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分别用恒电位阶跃法、恒电流放电法和电化学阻抗法研究了不同荷电状态和不同温度下MlNi3.75Co0.65Mn0.4Al0.2贮氢合金电极中氢的扩散系数,并对各种方法的测试结果及其在实际应用中的优缺点进行了比较和讨论.测试结果表明,室温下MlNi3.75Co0.65Mn0.4Al0.2贮氢合金电极中氢的扩散系数随其荷电量的增大而减小;同一荷电状态的MlNi3.75Co0.65Mn0.4Al0.2贮氢合金电极中氢的扩散系数随温度的升高而增大;该电极中氢扩散的活化能为17.9kJ/mol~19.8kJ/mol.

参考文献

[1] Van Rijiswick M H J.[A].Oxford:Pergamon Press,1978:261.
[2] Tatsuo Nishna;Hironori Ura;Isamu Uchida .[J].Journal of the Electrochemical Society,1997,144:1273.
[3] Bowman Robert C;Gruen Dieter M;Mendelsohn Marshall H .[J].Solid State communications,1979,32:501.
[4] Lebsanft E;Richter D;Topler J M .[J].Zeitschrift für Physikalische Chemie,1979,116:175.
[5] Yuan Xianxia;Xu Naixin .[J].Journal of Applied Electrochemistry,2001,31(09):1033.
[6] 原鲜霞,徐乃欣.颗粒度对贮氢合金MlNi3.65Co0.75Mn0.4Al0.2电化学性能的影响[J].稀有金属材料与工程,2001(04):306-309.
[7] Zheng G.;White RE.;Popov BN. .ELECTROCHEMICAL DETERMINATION OF THE DIFFUSION COEFFICIENT OF HYDROGEN THROUGH AN LANI4.25AL0.75 ELECTRODE IN ALKALINE AQUEOUS SOLUTION[J].Journal of the Electrochemical Society,1995(8):2695-2698.
[8] Chiaki Iwakura;Takafumi Oura;Hiroshi Inoue et al.[J].Journal of Electroanalytical Chemistry,1995,398:37.
[9] Haran Bala S;Popov Branko N et al.[J].Journal of Power Sources,1998,75:56.
[10] Yuan Xianxia .Study on Electrochemical Behavior of AB5- Type Hydrogen Storage Alloys for Ni- MH Battery[D].Shanghai:Shanghai Institute of Microsystem and Information Technology the Chinese Academy of Science,2002.
[11] Sathya Motupally;Streina Christopher C;Weidner John W .[J].Journal of the Electrochemical Society,1995,142:1401.
[12] Yu Ping;Popov B N;Ritter J A;White R E .[J].Journal of the Electrochemical Society,1999,146:8.
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