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以乙二胺四乙酸为掺杂剂,过硫酸铵为氧化剂,采用自组装的方法合成了掺杂态的聚苯胺纳米管.通过扫描电镜(SEM),透射电镜(TEM),红外光谱(IR),X射线衍射(XRD),UV-Vis和四探针法等测试手段对产物的形貌、结构和性能进行了表征.分析了不同乙二胺四乙酸和苯胺的摩尔比对产物的形貌和导电性能的影响.结果表明,不同乙二胺四乙酸和苯胺的摩尔比对产物有一定的影响,随着摩尔比的增加,产物纳米管的直径增大;合成的聚苯胺纳米管具有一定的导电性.

参考文献

[1] Wei ZX.;Zhang ZM.;Wan MX. .Formation mechanism of self-assembled polyaniline micro/nanotubes[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(3):917-921.
[2] Youqing Shen;Meixiang Wan .Tubular Polypyrrole Synthesized by in Situ Doping Polymerization in the Presence of Organic Function Acids as Dopants[J].Journal of Polymer Science, Part A. Polymer Chemistry,1999(10):1443-1449.
[3] Wan MX.;Li JC. .Formation mechanism of polyaniline microtubules synthesized by a template-free method[J].Journal of Polymer Science, Part A. Polymer Chemistry,2000(13):2359-2364.
[4] Lijuan Zhang;Yunze Long;Zhaojia Chen;Meixiang Wan .The Effect of Hydrogen Bonding on Self-Assembled Polyaniline Nanostructures[J].Advanced functional materials,2004(7):693-698.
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