Interactions Between Metal Ions and Carbohydrates: Coordination Behavior of D-Ribose to Lanthanide Ions

稀土学报(英文版), 2002, 20(5): 339-342.

1.The State Key Laboratory of Rare Earth Materials Chemistry and Applications, Department of Chemical Biology, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

2.The State Key Laboratory of Rare Earth Materials Chemistry and Applications, Department of Chemical Biology, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

3.The State Key Laboratory of Rare Earth Materials Chemistry and Applications, Department of Chemical Biology, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

4.The State Key Laboratory of Rare Earth Materials Chemistry and Applications, Department of Chemical Biology, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

基金项目: 国家自然科学基金(29671002,39730160 and 20023005) 国家重点基础研究发展计划(973计划)(G1998061307)

Interactions Between Metal Ions and Carbohydrates: Coordination Behavior of D-Ribose to Lanthanide Ions

Keywords： rare earths

Lanthanum chloride α-D-ribopyranose pentahydrate complex was prepared and speculated its structure from the similar IR spectra of corresponding praseodymium and neodymium-D-ribose complexes, which reveal the coordination behavior of D-ribose to lanthanide ions and give us a model of the interactions between metal ions and carbohydrates.

参考文献

[1]	Gyurcsik B;Nagy L .Carbohydrates as ligands: coordination equilibria and structure of the metal complexes[J].Coordination Chemistry Reviews,2000,203:81.
[2]	卢然,倪嘉缵.稀土对肝脏作用的机制[J].中国稀土学报,2002(03):193-198.
[3]	Yano S;Otsuka T.Sugar-Metal Ion Interactions[M].Metal Ions Biol Syst (H Sigel eds), Mareel Dekker, New York,1996:27.
[4]	Araki K;Shiraishi S .Mode of interaction of Cu(Ⅱ) and Mn(Ⅱ) with D-ribose and D-arabinose as studied by 13C-n.m.r. spectrometry[J].Carbohydrate Release,1986,148:121.
[5]	Angyal S J;Craig D C.Complex formation between polyols and rare earth cations[A].Carbohydrate Research,1993:1.
[6]	苏允兰,杨丽敏,刘维,翁诗甫,吴瑾光.镧与半乳糖醇的两种配合物的FTIR和Raman光谱研究[J].光谱学与光谱分析,2002(03):401-402.
[7]	YANG L M;Zhao Y;Xu Y Z.Complexation of trivalent lanthanide cations by D-ribose in the solid state[A].Carbohydrate Research,2001:91.
[8]	Yang LM.;Wu JG.;Weng SF.;Jin XL. .Interactions between metal ions and carbohydrates: FT-IR and Raman spectra study of NdCl3 center dot alpha-D-ribopyranose center dot 5H(2)O[J].Journal of Molecular Structure,2002(1):49-57.
[9]	YANG L M;Wang Z M;Zhao Y et al.Complexation of trivalent lanthanide cations by inositol in solid state. The crystal structure and FT-IR study of PrCl3myo-inositol9H2O[J].Carbohydrate Release,2000,329:847.
[10]	Morel-Desrosiers N;Lhermet C;Morel J P .Interactions between cations and sugars Part 7.-Gibbs energies enthalpies and entropies of association of the trivalent lanthanide cations with ribose in water at 298.15 K[J].Journal of the Chemical Society,Faraday Transactions,1993,89(08):1223.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

Interactions Between Metal Ions and Carbohydrates: Coordination Behavior of D-Ribose to Lanthanide Ions

参考文献