欢迎登录材料期刊网

材料期刊网

高级检索

用差示扫描量热仪(DSC)研究了4,4′-二氨基二苯甲烷环氧树脂(TGDDM)/4,4′-二氨基二苯基砜(DDS)环氧树脂体系及其多壁碳纳米管复合物的固化行为.碳纳米管加入TGDDM/DDS体系后,起始固化反应速率增大,达到最大反应速率的时间减小,说明碳纳米管对环氧树脂的固化反应有催化作用.和纯树脂相比,在固化反应初期碳纳米管复合物的活化能降低.在玻璃化现象出现以前,Kamal的固化动力学模型得到的结果与实验数据相当吻合.

参考文献

[1] Ajayan P.M. .Nanotubes from Carbon[J].Chemical Reviews,1999(6):1787-1799.
[2] Thostenson E T;Ren Z;Chou T W .[J].Composites Science and Technology,2001,61:1899-1912.
[3] Prime R B;Turi E A.Thermal Characterization of Polymeric Materials[M].Academic Press,New York,1997:1376-1379.
[4] Sourour S;Kamal M R .[J].Thermochimica Acta,1976,14:41-59.
[5] Cole K C;Hechler J J;Noel D .[J].Macromolecules,1991,24:3098-3110.
[6] Shaffer MSP.;Windle AH.;Fan X. .Dispersion and packing of carbon nanotubes[J].Carbon: An International Journal Sponsored by the American Carbon Society,1998(11):1603-1612.
[7] Ryan M E;Dutta A .[J].Polymer,1979,20:203-206.
[8] Keenan M R .[J].Journal of Applied Polymer Science,1987,33:1725-1734.
[9] Hseih HK.;Woo EM.;Su CC. .Cure kinetics and inter-domain etherification in an amine-cured phenoxy/epoxy system[J].Polymer: The International Journal for the Science and Technology of Polymers,1998(11):2175-2183.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%