chemical communications,2007(1):40-42. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%