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为明确溅射偏压对ITO薄膜性质的影响,用射频磁控溅射法于室温在玻璃衬底制备出ITO透明导电薄膜,研究了不同偏压下ITO薄膜的生长模式、光学和电学性能.结果表明:随着偏压的增加,薄膜沉积模式经历了沉积、沉积和扩散、表面脱附3种方式;AFM和SEM显示,偏压为100 V时,膜层表面光洁、均匀,粗糙度最小,均方根粗糙度为1.61 nm;XRD分析表明偏压会影响与薄膜的择优取向,偏压为100 V时,薄膜晶粒取向为(222)面;薄膜偏压为120 V时,薄膜的光电性能最佳,电阻率最低为2.59×10-4Ω.cm,可见光区的平均透过率在85%以上;偏压的大小使薄膜的吸收边发生了"蓝移"或"红移".

To clarify the effect of sputtering bias-vohage on the photoelectric properties of indium tin oxide (ITO) thin films, the ITO thin fihns were deposited by RF magnetron sputtering on glass substrates at room temperature and the growth modes, electrical and optical properties of these films were investigated as a func- tion of the sputtering bias-voltage. The results show that, with the increasing of sputtering bias-voltage, tile films deposition undergoes three modes "deposition", "diffusion" and "desorption". AFM and SEM investigations reveal that the films have very smooth and uniform surface with a smallest root mean square roughness of 1.61 nm at 100 V sputtering bias-voltage. XRD results show the deposited films demonstrate a preferred orien- tation of (222) with a similar crystal structure at 100 V sputtering bias-voltage. The films with the sputtering bias-voltage of 120 V in this study show that the lowest resistivity of 2.59× 10 -4Ω . cm and the optical trans- mittance in visible range of the films is over 85 %. "Blue shift" or "red shift" of the absorption edge can be observed with different bias-voltages.

参考文献

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[3] Aldrin Antony;M. Nisha;R. Manoj;M.K. Jayaraj .Influence of target to substrate spacing on the properties of ITO thin films[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2004(1/4):294-301.
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[6] Vidhya, V.S.;Malathy, V.;Balasubramanian, T.;Saaminathan, V.;Sanjeeviraja, C.;Jayachandran, M. .Influence of RF power on the growth mechanism, preferential orientation and optoelectronic properties of nanocrystalline ITO films[J].Current applied physics: the official journal of the Korean Physical Society,2011(3):286-294.
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