磺胺类抗生素(SAs)是水环境中广泛存在的一类新型污染物,因其具有“准”持久性和潜在的生态风险而备受关注.表层水体中,SAs具有多种解离形态,表现为“复合”的光化学行为,从而影响其环境归趋及生态风险.本文总结了水环境中SAs光化学行为研究的最新进展,介绍了该类污染物的直接、间接和自敏化光解动力学,讨论了pH和溶解性物质对其光解动力学的影响机制,评述了其光化学转化路径及羟基自由基氧化机理,简述了该类抗生素的光催化降解和光致毒性效应.最后,对SAs的光化学行为研究进行了展望.
参考文献
| [1] | YI-LUO;DAQING MAO;MICHAL RYSZ.Trends in Antibiotic Resistance Genes Occurrence in the Haihe River, China[J].Environmental Science & Technology: ES&T,201019(19):7220-7225. |
| [2] | 王丹;隋倩;赵文涛;吕树光;邱兆富;余刚.中国地表水环境中药物和个人护理品的研究进展[J].科学通报,2014(9):743-751. |
| [3] | 葛林科;张思玉;谢晴;陈景文.抗生素在水环境中的光化学行为[J].中国科学B辑,2010(2):124-135. |
| [4] | Homem, V.;Santos, L..Degradation and removal methods of antibiotics from aqueous matrices - a review.[J].Journal of Environmental Management,201110(10):2304-2347. |
| [5] | Verlicchi, P.;Al Aukidy, M.;Zambello, E..Occurrence of pharmaceutical compounds in urban wastewater: Removal, mass load and environmental risk after a secondary treatment-A review[J].Science of the Total Environment,2012:123-155. |
| [6] | 贾瑷;胡建英;孙建仙;施嘉琛.环境中的医药品与个人护理品[J].化学进展,2009(2):389-399. |
| [7] | Yang, Chun-Chen;Huang, Cheng-Liang;Cheng, Ta-Chih;Lai, Hong-Thih.Inhibitory effect of salinity on the photocatalytic degradation of three sulfonamide antibiotics[J].International Biodeterioration & Biodegradation,2015:116-125. |
| [8] | 葛林科;任红蕾;鲁建江;高会;张蓬;那广水.我国环境中新兴污染物抗生素及其抗性基因的分布特征?[J].环境化学,2015(5):875-883. |
| [9] | 杨常青;王龙星;侯晓虹;陈吉平.大辽河水系河水中16种抗生素的污染水平分析[J].色谱,2012(8):756-762. |
| [10] | Ruijie Zhang;Jianhui Tang;Jun Li;Qian Zheng;Di Liu;Yingjun Chen;Yongde Zou;Xiaoxiang Chen;Chunling Luo;Gan Zhang.Antibiotics in the offshore waters of the Bohai Sea and the Yellow Sea in China: Occurrence, distribution and ecological risks[J].Environmental Pollution,2013Mar.(Mar.):71-77. |
| [11] | NA Guangshui;GU Jia;GE Linke;ZHANG Peng;WANG Zhen;LIU Chunyang;ZHANG Lin.Detection of 36 antibiotics in coastal waters using high performance liquid chromatography-tandem mass spectrometry[J].中国海洋湖沼学报（英文版）,2011(05):1093-1102. |
| [12] | Ruicheng Wei;Feng Ge;Siyu Huang;Ming Chen;Ran Wang.Occurrence of veterinary antibiotics in animal wastewater and surface water around farms in Jiangsu Province, China[J].Chemosphere: Environmental toxicology and risk assessment,201110(10):1408-1414. |
| [13] | Guangshui Na;Xiaodan Fang;Yaqi Cai;Linke Ge;Humin Zong;Xiutang Yuan;Ziwei Yao;Zhifeng Zhang.Occurrence, distribution, and bioaccumulation of antibiotics in coastal environment of Dalian, China[J].Marine pollution bulletin,20131/2(1/2):233-237. |
| [14] | Lei Jiang;Xialin Hu;Daqiang Yin;Hongchang Zhang;Zhenyang Yu.Occurrence, distribution and seasonal variation of antibiotics in the Huangpu River Shanghai China[J].Chemosphere: Environmental toxicology and risk assessment,20116(6):822-828. |
| [15] | Wenhui Li;Yali Shi;Lihong Gao;Jiemin Liu;Yaqi Cai.Occurrence of antibiotics in water, sediments, aquatic plants, and animals from Baiyangdian Lake in North China[J].Chemosphere: Environmental toxicology and risk assessment,201211(11):1307-1315. |
