采用HF/HNO3溶液化学腐蚀,在硅片上制备减反射效果优良的多孔硅太阳电池减反射膜,借助原子力显微镜(AFM)和X光电子谱(XPS)对其表面形貌和成分进行观察,发现该膜与电化学阳极腐蚀得到的多孔硅具有相似性,其主要成分为非化学配比的硅的氧化物SiOx(X<2).采用带积分球的光度分光计,测得形成多孔硅减反射膜后,硅片表面反射率大大下降,,在波长330~800nm范围反射率只有1.5~2.9%.研究指出这种强减反射作用,与多孔硅具有合适的折射率及其多孔特性的光陷阱作用有关.
参考文献
[1] | Canham L T .Silicon quantum wire array fabrication by electrochemical and chemical dissolution of wafers[J].Applied Physics Letters,1990(57):1046-1050. |
[2] | Koyama H;Araki M;Yamamoto Y et al.Visi-ble photoluminescence of porous Si and its related optical properties[J].Japanese Journal of Applied Physics,1991(30):3606-3010. |
[3] | Bilyalov RR.;Wettling W.;Stalmans L.;Poortmans J.;Nijs J. Schirone L.;Sotgiu G.;Strehlke S.;Levy-Clement C.;Ludemann R. .Multicrystalline silicon solar cells with porous silicon emitter[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2000(4):391-420. |
[4] | SAADOUN M;Ezzaouia H;Bessais B et al.Formation of porous sili con for large area silicon solar cells:A new method[J].Solar Energy Materials and Solar Cells,1999,59(04):377-385. |
[5] | Vitanov P.;Tyutyundzhiev N.;Delibasheva M.;Goranova E. Peneva M.;Kamenova M. .HIGH-EFFICIENCY SOLAR CELL USING A THIN POROUS SILICON LAYER[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1997(1/2):299-303. |
[6] | Schirone L.;Califano FP.;Sotgiu G. .CHEMICALLY ETCHED POROUS SILICON AS AN ANTI-REFLECTION COATING FOR HIGH EFFICIENCY SOLAR CELLS[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1997(1/2):296-298. |
[7] | Bastide S.;Strehlke S.;Levy-Clement C.;Albu-Yaron A. .Formation and characterization of porous silicon layers for application in multicrystalline silicon solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,1999(4):393-417. |
[8] | Ludemann R;Damiani B;Rohatgi.A.Novel processing of solar cells with porous silicon texturing[A].,2000:299-302. |
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