欢迎登录材料期刊网

材料期刊网

高级检索

以广东某垃圾焚烧炉为研究对象,应用富集因子法、主成分分析法对其周边环境空气中金属( Fe、Al、Mg、Cu、Zn、Mn、Ba、Pb、Cr、Ni、Bi和Cd)含量及来源进行分析.结果如下:研究区域环境空气中各金属含量(各点均值)(ng·m-3)为:Fe (1092—3487)> Al(939—3126)> Mg(716—1339)> Cu (63.4—995)> Zn (227—427)>Mn(162—291.1)>Ba(61.4—372)>Pb(21.9—41.8)> Cr(12.3—25.7)>Ni (5.70—15.5)> Bi (0.70—1.22)>Cd (0.42—0.82).相关分析和主成分分析发现,研究区域Fe与Ni、Cr、Mn、Ba主要来自于焚烧炉释放, Zn、Cd、Pb、Bi和Cu则来自于研究区域周边的交通污染源,而Al和Mg则主要来自于地壳或土壤背景值.

Taking a MSWI in Guangdong as a study subject, the concentrations and source of metals Fe, Al, Mg, Cu,Zn, Mn, Ba, Pb, Cr, Ni, Bi and Cd were analyzed through enrichment factor and principal component analysis method. The results showed that the concentrations of metals( ng·m-3 ) in TSP were Fe (1092—3487) >Al(939—3126) > Mg(716—1339)> Cu (63.4—995) > Zn (227—427)>Mn(162 —291.1)>Ba(61.4—372)>Pb(21.9—41.8)> Cr(12.3— 25.7) >Ni ( 5?70—15. 5 ) > Bi ( 0. 70—1. 22 ) >Cd ( 0. 42—0. 82 ) . The correlation analysis, principal component analysis results showed that Fe, Ni, Cr, Mn, Ba mainly came from MSWI emission. Zn, Cd, Pb, Bi and Cu mainly originated from traffic pollution in the surrounding of the study area. Al and Mg mainly originted from crust and natural background.