| [16] | Qian Zheng;Ruijie Zhang;Yinghui Wang;Xiaohui Pan;Jianhui Tang;Gan Zhang.Occurrence and distribution of antibiotics in the Beibu Gulf, China: Impacts of river discharge and aquaculture activities[J].Marine environmental research,2012Jul.(Jul.):26-33. |
| [17] | Lin Xu;Michal Rysz;Yi Luo.Occurrence and Transport of Tetracycline, Sulfonamide, Quinolone, and Macrolide Antibiotics in the Haihe River Basin, China[J].Environmental Science & Technology: ES&T,20115(5):1827-1833. |
| [18] | Wei-hai Xu;Gan Zhang;Shi-chun Zou;Xiang-dong Li;Yu-chun Liu.Determination of selected antibiotics in the Victoria Harbour and the Pearl River, South China using high-performance liquid chromatography-electrospray ionization tandem mass spectrometry[J].Environmental Pollution,20073(3):672-679. |
| [19] | Shichun Zou;Weihai Xu;Ruijie Zhang;Jianhui Tang;Yingjun Chen;Gan Zhang.Occurrence and distribution of antibiotics in coastal water of the Bohai Bay,China: Impacts of river discharge and aquaculture activities[J].Environmental Pollution,201110(10):2913-2920. |
| [20] | Ximei Liang;Baowei Chen;Xiangping Nie;Zhen Shi;Xiaoping Huang;Xiangdong Li.The distribution and partitioning of common antibiotics in water and sediment of the Pearl River Estuary, South China[J].Chemosphere: Environmental toxicology and risk assessment,201311(11):1410-1416. |
| [21] | Ruijie Zhang;Gan Zhang;Qian Zheng;Jianhui Tang;Yingjun Chen;Weihai Xu;Yongde Zou;Xiaoxiang Chen.Occurrence and risks of antibiotics in the Laizhou Bay, China: Impacts of river discharge[J].Ecotoxicology and Environmental Safety,2012:208-215. |
| [22] | Lei, Xiaoning;Lu, Jianjiang;Liu, Zilong;Tong, Yanbin;Li, Shanman.Concentration and distribution of antibiotics in water-sediment system of Bosten Lake, Xinjiang[J].Environmental Science and Pollution Research,20153(3):1670-1678. |
| [23] | 葛林科;李凯;杨凯;那广水;于春艳;张蓬;姚子伟.UV-vis光照下唑类抗菌药氟康唑的光化学反应类型[J].环境科学,2013(8):3132-3136. |
| [24] | Jonathan K. Challis;Jules C. Carlson;Ken J. Friesen.Aquatic photochemistry of the sulfonamide antibiotic sulfapyridine[J].Journal of Photochemistry and Photobiology, A. Chemistry,2013:14-21. |
| [25] | Ma Jesus Garcia-Galdn;M. Silvia Diaz-Cruz;Damid Barcelo.Kinetic studies and characterization of photolytic products of sulfamethazine, sulfapyridine and their acetylated metabolites in water under simulated solar irradiation[J].Water research: A journal of the international water association,20123(3):711-722. |
| [26] | Lian, Junfeng;Qiang, Zhimin;Li, Mengkai;Bolton, James R.;Qu, Jiuhui.UV photolysis kinetics of sulfonamides in aqueous solution based on optimized fluence quantification[J].Water research: A journal of the international water association,2015May 15(May 15):43-50. |
| [27] | Li, Yingjie;Wei, Xiaoxuan;Chen, Jingwen;Xie, Hongbin;Zhang, Ya-nan.Photodegradation mechanism of sulfonamides with excited triplet state dissolved organic matter: A case of sulfadiazine with 4-carboxybenzophenone as a proxy[J].Journal of hazardous materials,2015Jun.15(Jun.15):9-15. |
