具有良好生物相容性和生物活性的纳米羟基磷灰石(Ca10(PO4)6(OH)2,HA)被广泛应用在生物医学、环境功能材料等领域.反相微乳液法(W/O)制备纳米HA为实现高活性、低团聚、均一颗粒形貌及尺寸控制提供一种重要途径.综述目前国内外反相微乳液法制备纳米HA的研究进展及其机理；总结水油比、表面活性剂种类、助表面活性剂类型、反应物浓度等因素对制备纳米HA的影响；对反相微乳液法制备纳米HA的研究发展趋势进行前景展望.
参考文献
| [1] | Ramachandre R R .Solid state synthesis and thermal stability of HAP and HAP-β-TCP composite ceramic powders[J].Journal of Materials Science: Materials in Medicine,1997,8(08):511-518. |
| [2] | Monma H;Ueno S;Kanazawa T .Pmperties of hydroxyapatite prepared by the hydro lysis of tricalcium phosphate[J].Journal of Chemical Technology and Biotechnology,1981,31:15. |
| [3] | Monma H;Kamiya T .Preparation of hydroxyapatite by the hydrolysis of brushite[J].Journal of Materials Science,1987,22:4247. |
| [4] | 王欣宇,韩颖超,李世普,闫玉华.自燃烧法制备纳米羟基磷灰石粉的机理探讨及影响因素[J].硅酸盐学报,2002(05):564-568. |
| [5] | Liu H S;Chin T S;Lai L S et al.Hydroxyapatite synthesized by a simplified hydrothermal method[J].Ceramics International,1997,23:19. |
| [6] | Yubao L;de Groot K;de Wijn J et al.Morphology and composition of nanograde calcium phosphate needle-like crystal formed by simple hydrothermal theatment[J].Journal of Materials Science: Materials in Medicine,1994,5(6/7):326. |
| [7] | Zhang S;Gonsalves KE .Preparation and characterization of thermally stable nanohydroxyapatite[J].Journal of Materials Science. Materials in Medicine,1997(1):25-28. |
| [8] | Hattori T;Iwadate Y .Hydrothermal preparation of calcium hydroxyapatite powders[J].Journal of the American Ceramic Society,1990,73(06):1803. |
| [9] | Mobasherpour I;SoulatiHeshajin M;Kazemzadeh A et al.Synthesis of nano-crystalline hydroxyapatite by using precipitation method[J].Journal of Alloys and Compounds,2007,430:330. |
| [10] | Pach L;Duncan S;Roy R et al.Morphological control of precipitated calcium carbonates and phosphates by colloidal additives[J].Journal of Materials Science,1996,31:65. |
| [11] | Kordas G;Trapalis C C .Fourier transform and multi dimensional EPR spectroscopy for the characterization of Sol-Gel derived hydroxyapatite[J].Journal of Sol-Gel Science and Technology,1997,9:17. |
| [12] | 宋云京,温树林,李木森,宿庆财,姜庆辉.高品质羟基磷灰石纳米粉体的制备及物理化学过程研究[J].无机材料学报,2002(05):985-991. |
| [13] | Lim GK.;Ng SC.;Chew CH.;Gan LM.;Wang J. .PROCESSING OF HYDROXYAPATITE VIA MICROEMULSION AND EMULSION ROUTES[J].Biomaterials,1997(21):1433-1439. |
| [14] | Lim G K;Wang J;Ng S C et al.Nanosized hydroxyapatite powders from microemulsions and emulsions stabilized by a biodegradable surfactant[J].Journal of Materials Chemistry,1999,9:1635. |
| [15] | 李世普;陈晓明.生物陶瓷[M].武汉:武汉工业大学出版社,1998:45. |
| [16] | Lim G K;Wang J;Ng S C et al.Processing of fine hydroxyapatite powders via an inverse microemulsion route[J].Materials Letters,1996,28:431. |
| [17] | 郭广生,孙玉绣,王志华,郭洪猷.反相微乳液法制备棒状羟基磷灰石纳米粒子[J].化学通报（印刷版）,2005(05):368-372. |
| [18] | 周炬,张筠,侯哲哲.两种反相微乳液体系合成纳米羟基磷灰石的比较[J].河北化工,2005(03):52-54. |
