为了改善Ti基储氢合金的电化学性能,采用Si元素部分替代Mn元素的方法,分析研究了Ti基储氢合金Ti03Zr0.225V0.25Mn0.25-xNi0.5Six的相结构及电化学性能.结果表明,合金均由六方结构的C14型Laves主相和立方结构的TiNi第二相构成;随着Si元素替代量x的增大,合金的活化性能降低,而循环稳定性得到很大程度的改善.
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