| [28] | Anne L.Boreen;William A.Arnold;Kristopehr McNeill.Photochemical Fate of Sulfa Drugs in the Aquatic Environment:Sulfa Drugs Containing Five-Membered Heterocyclic Groups[J].Environmental Science & Technology: ES&T,200414(14):3933-3940. |
| [29] | Boreen AL;Arnold WA;McNeill K.Triplet-sensitized photodegradation of sulfa drugs containing six-membered heterocyclic groups: Identification of an SO2 extrusion photoproduct[J].Environmental Science & Technology: ES&T,200510(10):3630-3638. |
| [30] | Florence Bonvin;Julien Omlin;Rebecca Rutler.Direct Photolysis of Human Metabolites of the Antibiotic Sulfamethoxazole: Evidence for Abiotic Back-Transformation[J].Environmental Science & Technology: ES&T,201313(13):6746-6755. |
| [31] | Junfeng Niu;Lilan Zhang;Yang Li;Jinbo Zhao;Sidan Lv;Keqing Xiao.Effects of environmental factors on sulfamethoxazole photodegradation under simulated sunlight irradiation: Kinetics and mechanism[J].环境科学学报（英文版）,2013(06):1098-1106. |
| [32] | Xiaoxuan Wei;Jingwen Chen;Qing Xie.Distinct Photolytic Mechanisms and Products for Different Dissociation Species of Ciprofloxacin[J].Environmental Science & Technology: ES&T,20139(9):4284-4290. |
| [33] | LINKE GE;JINGWEN CHEN;XIAOXUAN WEI.Aquatic Photochemistry of Fluoroquinolone Antibiotics: Kinetics, Pathways, and Multivariate Effects of Main Water Constituents[J].Environmental Science & Technology: ES&T,20107(7):2400-2405. |
| [34] | 葛林科;陈景文;张思玉;蔡喜运;王壮;王春玲.水中氟喹诺酮类抗生素加替沙星的光降解[J].科学通报,2010(11):996-1001. |
| [35] | Werner JJ;Arnold WA;McNeill K.Water hardness as a photochemical parameter: Tetracycline photolysis as a function of calcium concentration, magnesium concentration, and pH[J].Environmental Science & Technology: ES&T,200623(23):7236-7241. |
| [36] | Junfeng Niu;Yang Li;Wenlong Wang.Light-source-dependent role of nitrate and humic acid in tetracycline photolysis: Kinetics and mechanism[J].Chemosphere: Environmental toxicology and risk assessment,201311(11):1423-1429. |
| [37] | Li, Yang;Niu, Junfeng;Shang, Enxiang;Crittenden, John Charles.Synergistic Photogeneration of Reactive Oxygen Species by Dissolved Organic Matter and C-60 in Aqueous Phase[J].Environmental Science & Technology: ES&T,20152(2):965-973. |
| [38] | HUI LIU;HUIMIN ZHAO;XIE QUAN.Formation of Chlorinated Intermediate from Bisphenol A in Surface Saline Water under Simulated Solar Light Irradiation[J].Environmental Science & Technology: ES&T,200920(20):7712-7717. |
| [39] | Zhang, Ruochun;Sun, Peizhe;Boyer, Treavor H.;Zhao, Lin;Huang, Ching-Hua.Degradation of Pharmaceuticals and Metabolite in Synthetic Human Urine by UV, UV/H2O2, and UV/PDS[J].Environmental Science & Technology: ES&T,20155(5):3056-3066. |
| [40] | Tias Paul;Michael L. Machesky;Timothy J. Strathmann.Surface Complexation of the Zwitterionic Fluoroquinolone Antibiotic Ofloxacin to Nano-Anatase TiO2 Photocatalyst Surfaces[J].Environmental Science & Technology: ES&T,201221(21):11896-11904. |