| [19] | Lin Kaili;Chang Jiang;Cheng Rongming et al.Hydrothermal microemulsion synthesis of stoichiometric single crystal hydroxyapatite nanorods with mono-dispersion and narrow-size distribution[J].Materials Letters,2007,61:1683-1867. |
| [20] | Zheng Xianpeng;Liu Shuyuan;Liu Qing et al.Synthesis of hydroxyapatite in microemulsion and the study of adsorption on cadmium in wastewater[J].Bioinformatics and Biomedical Engineering,2009,3:1-4. |
| [21] | Li Shipu;Zhang Shicheng;Chen Wenjie et al.Effects of hydroxyapatite ultrafine powder on colony formation and cytoskeletons of MGC-803 cell[J].Bioceraraics,1996,9:225-227. |
| [22] | Yang Chun;Yang Piaoping;Wang Wenxin et al.Synthesis and characterization of Eu-doped hydroxyapatite through a microwave assisted microemulsion process[J].Solid State Sciences,2009,11:1923. |
| [23] | 任卫,李世普,王友法,曹献英,陈晓明.超细羟基磷灰石颗粒的反相微乳液合成[J].硅酸盐通报,2002(06):27-31. |
| [24] | Li, H.;Zhu, M.;Li, L.;Zhou, C. .Processing of nanocrystalline hydroxyapatite particles via reverse microemulsions[J].Journal of Materials Science,2008(1):384-389. |
| [25] | 王风贺,雷武,彭加斌,夏明珠,魏运洋,王风云.AOT/异辛烷反相微乳液的增溶与电导性质研究[J].南京理工大学学报（自然科学版）,2008(02):257-260. |
| [26] | 李玲,刁兆玉,王仲妮.不同因素对CTAB/TX-100微乳液相图的影响[J].化学世界,2011(04):206-210. |
| [27] | G. GUO;Y. SUN;Z. WANG .Preparation of hydroxyapatite nanoparticles by reverse microemulsion[J].Ceramics International,2005(6):869-872. |
| [28] | 侯长军,刁显珍,唐一科,霍丹群,董亮,范小花,韦立凡.十六烷基三甲基溴化铵/正丁醇/正辛烷/水油包水型微乳体系的相行为[J].化学工程,2008(04):41-44. |
| [29] | 马兰,张军,温喜梅.助剂链长对十六烷基三甲基溴化铵反相微乳液制备纳米HA形貌的影响[J].硅酸盐通报,2008(05):1081-1084. |
| [30] | Sujoy Kumar Samanta;Tanmay Basak .Enhanced microwave processing of oil-water emulsions confined within ceramic and ceramic/metallic or composite plates[J].Chemical Engineering and Processing,2009(2):706-721. |
| [31] | Sager W;Eicke H F;Sun W .Precipitation of nanometre-sized uniform ceramic particles in emulsions[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,1993,79(2/3):199-216. |
| [32] | Yukio Sakabe;Yasuhisa Yamashita;Hiroshi Yamamoto .Dielectric properties of nano-crystalline BaTiO_3 synthesized by micro-emulsion method[J].Journal of the European Ceramic Society,2005(12):2739-2742. |
| [33] | 陈文君,李干佐,周国伟,陈华,韩君颜.作为微反应器的微乳液体系研究进展[J].日用化学工业,2002(02):57-60. |
| [34] | 白玮,沈青.结构化乳液的理论、制备与应用Ⅰ.连续相结构化乳液[J].高分子通报,2009(11):49-56. |
| [35] | 张晓光,董金凤,张高勇,周晓海,洪昕林.有机盐对水/AOT/醇反相微乳体系电导行为的影响[J].物理化学学报,2006(01):22-27. |
| [36] | 刘恋,田森林.微乳液增溶吸收甲苯传质机理及影响因素[J].化学工程,2010(05):5-8. |
| [37] | 崔海萍,闫军,叶明惠.超细氧化铝粉体的表面改性研究[J].材料科学与工艺,2008(03):407-409. |
| [38] | 喻发全.微乳液结构及其应用[J].武汉化工学院学报,1999(02):12-16. |
| [39] | C.S.Chern .Emulsion polymerization mechanisms and kinetics[J].Progress in Polymer Science,2006(5):443-486. |
| [40] | 任卫,李世普,王友法.微乳液法制备纳米羟基磷灰石的机理[J].材料研究学报,2004(03):257-264. |
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