参考文献

[1] Hu CW.;Chao MR.;Wu KY.;Chang-Chien GP.;Lee WJ.;Chang LW.;Lee WS. .Characterization of multiple airborne particulate metals in the surroundings of a municipal waste incinerator in Taiwan[J].Atmospheric environment,2003(20):2845-2852.
[2] Min Li;Song Hu;Jun Xiang;Lu-Shi Sun;Pei-Sheng Li;Sheng Su;Xue-Xin Sun .Characterization of Fly Ashes from Two Chinese Municipal Solid Waste Incinerators[J].Energy & Fuels,2003(6):1487-1491.
[3] Sakai S;Sawell S E;Chandler A J et al.World trends in municipal solid waste management[J].WASTE MANAGEMENT,1996,16(5/6):341-350.
[4] Kogevinas M .Human health effects of dioxins: cancer, reproductive and endocrine system effects.[J].Human reproduction update,2001(3):331-339.
[5] Montse Mari;Marti Nadal;Marta Schuhmacher;Jose L. Domingo .Monitoring PCDD/Fs, PCBs and metals in the ambient air of an industrial area of Catalonia, Spain[J].Chemosphere: Environmental toxicology and risk assessment,2008(6):990-998.
[6] Leung, AOW;Duzgoren-Aydin, NS;Cheung, KC;Wong, MH .Heavy metals concentrations of surface dust from e-waste recycling and its human health implications in southeast China[J].Environmental Science & Technology,2008(7):2674-2680.
[7] F. C. Bretzel;M. Calderisi .Contribution of a municipal solid waste incinerator to the trace metals in the surrounding soil[J].Environmental Monitoring and Assessment: An International Journal,2011(1/4):523-533.
[8] Rimmer DL;Vizard CG;Pless-Mulloli T;Singleton I;Air VS;Keatinge ZAF .Metal contamination of urban soils in the vicinity of a municipal waste incinerator: One source among many[J].Science of the Total Environment,2006(1/3):207-216.
[9] Bache C A;Gutenmann W H;Rutzke M et al.Concentrations of metals in grasses in the vicinity of a municipal refuse incinerator[J].Archives of Environmental Contamination and Toxicology,1991,20(4):538-542.
[10] Wrobel A.;Maenhaut W.;Rokita E. .Transport of traffic-related aerosols in urban areas[J].Science of the Total Environment,2000(2/3):199-211.
[11] C. Bilos;J. C. Colombo;C. N. Skorupka .Sources, distribution and variability of airborne trace metals in La Plata City area, Argentina[J].Environmental Pollution,2001(1):149-158.
[12] Manisha Singh;Peter A. Jaques;Constantinos Sioutas .Size distribution and diurnal characteristics of particle-bound metals in source and receptor sites of the Los Angeles Basin[J].Atmospheric environment,2002(10):1675-1689.
[13] Gao Y;Arimoto R;Duce R A et al.Input of atmospheric trace elements and mineral matter to the Yellow Sea during the spring of a low-dust year[J].Journal of Geophysical Research:Atmospheres,1992,97(D4):3767-3777.
[14] Gao Y.;Nelson ED.;Field MP.;Ding Q.;Li H.;Sherrell RM.;Gigliotti CL. Van Ry DA.;Glenn TR.;Eisenreich SJ. .Characterization of atmospheric trace elements on PM2.5 particulate matter over the New York-New Jersey harbor estuary[J].Atmospheric environment,2002(6):1077-1086.
[15] Xilong Wang;Tsutomu Sato;Baoshan Xing .Size distribution and anthropogenic sources apportionment of airborne trace metals in Kanazawa, Japan[J].Chemosphere: Environmental toxicology and risk assessment,2006(11):2440-2448.
[16] Kuo,C.-Y.;Wang,J.-Y.;Liu,W.-T.;Lin,P.-Y.;Tsai,C.-T.;Cheng,M.-T. .Evaluation of the vehicle contributions of metals to indoor environments[J].Journal of exposure science & environmental epidemiology,2012(5):489-495.
[17] 刘凤娴,彭林,牟玲,胡冬梅,史美鲜,杨花.忻州市市区大气颗粒物中的元素组成特征[J].环境化学,2014(02):313-320.
[18] 赵金平,谭吉华,毕新慧,盛国英,傅家谟.广州市灰霾期间大气颗粒物中无机元素的质量浓度[J].环境化学,2008(03):322-326.
[19] 张春荣,吴正龙,田红,高宗军.青岛市区大气降尘重金属的特征和来源分析[J].环境化学,2014(07):1187-1193.
[20] Guelen Guellue;Gueray Dogan;Guerdal Tuncel .Atmospheric trace element and major ion concentrations over the eastern Mediterranean Sea: Identification of anthropogenic source regions[J].Atmospheric environment,2005(34):6376-6387.
[21] D. Voutsa;C. Samara;Th. Kouimtzis;K. Ochsenkuehn .Elemental composition of airborne particulate matter in the multi-impacted urban area of Thessaloniki, Greece[J].Atmospheric environment,2002(28):4453-4462.
[22] 魏复盛.中国土壤元素背景值[M].北京:中国环境科学出版社,1990
[23] Wang K S;Chiang K Y;Tsai C C et al.The effects of FeCl3 on the distribution of the heavy metals Cd,Cu,Cr,and Zn in a simulated multimetal incineration system[J].Environment International,2001,26(4):257-263.
[24] v.Bruder-Hubscher;F.Lagarde;M.J.F.Leroy;C.Coughanowr .Application of a sequential extraction procedure to study the release of elements from municipal solid waste incineration bottom ash[J].Analytica chimica acta,2002(2):285-295.
[25] Santos, R. M.;Mertens, G.;Salman, M.;Cizer, O.;Gerven, T. van.Comparative study of ageing, heat treatment and accelerated carbonation for stabilization of municipal solid waste incineration bottom ash in view of reducing regulated heavy metal/metalloid leaching.[J].Journal of Environmental Management,2013:807-821.
[26] Janaka Gunawardena;Prasanna Egodawatta;Godwin A. Ayoko;Ashantha Goonetilleke .Role of traffic in atmospheric accumulation of heavy metals and polycyclic aromatic hydrocarbons[J].Atmospheric environment,2012(Jul.):502-510.
[27] Herngren L;Goonetilleke A;Ayoko GA .Analysis of heavy metals in road-deposited sediments[J].Analytica chimica acta,2006(2):270-278.
[28] Sartor J D;Boyd G B;Agardy F J.Water pollution aspects of street surface contaminants[J].Journal (Water Pollution Control Federation),1974:458-467.
[29] Janssen NAH.;Vanderjagt K.;Harssema H.;Hoek G.;Vanmansom DFM. .MASS CONCENTRATION AND ELEMENTAL COMPOSITION OF AIRBORNE PARTICULATE MATTER AT STREET AND BACKGROUND LOCATIONS[J].Atmospheric environment,1997(8):1185-1193.
[30] Aslam J;Khan S A;Khan S H .Heavy metals contamination in roadside soil near different traffic signals in Dubai, United Arab Emirates[J].Journal of Saudi Chemical Society,2011,17(2013):315-319.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%