| [41] | Katherine Neafsey;Xia Zeng;Ann T. Lemley.Degradation of Sulfonamides in Aqueous Solution by Membrane Anodic Fenton Treatment[J].Journal of Agricultural and Food Chemistry,20102(2):1068-1076. |
| [42] | Junwei Zhang.Degradation mechanism of sulfa drugs based on theoretical prediction and experimental examination in TiO_2 suspension[J].Research on Chemical Intermediates,20143(3):1089-1102. |
| [43] | Yong Chen;Hua Li;Zongping Wang;Tao Tao;Chun Hu.Photoproducts of tetracycline and oxytetracycline involving self-sensitized oxidation in aqueous solutions: Effects of Ca2+ and Mg2+[J].环境科学学报（英文版）,2011(10):1634-1639. |
| [44] | Carolina Baeza;Detlef R.U. Knappe.Transformation kinetics of biochemically active compounds in low-pressure UV Photolysis and UV/H_2O_2 advanced oxidation processes[J].Water research: A journal of the international water association,201115(15):4531-4543. |
| [45] | 孙兴霞;许毓.水中磺胺类抗生素的光降解及富里酸对其光降解的影响[J].中国科学技术大学学报,2013(8):654-660. |
| [46] | 黄春年;李学德;花日茂.磺胺二甲嘧啶在水溶液中的光化学降解[J].环境污染与防治,2011(12):59-64. |
| [47] | 马艳;高乃云;张东;卢宁;顾玉亮;周新宇.UV C辐照降解水中磺胺类药物[J].净水技术,2014(3):75-78,83. |
| [48] | Zhimin Qiang;Craig Adams.Potentiometric determination of acid dissociation constants (pK_a) for human and veterinary antibiotics[J].Water research: A journal of the international water association,200412(12):2874-2890. |
| [49] | JENNIFER J. GUERARD;YU-PING CHIN;HEATH MASH.Photochemical Fate of Sulfadimethoxine in Aquaculture Waters[J].Environmental Science & Technology: ES&T,200922(22):8587-8592. |
| [50] | Jannis Wenk;Urs von Gunten;Silvio Canonica.Effect of Dissolved Organic Matter on the Transformation of Contaminants Induced by Excited Triplet States and the Hydroxyl Radical[J].Environmental Science & Technology: ES&T,20114(4):1334-1340. |
| [51] | 赵家兴;陈景文;张思玉;尉小旋.Mg^2＋配位作用对磺胺嘧啶结构及吸收光谱影响的计算模拟及验证。[J].环境化学,2011(12):1975-1982. |
| [52] | Danna Zhou;Wenyu Huang;Feng Wu.Photodegradation of Chloromycetin in aqueous solutions: kinetics and influencing factors[J].Reaction kinetics,mechanisms and catalysis,20101(1):45-53. |
| [53] | Beate Fulda;Andreas Voegelin;Felix Maurer.Copper Redox Transformation and Complexation by Reduced and Oxidized Soil Humic Acid. 1. X-ray Absorption Spectroscopy Study[J].Environmental Science & Technology: ES&T,201319(19):10903-10911. |
| [54] | 李英杰;尉小旋;乔显亮;陈景文.溶解性有机质及Cu（Ⅱ）配位对磺胺二甲基嘧啶光转化的影响[J].科学通报,2015(30):2900-2906. |
| [55] | 路莹;鲁楠;赵雅辉;袁星.磺胺甲唑在磷钨酸／二氧化钛复合膜上的光催化降解[J].环境化学,2014(4):649-655. |
| [56] | Christian Silvio Pomelli;Cinzia Chiappe;Andrea Lapi.Accelerating effect of imidazolium ionic liquids on the singlet oxygen promoted oxidation of thioethers: A theoretical study[J].Journal of Photochemistry and Photobiology, A. Chemistry,2012:59-65. |
| [57] | Marianna Czaplicka.Photo-degradation of chlorophenols in the aqueous solution[J].Journal of hazardous materials,20061/3(1/3):45-59. |
