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使用原位插层聚合法制备了一系列不同有机蒙脱土含量的基于异佛尔酮二异氰酸酯的脂肪族聚氨酯弹性体/蒙脱土纳米复合材料,通过X射线衍射(XRD)、差示扫描量热测试(DSC)、热重分析(TGA)等研究了有机蒙脱土含量对脂肪族聚氨酯弹性体结构与性能的影响.XRD结果表明,成功地合成了聚氨酯/蒙脱土插层型纳米复合材料.TGA结果表明,纳米复合材料的热稳定性随着有机蒙脱土含量的增加而提高.有机蒙脱土对聚氨酯基体有较好的增强和增韧作用,而当有机蒙脱土含量为7%时,纳米复合材料的力学性能最佳.

参考文献

[1] Chattopadhyay DK;Sreedhar B;Raju KVSN .Thermal stability of chemically crosslinked moisture-cured polyurethane coatings[J].Journal of Applied Polymer Science,2005(6):1509-1518.
[2] Kim BK.;Seo JW.;Jeong HM. .Morphology and properties of waterborne polyurethane/clay nanocomposites[J].European Polymer Journal,2003(1):85-91.
[3] Mariarosaria Tortora;Giuliana Gorrasi;Vittoria Vittoria;Giancarlo Galli;Stefano Ritrovati;Emo Chiellini .Structural characterization and transport properties of organically modified montmorillonite/polyurethane nanocomposites[J].Polymer: The International Journal for the Science and Technology of Polymers,2002(23):6147-6157.
[4] Woo Jin Choi;Se Hoon Kim;Young Jin Kim;Sung Chl Kim .Synthesis of chain-extended organifier and properties of polyurethane/clay nanocomposites[J].Polymer: The International Journal for the Science and Technology of Polymers,2004(17):6045-6057.
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