| [58] | Ana Paula S Batista;Flavio Chiquetto C Pires;Antonio Carlos S C Teixeira.Photochemical degradation of sulfadiazine, sulfamerazine and sulfamethazine: Relevance of concentration and heterocyclic aromatic groups to degradation kinetics[J].Journal of Photochemistry and Photobiology, A. Chemistry,2014:40-46. |
| [59] | 焦晓微;赵丹;罗一;曲景平.磺胺甲恶唑在羟基自由基作用下降解机理的密度泛函研究[J].安全与环境学报,2013(2):40-46. |
| [60] | Calza P;Medana C;Pazzi M;Baiocchi C;Pelizzetti E.Photocatalytic transformations of sulphonamides on titanium dioxide[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,20041(1):63-69. |
| [61] | 梁凤颜;尹平河;赵玲;吴楚萍.水体中微污染磺胺嘧啶光催化降解行为[J].生态环境学报,2009(4):1227-1230. |
| [62] | Abellan MN;Bayarri B;Gimenez J;Costa J.Photocatalytic degradation of sulfamethoxazole in aqueous suspension of TiO2[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,20073/4(3/4):233-241. |
| [63] | Lei Xu;Geriletu Wang;Fengya Ma;Yahui Zhao;Nan Lu;Yihang Guo;Xia Yang.Photocatalytic degradation of an aqueous sulfamethoxazole over the metallic silver and Keggin unit codoped titania nanocomposites[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,201218(18):7039-7046. |
| [64] | Diugosz, Maciej;Zmudzki, Pawel;Kwiecien, Anna;Szczubialka, Krzysztof;Krzek, Jan;Nowakowska, Maria.Photocatalytic degradation of sulfamethoxazole in aqueous solution using a floating TiO2-expanded perlite photocatalyst[J].Journal of hazardous materials,2015Nov.15(Nov.15):146-153. |
| [65] | Jung J;Kim Y;Kim J;Jeong DH;Choi K.Environmental levels of ultraviolet light potentiate the toxicity of sulfonamide antibiotics in Daphnia magna.[J].Ecotoxicology,20081(1):37-45. |
| [66] | Photodegradation of sulfamethoxazole in various aqueous media: Persistence, toxicity and photoproducts assessment[J].Chemosphere: Environmental toxicology and risk assessment,200910(10):1292. |
| [67] | SERGE CHIRON;CLAUDIO MINERO;DAVIDE VIONE.Photodegradation Processes of the Antiepileptic Drag Carbamazepine,Relevant To Estuarine Waters[J].Environmental Science & Technology: ES&T,200619(19):5977-5983. |
| [68] | Kenshi Sankoda;Tomonori Kuribayashi;Kei Nomiyama.Occurrence and Source of Chlorinated Polycyclic Aromatic Hydrocarbons (CI-PAHs) in Tidal Flats of the Ariake Bay, Japan[J].Environmental Science & Technology: ES&T,201313(13):7037-7044. |
| [69] | 胡学锋;吴蕾;骆永明.苯胺在含富里酸／Fe（Ⅲ）高盐水体中的光氯化[J].环境化学,2014(4):611-616. |
| [70] | Dodd MC;Shah AD;Von Gunten U;Huang CH.Interactions of fluoroquinolone antibacterial agents with aqueous chlorine: Reaction kinetics, mechanisms, and transformation pathways[J].Environmental Science & Technology: ES&T,200518(18):7065-7076. |
| [71] | Edhlund BL;Arnold WA;McNeill K.Aquatic photochemistry of nitrofuran antibiotics[J].Environmental Science & Technology: ES&T,200617(17):5422-5427. |
| [72] | 任红蕾;张蓬;李凯;葛林科;那广水;姜华.水中氟喹诺酮类抗生素光降解过程中抑菌活性的变化[J].环境化学,2014(5):753-759. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%